The Pearcey Process

The extended Airy kernel describes the space-time correlation functions for the Airy process, which is the limiting process for a polynuclear growth model. The Airy functions themselves are given by integrals in which the exponents have a cubic singularity, arising from the coalescence of two saddle points in an asymptotic analysis. Pearcey functions are given by integrals in which the exponents have a quartic singularity, arising from the coalescence of three saddle points. A corresponding Pearcey kernel appears in a random matrix model and a Brownian motion model for a fixed time. This paper derives an extended Pearcey kernel by scaling the Brownian motion model at several times, and a system of partial differential equations whose solution determines associated distribution functions. We expect there to be a limiting nonstationary process consisting of infinitely many paths, which we call the Pearcey process, whose space-time correlation functions are expressible in terms of this extended kernel.     

Astrogeometry: Toward mathematical foundations

Inimage processing (e.g., inastronomy), the desired black-and-white image is, from the mathematical viewpoint, aset. Hence, to process images, we need to process sets. To define a generic set, we need infinitely many parameters; therefore, if we want to represent and process sets in the computer, we must restrict ourselves to finite-parameter families of sets that will be used to approximate the desired sets. The wrong choice of a family can lead to longer computations and worse approximation. Hence, it is desirable to find the family that it isthe best in some reasonable sense. In this paper, we show how the problems of choosing the optimal family of sets can be formalized and solved. As a result of the described general methodology, forastronomical images, we get exactly the geometric shapes that have been empirically used by astronomers and astrophysicists; thus, we have atheoretical explanation for these shapes.     

Finite Dimensional Unitary Representations of Quantum Anti–de Sitter Groups at Roots of Unity

We study irreducible unitary representations of U _q (SO(2,1)) and U _q (SO(2,?3)) for q a root of unity, which are finite dimensional. Among others, unitary representations corresponding to all classical one-particle representations with integral weights are found for , with M being large enough. In the “massless” case with spin bigger than or equal to 1 in 4 dimensions, they are unitarizable only after factoring out a subspace of “pure gauges” as classically. A truncated associative tensor product describing unitary many-particle representations is defined for . Received: 27 November 1996 / Accepted: 28 July 1997     

Comparative study of the cope rearrangement of hexa-1,5-diene and barbaralane

The classical rules for Cope rearrangements predict a transition state with chair form to be favored over the boat form. On the other hand, bridged homotropylidenes, which allow only a boat-form transition state by steric reasons, have extremely low barriers. A controversy about the correct pathway and the different possible intermediates and transition states of the reaction has gone on for years. In this work, the hypersurfaces of barbaralane, in comparison with the boat- and chair-form of hexa-1,5-diene, are computed by the ab inito CASSCF (6,6)/6-31G** method starting with UMP2/6-31G** natural orbitals (NO's). All three hypersurfaces show characteristic features, and, moreover differ from each other. A hitherto undiscussed intermediate, bicyclo[2.2.0]hexane, was localized on the boat-hexa-1,5-diene pathway. So it is noteworthy that our transition state for the boat-hexa-1,5-diene does not correspond to the transition states found by other authors for this conformation. The computed enthalpies of activation of boat- and chair-hexa-1,5-diene, and barbaralane are in good agreement with the experimental data.     

Some approaches to the multiple-minima problem in the calculation of polypeptide and protein structures

Various methods are used to surmount the multiple-minima problem that is encountered in the multidimensional conformational energy surface of a polypeptide. A summary is given here of two of these methods: (i) The build-up procedure that is modified to include statistical data on the positional frequencies of occurrence of amino acid residues along the chain, and (ii) the diffusion equation method that smoothes out the potential surface, leaving only the potential well containing the global minimum.     

General Quantization

In the Darwinian evolution of physical theories, stability (genericity) has survival value. To convert a singular physical theory based on Lie algebras of several levels into a generic quantum theory with the same levels and nearly the same predictions and symmetries in a limited correspondence domain, it suffices to simplify the algebra of each level by a small homotopy (general quantization). This extends and unifies special relativization, general relativization, and canonical quantization. For exercise I general-quantize the scalar meson field in Minkowski space-time. The predictions of the resulting theory are finite, including its zero-point energy.This updates part of a talk given at Glafka 2005, Athens. quant-ph/0601002     

An algorithm for packing regular multistrand polypeptide structures by energy minimization

An algorithm has been developed for packing polypeptide chains by energy minimization subject to regularity conditions, in which regularity is maintained without the addition of pseudoenergy terms by defining the energy as a function of appropriately chosen independent variables. The gradient of the energy with respect to the independent variables is calculated analytically. The speed and efficiency of convergence of the algorithm to a local energy minimum are comparable to those of existing algorithms for minimizing the energy of a single polypeptide chain. The algorithm has been used to reinvestigate the minimum-energy regular structures of three-stranded (L -Ala)₈, three-stranded (L -Val)₆, five-stranded (L -Ile)₆, and the regular and truncated three-stranded (Gly-L -Pro-L -Pro)₄ triple helices. Local minima with improved packing energies, but with essentially unchanged geometrical properties, were obtained in all cases. The algorithm was also used to reinvestigate the structures proposed previously for the I and II forms of crystalline silk fibroin. The silk II structure was reproduced with slightly improved packing and little other change. The orthorhombic silk I structure showed more change and considerably improved packing energy, but the new regular monoclinic silk I structure had considerably higher energy. The results support the structure proposed previously for silk II and the orthorhombic structure, but not the monoclinic structure proposed for silk I. © 1994 by John Wiley & Sons, Inc.