全文获取类型
收费全文 | 537篇 |
免费 | 11篇 |
国内免费 | 2篇 |
专业分类
化学 | 402篇 |
晶体学 | 2篇 |
力学 | 6篇 |
数学 | 74篇 |
物理学 | 66篇 |
出版年
2021年 | 4篇 |
2020年 | 9篇 |
2019年 | 19篇 |
2018年 | 8篇 |
2017年 | 4篇 |
2016年 | 10篇 |
2015年 | 14篇 |
2014年 | 13篇 |
2013年 | 20篇 |
2012年 | 26篇 |
2011年 | 25篇 |
2010年 | 12篇 |
2009年 | 6篇 |
2008年 | 20篇 |
2007年 | 12篇 |
2006年 | 15篇 |
2005年 | 12篇 |
2004年 | 15篇 |
2003年 | 12篇 |
2002年 | 10篇 |
2001年 | 6篇 |
2000年 | 8篇 |
1998年 | 6篇 |
1997年 | 5篇 |
1995年 | 7篇 |
1994年 | 6篇 |
1993年 | 6篇 |
1992年 | 8篇 |
1991年 | 10篇 |
1990年 | 5篇 |
1989年 | 6篇 |
1988年 | 11篇 |
1987年 | 10篇 |
1985年 | 8篇 |
1984年 | 8篇 |
1983年 | 4篇 |
1982年 | 7篇 |
1981年 | 7篇 |
1979年 | 8篇 |
1977年 | 7篇 |
1976年 | 6篇 |
1975年 | 12篇 |
1974年 | 23篇 |
1973年 | 16篇 |
1972年 | 5篇 |
1956年 | 4篇 |
1947年 | 3篇 |
1902年 | 3篇 |
1901年 | 3篇 |
1888年 | 3篇 |
排序方式: 共有550条查询结果,搜索用时 15 毫秒
1.
The refraction holodiagram RHD is analyzed here with respect to the law of refraction. Particularly, we study the surface that exactly conjugates by refraction a virtual point source with a real image or conversely. By using the total optical path as a parameter we build a diagram that consists in a family of Descartes ovals of the apple type that contains the Pascal's limaçon as a particular extreme case and the spherical surface with the Weierstrass points as another. These representations permit the straightforward application of Fermat's principle in the case of arbitrary refracting surfaces and show the shape of generalized Fresnel's zones in the intersections with any surface. Snell's law is applied to rays incident on the apple type surfaces to find out the conditions for exact conjugation. Sensitivity to optical path variations is also discussed. The RHD curves family can be represented in a Cartesian way where the ovals appear as equally spaced straight lines. 相似文献
2.
3.
4.
5.
6.
By investigation of isomeric 2H- and 13C-labelled C9H11 Cl-compounds it has been shown that the ion [M ? Cl]+ is transformed mainly to the ion [C7H7]+ via C2H4-elimination from alkyl-substituted tropylium-ions. Phenyl-cyclopropane-cations play only a small part, if at all, in this fragmentation process. 相似文献
7.
Zepeck F Gräwert T Kaiser J Schramek N Eisenreich W Bacher A Rohdich F 《The Journal of organic chemistry》2005,70(23):9168-9174
[Structure: see text]. The IspG protein is known to catalyze the transformation of 2-C-methyl-d-erythritol 2,4-cyclodiphosphate into 1-hydroxy-2-methyl-2-(E)-butenyl 4-diphosphate in the nonmevalonate pathway of isoprenoid biosynthesis. We have found that the apparent IspG activity in the cell extracts of recombinant Escherichia coli cells as observed by a radiochemical assay can be enhanced severalfold by coexpression of the isc operon which is involved in the assembly of iron-sulfur clusters. The recombinant protein was isolated by affinity chromatography under anaerobic conditions. With a mixture of flavodoxin, flavodoxin reductase, and NADPH as the reducing agent, stringent assay methods based on photometry or on 13C NMR detection of multiply 13C-labeled substrate/product ratios afforded catalytic activities greater than 60 nmol mg(-1) min(-1) for the protein "as isolated" (i.e., without reconstitution of any kind). Lower apparent activities were found using photoreduced deazaflavin as an artifactual electron donor, whereas dithionite was unable to serve as an artificial electron donor. The apparent Michaelis constant for 2-C-methyl-D-erythritol 2,4-cyclodiphosphate was 700 microM. The enzyme was inactivated by EDTA and could be reactivated by Mn2+. The pH optimum was at 9.0. The protein contained 2.4 iron ions and 4.4 sulfide ions per subunit. The replacement of any of the three conserved cysteine residues afforded mutant proteins which were devoid of catalytic activity and contained less than 6% of Fe2+ and less than 23% of S2- as compared to the wild-type protein. Sequence comparison indicates that putative IspG proteins of plants, the apicomplexan protozoan Plasmodium falciparum, and bacteria from the Bacteroidetes/Chlorobi group contain an insert of about 170-320 amino acid residues as compared with eubacterial enzymes. 相似文献
8.
Mass spectroscopic investigations of 2H- and 13C-labelled derivatives of e.g. 1-, 2-chloro-methyl-naphthalene and 1-chloro-phenyl(5)-pentene-(2)-in-(4) show that the [C11H9]+ ion, which gives [C9H7]+ by acetylene elimination, has the structure of a benztropylium cation. Model considerations show that the formation of this cation [C11H9]+ through a common transition state with a three-membered ring is very probable. 相似文献
9.
The reaction between (Z)-1-alkenyllithium and (E)-β-(N, N-dialkylamino)-α, β-alkenals, (E)-β-(N, N-dialkylamino)-α, β-alkenones or (E)-β-(N, N-dialkylamino)-α, β-alkenoic esters yields mainly (E, Z)-α, β-γ, δ-diunsaturated aldehydes, ketones, or esters and is therefore highly stereospecific. 相似文献
10.
The synthesis of ( - ) 2S,3S,11S,12R-2, 3,11,12-tetraphenyl [18]-crown-6 from (-)-1S,2S-hydrobenzoin and meso-hydrobenzoin is described. Chemical shifts and vicinal coupling constants of the benzylic protons in the 2 S, 3 S and 11 S,12 R substructures in the free ligands and in complexes with KSCN and 1-phenylethylammonium bromides and a brief discussion of the related conformational changes are also presented. A detailed procedure for the resolution of racemic hydrobenzoin is given. 相似文献