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排序方式: 共有113条查询结果,搜索用时 31 毫秒
1.
Demetrio Pitea Laura Bonati Elena Collina Ugo Cosentino Marina Lasagni Giorgio Moro Roberto Todeschini 《Fresenius' Journal of Analytical Chemistry》1994,348(1-2):111-120
Summary The role of multivariate analysis methods in evaluating, rationalizing, and working out complex environmental problems is discussed. The discussion is organized in two sections; a literature analysis of the application of chemometric methods to PCDD/PCDF data interpretation and source correlation and a review of the role of chemometric methods in analysing the results obtained by the Authors studying PCDD/PCDF formation and destruction mechanisms in MSW combustion processes. 相似文献
2.
Demetrio De Calle García M. Reichenbächer Klaus Danzer Christian Hurlbeck Christine Bartzsch Karl-Heinz Feller 《Analytical and bioanalytical chemistry》1998,360(7-8):784-787
The extraction of wine aroma compounds was studied by direct-SPME (DI/SPME), headspace-SPME (HS/SPME) and multiple-headspace-extraction-SPME
(MHE/SPME). The aromagrams obtained by HS/SPME-CGC were evaluated with chemometrical methods for the varietal classification
of wines.
Received: 25 July 1997 / Revised: 24 September 1997 / Accepted: 7 October 1997 相似文献
3.
Giorgio Favini Demetrio Pitea Manuela Sottocornola Roberto Todeschini 《Journal of Molecular Structure》1982,87(1):53-64
The conformational geometries and possible interconversion paths for some oxa derivatives of bicyclo[5.1.0] octane have been studied by the molecular mechanics method. The theoretical results are compared with the experimental data for the molecular geometry of bicyclo[5.1.0] octane and 3,5,8-trioxabicyclo[5.1.0] octane, the free energy of activation for cycloheptene epoxide and 3,5-dioxabicyclo[5.1.0] octane, the dipole moments and molar Kerr constants in solution for cycloheptene epoxide, 3,5-dioxa- and 3,5,8-trioxabicyclo[5.1.0] octane. 相似文献
4.
Alessandro?De?Robertis Concetta?De?Stefano Demetrio?Milea Silvio?SammartanoEmail author 《Journal of solution chemistry》2005,34(10):1211-1226
Complex formation constants were determined potentiometrically (by a ISE-H+, glass electrode) in the systems, M2+ – Lz – H+ [M2+ = (C2H5)2Sn2+, Lz = malonate, glycinate and ethylenediamine] at t = 25 ∘C and 0.1 mol-L−1≤ I/ ≤ 1 mol-L−1 in NaClaq (0.1 mol-L−1 ≤ I ≤ 0.75 mol-L−1 for the ethylenediamine system). Thermodynamic values of formation constants, at infinite dilution, are [± 95% confidence
interval, Tβpqr refer to the equilibrium, pM2+ + qLz + rH+ = MpLqHr(2+z+r)]: for malonate, log10 Tβ110 = (5.47 ± 0.10); for glycinate, log10 Tβ110 = (9.54 ± 0.08), log10 Tβ111 = (12.97 ± 0.10); and for ethylenediamine, log10 Tβ110 = (10.47 ± 0.10), log10 Tβ120 = (16.17 ± 0.12) and log10 Tβ111 = (15.46 ± 0.10). The dependence on ionic strength of the formation constants was modeled by a simple Debye–Hückel type equation
and by the SIT approach. By analyzing the stability of the species in the three different systems we found a simple additivity
rule that can be expressed by the relationship: log10 K = 6.46 nN + 3.96 nO − 0.60 (nN2+ nO2), with a mean deviation, ε(log10 K) = 0.15 (K = equilibrium constant for the interaction of the organometal cation with the unprotonated or protonated ligand, nN = number of amino groups and nO = number of carboxylic groups of the ligand(s) involved in the formation reaction of complex species). 相似文献
5.
Leonardo Dalseno Antonino Júlia Rocha Gouveia Rogrio Ramos de Sousa Júnior Guilherme Elias Saltarelli Garcia Luara Carneiro Gobbo Lara Basílio Tavares Demetrio Jackson dos Santos 《Molecules (Basel, Switzerland)》2021,26(8)
Several efforts have been dedicated to the development of lignin-based polyurethanes (PU) in recent years. The low and heterogeneous reactivity of lignin hydroxyl groups towards diisocyanates, arising from their highly complex chemical structure, limits the application of this biopolymer in PU synthesis. Besides the well-known differences in the reactivity of aliphatic and aromatic hydroxyl groups, experimental work in which the reactivity of both types of hydroxyl, especially the aromatic ones present in syringyl (S-unit), guaiacyl (G-unit), and p-hydroxyphenyl (H-unit) building units are considered and compared, is still lacking in the literature. In this work, the hydroxyl reactivity of two kraft lignin grades towards 4,4′-diphenylmethane diisocyanate (MDI) was investigated. 31P NMR allowed the monitoring of the reactivity of each hydroxyl group in the lignin structure. FTIR spectra revealed the evolution of peaks related to hydroxyl consumption and urethane formation. These results might support new PU developments, including the use of unmodified lignin and the synthesis of MDI-functionalized biopolymers or prepolymers. 相似文献
6.
Pedro G. Massey Mariano A. Ruiz Demetrio Stojanoff 《Linear algebra and its applications》2012,436(3):447-464
We consider reconstruction systems (RS’s), which are G-frames in a finite dimensional setting, and that includes the fusion frames as projective RS’s. We describe the spectral picture of the set of RS operators for the projective systems with fixed weights. We also introduce a functional defined on dual pairs of RS’s, called the joint potential, and study the structure of the minimizers of this functional. In the case of irreducible RS’s the minimizers are characterize as the tight systems. In the general case we give spectral and geometric characterizations of the minimizers of the joint potential. At the end of the paper we show several examples that illustrate our results. 相似文献
7.
Demetrio Labate 《Journal of Geometric Analysis》2002,12(3):469-491
This article presents a general result from the study of shift-invariant spaces that characterizes tight frame and dual frame
generators for shift-invariant subspaces of L2(ℝn). A number of applications of this general result are then obtained, among which are the characterization of tight frames
and dual frames for Gabor and wavelet systems. 相似文献
8.
We prove that the space of spectral measures on a W*-algebra is a smooth Banach manifold in a natural way and that the action of the group of invertible elements of the algebra by inner automorphisms makes it into a reductive homogeneous space. This gives a geometric structure for the set of normal operators with the same spectrum. 相似文献
9.
Let
be a unital C*-algebra and G the group of units of
. A geometrical study of the action of G over the set
+ of all positive elements of
is presented. The orbits of elements with closed range by this action are provided with a structure of differentiable homogeneous space with a natural connection. The orbits are partitioned in 'components' which also have a rich geometrical structure. 相似文献
10.
Pelayo S López-Roldán R González S Casado M Raldúa D Cortina JL Piña B 《Analytical and bioanalytical chemistry》2011,401(6):1861-1869
New regulations on water quality require a close control of the possible biological activities known or unexpected pollutants
may bring about. We present here a protocol based on the direct exposure of zebrafish to river water and the analysis of expression
of specific genes in their scales to determine the presence of compounds with dioxin-like biological activity. The method
does not require the killing of animals and allows detection of the biological activity after a single day of exposure. When
tested, the method with real samples from the Llobregat River, clear temporal and spatial variations were observed, demonstrating
its suitability for monitoring natural variations in water quality linked to specific discharges. High biological activities
were unrelated to the currently checked water quality parameters (macropollutants, turbidity, TOC, etc.), but they did correlate
with the presence of micropollutants (estrogens, detergents, etc.) related to domestic and/or industrial runoffs. The scale
assay therefore provides a new tool to evaluate water quality changes that cannot be easily derived from the existing standard
analytical procedures. It ranks among the very few described protocols able to detect biological effects from natural water
samples, without a pre-concentration step, and after only 24 h of exposure. 相似文献