Shape-preserving approximation inL p

We prove a direct theorem for shape preservingL _p -approximation, 0p, in terms of the classical modulus of smoothnessw ₂(f, t _p ¹ ). This theorem may be regarded as an extension toL _p of the well-known pointwise estimates of the Timan type and their shape-preserving variants of R. DeVore, D. Leviatan, and X. M. Yu. It leads to a characterization of monotone and convex functions in Lipschitz classes (and more general Besov spaces) in terms of their approximation by algebraic polynomials.Communicated by Ron DeVore.     

Convex polynomial and spline approximation in C[−1, 1]

We prove that a convex functionf C[–1, 1] can be approximated by convex polynomialsp _n of degreen at the rate of ₃(f, 1/n). We show this by proving that the error in approximatingf by C² convex cubic splines withn knots is bounded by ₃(f, 1/n) and that such a spline approximant has anL third derivative which is bounded by n³₃(f, 1/n). Also we prove that iff C²[–1, 1], then it is approximable at the rate ofn ^–2 (f, 1/n) and the two estimates yield the desired result.Communicated by Ronald A. DeVore.     

Apparent Molar Volume, Heat Capacity, and Conductance of Lithium Bis(trifluoromethylsulfone)imide in Glymes and Other Aprotic Solvents

Lithium bis(trifluoromethylsulfone)imide (LiTFSI) is a promising electrolyte for high-energy lithium batteries due to its high solubility in most solvents and electrochemical stability. To characterize this electrolyte in solution, its conductance and apparent molar volume and heat capacity were measured over a wide range of concentration in glymes, tetraethylsulfamide (TESA), acetonitrile, -butyrolactone, and propylene carbonate at 25°C and were compared with those of LiClO₄ in the same solvents. The glymes or n(ethylene glycol) dimethyl ethers (nEGDME), which have the chemical structure CH₃–O–(CH₂–CH₂–O) _n –CH₃ for n = 1 to 4, are particularly interesting since they are electrochemically stable, have a good redox window, and are analogs of the polyethylene oxides used in polymer-electrolyte batteries. TESA is a good plasticizer for polymer-electrolyte batteries. Whenever required, the following properties of the pure solvents were measured: compressibilities, expansibilities, temperature and pressure dependences of the dielectric constant, acceptor number, and donor number. These data were used in particular to calculate the limiting Debye-Hückel parameters for volumes and heat capacities. The infinite dilution properties of LiTFSI are quite similar to those of other lithium salts. At low concentrations, LiTFSI is strongly associated in the glymes and moderately associated in TESA. At intermediate concentrations, the thermodynamic data suggests that a stable solvate of LiTFSI in EGDME exists in the solution state. At high concentrations, the thermodynamic properties of the two lithium salts approach those of the molten salts. These salts have a reasonably high specific conductivity in most of the solvents. This suggests that the conductance of ions at high concentration in solvents of low dielectric constant is due to a charge transfer process rather than to the migration of free ions.     

Polynomial approximation inL p (0<p<1)

We prove that forf∈L _p , 0<p<1, andk a positive integer, there exists an algebraic polynomialP _n of degree ≤n such that $$\left\| {f - P_n } \right\|_p \leqslant C\omega _k^\varphi \left( {f,\frac{1}{n}} \right)_p $$ whereω _k ^? (f,t)p is the Ditzian-Totik modulus of smoothness off inL _p , andC is a constant depending only onk andp. Moreover, iff is nondecreasing andk≤2, then the polynomialP _n can also be taken to be nondecreasing.     

Local atomic and electronic structure in the LiVPO4(F,O) tavorite-type materials from solid-state NMR combined with DFT calculations

⁷Li, ³¹P, and ¹⁹F solid-state nuclear magnetic resonance (NMR) spectroscopy was used to investigate the local arrangement of oxygen and fluorine in LiVPO₄F_1-yO_y materials, interesting as positive electrode materials for Li-ion batteries. From the evolution of the 1D spectra versus y, 2D ⁷Li radiofrequency-driven recoupling (RFDR) experiments combined, and a tentative signal assignment based on density functional theory (DFT) calculations, it appears that F and O are not randomly dispersed on the bridging X position between two X–VO₄–X octahedra (X = O or F) but tend to segregate at a local scale. Using DFT calculations, we analyzed the impact of the different local environments on the local electronic structure. Depending on the nature of the VO₄X₂ environments, vanadium ions are either in the +III or in the +IV oxidation state and can exhibit different distributions of their unpaired electron(s) on the d orbitals. Based on those different local electronic structures and on the computed Fermi contact shifts, we discuss the impact on the spin transfer mechanism on adjacent nuclei and propose tentative signal assignments. The O/F clustering tendency is discussed in relation with the formation of short V^IVO vanadyl bonds with a very specific electronic structure and possible cooperative effect along the chain.     

Consistent values and the core in continuum market games with two types of players

The consistent value is an extension of the Shapley value to the class of games with non-transferable utility.? In this paper, the consistent value will be characterized for market games with a continuum of players of two types. We will show that for such games the consistent value need not belong to the core, and provide conditions under which there is equivalence between the two concepts. Received: October 1998 RID="*" ID="*"  This thesis was completed under the supervision of Professor Sergiu Hart, The Center for Rationality and Interactive Decision Theory, Department of Mathematics, Department of Economics, The Hebrew University of Jerusalem. I would like to thank Professor Hart for introducing me to this area of research, for his help and guidance, and, especially, for all his patience.? I would also like to thank Michael Borns for improving the style, and an anonymous referee for helpful comments.