排序方式: 共有45条查询结果,搜索用时 31 毫秒
1.
2.
Résumé L'hydrure d'aluminium AlH3- a été obtenu par action de LiAlH4 sur AlCl3 ou ZnCl2 dans l'éther éthylique. La décomposition thermique a été étudiée par thermogravimé trie sous pression réduite (10–2 torr). La capacité calorifique molaire à 298 K, l'enthalpie de décomposition, ainsi que l'enthalpie de formation ont été déterminées avec un microcalorimètre Calvet.
Ce travail a été effectué dans le cadre d'un contrat de recherches passé par le laboratoire de Thermochimie Minérale avec la Direction des Recherches et Moyen d'Essai. Nous remercions bien vivement cet organisme de l'aide qu'il nous a apportée. 相似文献
Aluminium hydride,-AlH3, was prepared by reaction of LiAlH4 on A1C13 or ZnCl2 in diethyl ether. Thermogravimetry was used to investigate its thermal decomposition under low pressure (10–2 torr). The molar heat capacity at 298 K, the heat of decomposition, and the heat of formation, were measured with a Calvet microcalorimeter.
Zusammenfassung Aluminiumhydrid AlH3- wurde durch Einwirkung von LiAlH4 auf AlCl3 oder ZnCl2 in DiÄthylether hergestellt. Die Thermo gravimetrie wurde zur Untersuchung der thermischen Zersetzung bei niedrigem Druck (10–2 torr) herangezogen. Die molare WÄrmekapazitÄt bei 298 K, die Zersetzungsenthalpie sowie die Bildungsenthalpie wurden mit einem Calvet-Mikrokalorimeter bestimmt.
— - l3 LiAlH4 ll3 ZnCl2 . (10–2 ) . 298 , .
Ce travail a été effectué dans le cadre d'un contrat de recherches passé par le laboratoire de Thermochimie Minérale avec la Direction des Recherches et Moyen d'Essai. Nous remercions bien vivement cet organisme de l'aide qu'il nous a apportée. 相似文献
3.
J. F. Quinson M. Brun J. M. Letoffe P. Claudy 《Journal of Thermal Analysis and Calorimetry》1983,28(1):87-93
A thermal method connects the solid-liquid surface tension/s of a substance to its triple point temperature depression. Here a practical process for application of this method is described. A previous determination of the thickness of the condensate layer which does not freeze near the wall of the porous material is no longer necessary. The process is applied to some organic substances and to a metal (indium).
Zusammenfassung Eine thermische Methode ermöglicht die Oberflächenspannung/s einer Substanz mit der Erniedrigung der Tripelpunkttemperatur in Bezug zu bringen. Eine vorangehende Bestimmung der Dicke der Kondensatschicht, deren Aggregatzustand sich bei Kontakt mit dem porösen Material nicht ändert, ist überflüssig. Die Methode wird auf einige organische Verbindungen und ein Metall (Indium) angewandt.
, .,. — . , , . .相似文献
4.
M. Siniti F. Schiets K. Alouani P. Claudy 《Journal of Thermal Analysis and Calorimetry》2007,89(1):45-50
Several models of DSC apparatuses are given in literature. However, use of these models requires a determination of the values
of the components of the apparatus. Based on the theoretical equations of a first order transition in a coupled-cells heat
flow DSC, two methods of determination of the values of the resistors and two methods of determination of the heat capacities
are given. It seems possible to use these values for desmearing of the DSC experiments. 相似文献
5.
In this research, differential scanning calorimetry (DSC) and gas chromatography is used to determine the wax content of fourteen
crude oils of different sources. Different empirical equations were applied to compare the wax content of crude oils. For
the fourteen crude oil samples with the wax content ranging from 7.5 to 43.8 mass%, it was observed that the results of empirical
equations were in good agreement with those determined by DSC and GC. Accordingly, a correlation between ASTM pour point and
the temperature at which 2 mass% of wax has precipitated out from crude oil is developed. 相似文献
6.
J. P. Bastide K. Ezzemouri J. M. Létoffé P. Claudy A. Bouamrane 《Journal of Thermal Analysis and Calorimetry》1996,47(3):833-846
The thermal behaviour of complexes [Li+-EC](AlH4)– withEC=12-C-4, 15-C-5, DC 18-C-6 (cis-anti-cis andcis-syn-cis isomers) was investigated by Differential Scanning Calorimetry (DSC). These complexes were prepared as solids from benzene solutions. Pure EC and several solvated species [Li+-EC](AlH4)–·nC6H6 (EC=15-C-5, DC 18-C-6syn) were also studied. DSC has revealed various phenomena. Solid-solid transitions were observed before melting for [Li+-EC](AlH4)– withEC=12-C-4 and 15-C-5. They are probably explained by small molecular modifications strongly dependent on the thermal history of the sample. A glass-transition was found for the pure crown-ether DC 18-C-6anti, the complex [Li+-EC](A1H4)– withEC=DC-18-C-6anti and the two solvates mentioned above. 相似文献
7.
8.
The enthalpies of dissolution and dilution of LiBH4 and LiAlH4 in THF have been determined.Dissolutions are exothermic. The endothermic dilution of LiAlH4 suggests for this compound, either a dissociation or an association equilibrium. 相似文献
9.
Thermal characteristics and rheological behaviour of eight crude oils covered a wide range of fluid composition and properties
were studied by differential scanning calorimeter (DSC) and viscometry. Wax appearance temperatures (WAT) of crude oils were
determined by DSC and viscometry. Good agreement is obtained between the results. The dynamic viscosity in the Newtonian temperature
range of the crude oils (above 30°C) generally obeyed a simple first-order Arrhenius type of temperature dependence. Activation
energies of flow in the non-Newtonian range are not uniquely defined.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
10.