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In this paper, we present the absorption and photoluminescence (PL) spectra of conjugated, metal-free organic dyes, triphenylamine derivatives 3-(4-(bis(4-(5-(4-(hexyloxy)phenyl)thiophenyl)phenyl)amino)phenyl)-2-cyanoacrylic acid (OD3) and (E)-3-(5′-(4-(bis(4-(5-(4-hexyloxy)phenyl)thiophen-2-yl)phenyl)amino)phenyl)-2,2′-bithiophen-5-yl)-2-cyanoacrylic acid (OD3DT), with and without a π-conjugated bridge, respectively, in film at a temperature range from 13 to 400 K. We find that the intensities of absorption and PL of OD3 decrease gradually beyond 200 K, as well as the ratios of integral areas of absorption to PL spectra. However, the other compound, OD3DT, shows a very different behavior. An increase is discovered in the ratio of the absorption to PL integral area when the temperature is higher than 200 K. A π-conjugated bridge gives this compound a higher degree of symmetry, and therefore, a better alignment of the molecules in the film, which causes a stacking aggregation such that the temperature effect on this compound is different than OD3.  相似文献   
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This paper describes a mixed-integer programming (MIP) model formulated for strategic capacity planning for light emitting diode (LED) makers of Taiwan, major companies in the global LED market. These firms have complex supply chains across Taiwan and China, and the region’s unique political and economic environment has created not only competitive advantages but also challenges in supply chain management: government regulations require that customer orders be accepted from Taiwan or China according to customer attributes; when conducting manufacturing, Taiwanese firms may need to transfer orders across national borders for reasons such as manufacturing technology (the required technology is available only at certain manufacturing facilities) or more efficient capacity utilization; and there are operations to be performed with specific processing requirements to follow, posing substantial challenges for planners. Motivated by the significance of these firms in the global market, we develop a MIP model with novel features to support their strategic capacity planning, covering demand and manufacturing-related decisions, including order acceptance and transfer, manufacturing starts, capacity expansion, and logistics. We illustrate the model’s performance using modified industry data in a numerical example; we also describe the potential impacts the model may create in industry applications.  相似文献   
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