全文获取类型
收费全文 | 1178篇 |
免费 | 37篇 |
国内免费 | 2篇 |
专业分类
化学 | 970篇 |
晶体学 | 2篇 |
力学 | 2篇 |
数学 | 102篇 |
物理学 | 141篇 |
出版年
2023年 | 6篇 |
2022年 | 7篇 |
2021年 | 8篇 |
2020年 | 19篇 |
2019年 | 13篇 |
2017年 | 5篇 |
2016年 | 30篇 |
2015年 | 10篇 |
2014年 | 26篇 |
2013年 | 49篇 |
2012年 | 40篇 |
2011年 | 44篇 |
2010年 | 28篇 |
2009年 | 22篇 |
2008年 | 56篇 |
2007年 | 40篇 |
2006年 | 44篇 |
2005年 | 45篇 |
2004年 | 58篇 |
2003年 | 36篇 |
2002年 | 24篇 |
2001年 | 17篇 |
2000年 | 23篇 |
1999年 | 13篇 |
1998年 | 6篇 |
1997年 | 10篇 |
1996年 | 7篇 |
1995年 | 12篇 |
1994年 | 7篇 |
1993年 | 9篇 |
1992年 | 7篇 |
1991年 | 8篇 |
1990年 | 11篇 |
1989年 | 10篇 |
1987年 | 5篇 |
1986年 | 11篇 |
1985年 | 7篇 |
1984年 | 15篇 |
1983年 | 12篇 |
1982年 | 6篇 |
1981年 | 6篇 |
1980年 | 5篇 |
1979年 | 10篇 |
1972年 | 6篇 |
1970年 | 5篇 |
1969年 | 5篇 |
1968年 | 43篇 |
1967年 | 116篇 |
1966年 | 96篇 |
1965年 | 80篇 |
排序方式: 共有1217条查询结果,搜索用时 984 毫秒
1.
2.
We prove that a finite solvable group G has at least (49p+1)/60 conjugacy classes whenever p is a prime such that p2 divides the order of G. We also construct an infinite family of finite solvable groups, where this bound is attained. 相似文献
3.
Marianne Gerny Burkhard Alpers 《International Journal of Computers for Mathematical Learning》2004,9(1):25-57
In this article we describe a mathematical microworld for investigating car motion on a racing course and its use with a group of grade 12 students. The microworld is concerned with the mathematical construction of courses and functions which describe car motion. It is implemented in the computer algebra system, Maple®, which provides the means to represent courses and functions symbolically and graphically. We describe the learning opportunities offered by the microworld in relation to the research literature on functions. Various facets and layers of the function concept are addressed in the microworld, and we suggest how work in the microworld might help in overcoming some well-known misconceptions.This revised version was published online in September 2005 with corrections to the Cover Date. 相似文献
4.
5.
6.
Mária Meiarová Katarína Hubinská tefan Toma Burkhard Koch Albrecht Berkessel 《Monatshefte für Chemie / Chemical Monthly》2007,138(11):1181-1186
Summary.
N-Toluensulfonyl-l-prolin amide was tested as catalyst in the enantioselective Michael addition of carbonyl compounds to (E)-β-nitrostyrene in nine ionic liquids under different reaction conditions. The reaction rates and enantioselectivities were
strongly dependent on the ionic liquids. Change of enantioselectivity was observed too and it is attributed to both the cation
and the anion of ionic liquid. The best yields (up to 98%) and enantioselectivity (70% ee) of product were obtained in a basic ionic liquid [bmim]BF4 at room temperature. 相似文献
7.
8.
9.
Thomas M. Klapötke Burkhard Krumm Dieter Naumann 《Journal of fluorine chemistry》2004,125(6):997-1005
The perfluoroaryl tellurolates C6F5TeLi (1) and 4-CF3C6F4TeLi (2) were prepared. These intermediates were identified by NMR spectroscopy and may form, depending on the reaction conditions, either the corresponding ditellanes C6F5TeTeC6F5 (3) and CF3C6F4TeTeC6F4CF3 (4) by subsequent oxidation, or in the case of 1, a telluranthrene (C6F4Te)2 (5) by reaction with itself. The halogenation products of 5, ( C6F4Te)2F4 (6), (C6F4Te)2Cl4 (7), (C6F4Te)2Br4 (8), as well as the azidation product (C6F4Te)2(N3)4 (9) were synthesized. Furthermore, in pursuit of our recent work on tellurium azides, the syntheses and properties of R2Te(N3)2 (R=CF3 (10), C6F2H3 (11)) and RTe(N3)3 (R=CF3 (12) and C6F5 (13)) are reported. The crystal structures of CF3C6F4TeTeC6F4CF3 (4), (C6F4Te)2Br4 (8), and (C6F2H3)2Te(N3)2 (11) were determined. 相似文献
10.
Xiaoqiang Li Stefan Miltschitzky Andreas Grauer Veronika Michlov Burkhard Knig 《Tetrahedron》2006,62(52):12191-12196
The synthesis and peptide-binding properties of a Zn(II)nitrilotriacetate complex substituted with pyrimidine hydrazine amides are reported. The metal complex provides millimolar binding affinity in aqueous buffer to peptides bearing N-terminal His. The pyrimidine heterocycles intermolecularly interact with the bound peptide and quench the emission of nearby Trp residues by energy transfer. 相似文献