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Mössbauer Spectroscopy, X-Ray Diffraction and Electron Microscopy were applied to the study of solid residues of coal hydroliquefaction, for which tin-based catalysts were used. In the general case hydroliquefaction runs were performed in the presence of added sulphur and of finely dispersed SnO2 as a catalyst precursor. The only observed tin species were SnO2 and SnS, the former with percentages higher than expected from XRD, due to its large f factor, the latter as a symmetric doublet, which suggests that any asymmetry should be ascribed to small particle sizes rather than to structure. When the S content was only that of coal and the catalyst precursor β-Sn, FeSn2 occurred together with Sn sulfides and oxides, while no β-Sn was detected. The main catalytic role is ascribed to SnS.  相似文献   
2.
Jacek Brodzki 《K-Theory》1995,9(4):353-377
We show that the entire cyclic cohomology of Banach algebras defined by Connes has the simplicial normalization property. A key tool in the proof is the notion and properties of supertraces on the Cuntz algebraQ A. As an example of further applications of this technique, we give a proof of the homotopy invariance of entire cyclic cohomology.Address after 1st October 1995: Department of Mathematics, University of Exeter, North Park Road, Exeter EX4 4QE, U.K.  相似文献   
3.
It is proved that every topologically pure extension of Fréchetalgebras 0 I A A/I 0 such that I is strongly H-unital hasthe excision property in continuous (co)homology of the followingtypes: bar, naive-Hochschild, Hochschild, cyclic, and periodiccyclic. In particular, the property holds for every extensionof Fréchet algebras such that I has a left or right boundedapproximate identity.  相似文献   
4.
We study the projective linear group PGL 2(A) associated with an arbitrary algebra A and its subgroups from the point of view of their action on the space of involutions in A. This action formally resembles M?bius transformations known from complex geometry. By specifying A to be an algebra of bounded operators in a Hilbert space H, we rediscover the M?bius group μ ev (M) defined by Connes and study its action on the space of Fredholm modules over the algebra A. There is an induced action on the K-homology of A, which turns out to be trivial. Moreover, this action leads naturally to a simpler object, the polarized module underlying a given Fredholm module, and we discuss this relation in detail. Any polarized module can be lifted to a Fredholm module, and the set of different lifts forms a category, whose morphisms are given by generalized M?bius tranformations. We present an example of a polarized module canonically associated with the differentiable structure of a smooth manifold V. Using our lifting procedure we obtain a class of Fredholm modules characterizing the conformal structures on V. Fredholm modules obtained in this way are a special case of those constructed by Connes, Sullivan and Teleman. Received: 2 October 1997 / Accepted: 11 August 1998  相似文献   
5.
We define the concept of a partial translation structure ona metric space X and show that there is a natural C*-algebraC*() associated with it, which is a subalgebra of the uniformRoe algebra C*u(X). We introduce a coarse invariant of the metricwhich provides an obstruction to embedding the space in a group.When the space is sufficiently group-like, as determined byour invariant, properties of the Roe algebra can be deducedfrom those of C*(). We also give a proof of the fact that theuniform Roe algebra of a metric space is a coarse invariantup to Morita equivalence.  相似文献   
6.
In an earlier paper, the authors introduced partial translation algebras as a generalisation of group C?C?-algebras. Here we establish an extension of partial translation algebras, which may be viewed as an excision theorem in this context. We apply this general framework to compute the K-theory of partial translation algebras and group C?C?-algebras in the context of almost invariant subspaces of discrete groups. This generalises the work of Cuntz, Lance, Pimsner and Voiculescu. In particular we provide a new perspective on Pimsner's calculation of the K-theory for a graph product of groups.  相似文献   
7.
We develop some of the ingredients needed for string theory on noncommutative spacetimes, proposing an axiomatic formulation of T-duality as well as establishing a very general formula for D-brane charges. This formula is closely related to a noncommutative Grothendieck-Riemann-Roch theorem that is proved here. Our approach relies on a very general form of Poincaré duality, which is studied here in detail. Among the technical tools employed are calculations with iterated products in bivariant -theory and cyclic theory, which are simplified using a novel diagram calculus reminiscent of Feynman diagrams.  相似文献   
8.
Let G denote the p-adic group GL(n), and let S(G) denote theSchwartz algebra of G. We construct a Chern character from theK-theory of the reduced C*-algebra of G to the periodic cyclichomology of S(G) which becomes an isomorphism after tensoringover Z with C.  相似文献   
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