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1.
Artūras Dubickas 《Proceedings Mathematical Sciences》2005,115(4):391-397
Suppose that α > 1 is an algebraic number and ξ > 0 is a real number. We prove that the sequence of fractional partsξα
n
, n = 1, 2, 3, …, has infinitely many limit points except when α is a PV-number and ξ ∈ ℚ(α). For ξ = 1 and α being a rational
non-integer number, this result was proved by Vijayaraghavan. 相似文献
2.
3.
J. Požela A. Namajūnas A. Tamaševičius J. Ulbikas 《Applied Physics A: Materials Science & Processing》1989,48(2):181-188
A method for quantitative characterization of chaotic dynamical systems is discussed. An electronic instrument for determining the number of independent variablesk
*, involved in the motion, is described. It allows one to obtain these in real time from a single observable. The suggested technique has been applied to quantification of strange attractors underlying chaotic instabilities in semi-insulating GaAsCr, and n-Ge, irradiated with high energy electrons. In n-Ge, for instance, the measured numbersk
* range from 2 to 4 depending on control parameters. These measurements reveal the highly deterministic nature of the observed chaotic oscillations. The physical mechanisms responsible for the current instabilities and chaotic behaviour are discussed. 相似文献
4.
S. Stupnikova E. Petushkova D. Muceniece V. Lūsis 《Chemistry of Heterocyclic Compounds》2007,43(1):41-49
The recyclization of 1,4-dihydropyridines in aqueous-alcoholic hydrochloric acid medium proceeds with cleavage of a C-N bond
and pyridine ring opening. Cyclohexenone derivatives are formed as a result of the subsequent intramolecular crotonic condensation
of the acyclic intermediate. The leaving carbonyl substituents depart simultaneously with recyclization, depending on the
acidity of the reaction medium.
Dedicated to Prof. Dr. E. Lukevics on the occasion of his 70th birthday.
__________
Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 1, pp. 49–58, January, 2007. 相似文献
5.
[reaction: see text] Catalytic, enantioselective Mannich-type reactions of alpha-imino esters bearing readily removable substituents on nitrogen are described. Several N-carbamate-protected alpha-imino esters, which are readily prepared from 2-bromoglycine esters using a polymer-supported amine, reacted with silicon enolates to afford the desired adducts in high yields with high enantioselectivity using a copper(II)-diamine complex. Easy deprotection of the product amine and transformation to free alpha-amino acid derivatives have also been demonstrated. 相似文献
6.
Several transition metal salts were found to catalyze aza-Michael reactions of enones with carbamates efficiently. The catalytic activity was strongly dependent on the nature of the metal salts. While conventional Lewis acids such as BF(3).OEt(2), AlCl(3), or TiCl(4) showed lower activity, group 7-11 transition metal salts in higher oxidation states such as ReCl(5), Fe(ClO(4))(3).9H(2)O, RuCl(3).nH(2)O, OsCl(3).3H(2)O, RhCl(3).nH(2)O, PtCl(4).5H(2)O, or AuCl(3).H(2)O exhibited higher catalytic activity. [reaction: see text] 相似文献
7.
G. Juzeliūnas 《Zeitschrift für Physik D Atoms, Molecules and Clusters》1988,8(4):379-384
Exciton absorption spectrum of optically excited linear molecular aggregate is theoretically investigated. The sum rules for the integral intensity of the absorption spectrum are derived. The dipole moments of the optical transitions from the one-exciton states to the two-exciton states are presented. The results obtained indicate an energy increase of the exciton transition after a single excitation of the aggregate. It accounts for the observed short-wavelength shift of the J-band of the pseudoisocyanine (PIC) J-aggregates after their optical excitation. The comparison of the experimental energy of the shift with its theoretical evaluation allows to estimate the number of monomers forming a typical PIC J-aggregate in the solutionN ?20–30. 相似文献
8.
R. Ramanauskas L. Gudavičiūtė A. Kaliničenko R. Juškėnas 《Journal of Solid State Electrochemistry》2005,9(12):900-908
The influence of pulse plating parameters on the surface morphology, grain size, lattice imperfection and corrosion properties
of Zn–Ni alloy has been studied. The coatings were electrodeposited in an alkaline cyanide-free solution. AFM was applied
for surface morphology examination, XRD measurements were carried out for phase composition and texture analysis, electron
probe microanalysis was used for alloy chemical composition studies, while electrochemical techniques were applied for corrosion
performance evaluation. The pulse plated Zn–Ni coatings appeared to consist of the γ-Zn21Ni5 phase and the composition of the alloy depended on the plating parameters. The grain size, lattice imperfection and homogeneity
of grain distribution were established to be the main factors determining corrosion behaviour of the coating.
Presented at the 4th Baltic Conference on Electrochemistry, Greifswald, March 13–16, 2005 相似文献
9.
The mean-square molecular dipole moments 〈μ2〉 of carbazole, N-ethylcarbazole and of the sequence of poly(epoxypropylcarbazole) (PEPCa) oligomers of various molecular weights have been evaluated in solutions of these organic compounds in dioxan. For PEPCa the values of 〈μ2〉 have also been determined in the solid state. On the basis of the experimental results and of molecular mechanics calculations it has been shown that the orientation of the lateral group of PEPCa favors noninteracting racemic dyads. The temperature-dependence of the effective dipole moment of solid PEPCa follows the Onsager theory above 295 K. 相似文献
10.
Žydrė Šaltienė Natalija Jatulienė Mudis Šalkauskas Daiva Brukštienė Asta Ruzgytė Aušra Tarasevičiūtė Julius Kalibatas 《Accreditation and quality assurance》2005,10(8):444-451
The estimation scheme of uncertainty of determination of 1-hydroxypyrene (1-OHP) in urine was developed analysing the main
stages of the analytical procedure: (1) preparation of 1-OHP standards, (2) creation of the calibration curve for the high
performance liquid chromatography (HPLC) analysis method with the evaluation of recovery, (3) measuring procedure of aliquot
of urine, (4) adjusting the pH of aliquot and hydrolysis with enzyme, (5) solid phase extraction, (6) concentration of the
extract, (7) injection of the extract to chromatograph and analysing by the HPLC method, (8) calculation of 1-OHP mass from
the calibration curve, (9) calculation of 1-OHP concentration in urine. The evaluation of the uncertainty is based on quantification
of individual components. Combined uncertainty was calculated using the law of propagation of uncertainties according to the
EURACHEM/CITAC guidelines. Level dependence of the uncertainty arises from the calibration curve.
The limits of detection and quantification were found to be equal to 0.03 and 0.1 ng/mL, respectively. The calculated expanded
level-dependent uncertainty covers 47–27–25% within the concentration range 0.03–0.1–0.4 ng/mL with the materials and equipment
used. These parameters could easily be recalculated according to the proposed scheme if there are some changes in the analysis
procedure. 相似文献