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1.
2.
Yuri M. Boiko Anders Bach Jørgen Lyngaae-Jørgensen 《Journal of Polymer Science.Polymer Physics》2004,42(10):1861-1867
Films of amorphous polystyrene (PS) with a weight-average molecular weight (Mw) of 225 × 103 g/mol were bonded in a T-peel test geometry, and the fracture energy (G) of a PS/PS interface was measured at the ambient temperature as a function of the healing time (th) and healing temperature (Th). G was found to develop with (th)1/2 at Th = Tg-bulk − 33 °C (where Tg-bulk is the glass-transition temperature of the bulk sample), and log G was found to develop with 1/Th at Tg-bulk − 43 °C ≤ Th ≤ Tg-bulk − 23 °C. The smallest measured value of G = 1.4 J/m2 was at least one order of magnitude larger than the work of adhesion required to reversibly separate the PS surfaces. These three observations indicated that the development of G at the PS/PS interface in the temperature range investigated (<Tg-bulk) was controlled by the diffusion of chain segments feasible above the glass-transition temperature of the interfacial layer, in agreement with our previous findings for fracture stress development at several polymer/polymer interfaces well below Tg-bulk. Close values of G = 8–9 J/m2 were measured for the symmetric interfaces of polydisperse PS [Mw = 225 × 103, weight-average molecular weight/number-average molecular weight (Mw/Mn) = 3] and monodisperse PS (Mw = 200 × 103, Mw/Mn = 1.04) after healing at Th = Tg-bulk − 33 °C for 24 h. This implies that the self-bonding of high-molecular-weight PS at such relatively low temperatures is not governed by polydispersity. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1861–1867, 2004 相似文献
3.
Andr Luciani Christopher J. G. Plummer Tuan Nguyen Lszl Garamszegi Jan‐Anders E. Mnson 《Journal of Polymer Science.Polymer Physics》2004,42(7):1218-1225
The effects of the size (pseudo‐generation number) and nature of end groups on physical and rheological properties were investigated for a series of hyperbranched polyesters based on an ethoxylated pentaerythritol core and 2,2‐bis‐(hydroxymethyl)propionic acid repeat units. The observed linear dependence of the melt viscosity on the molar mass in the high pseudo‐generation‐number limit indicated that entanglement effects were substantially absent. Moreover, the marked influence of end capping of the end groups on the physical and rheological properties suggested that intermolecular interactions were dominated by contacts between the outer shells of the molecules, in which the end groups were assumed to be concentrated. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 1218–1225, 2004 相似文献
4.
In this paper we prove the equivalence of various algebraically or geometrically defined assembly maps used in formulating the main conjectures in K- and L-theory, and C*-theory.Partially supported by NSERC grant A4000 and NSF grant DMS 9104026. The authors also wish to thank the SFB für Geometrie und Analysis, Münster, and the Max Planck Institut für Mathematik, Bonn, for their hospitality and support.Received: 7 May 2001 相似文献
5.
T. B. Anders W. Jachmann A. O. Barut 《Zeitschrift fur Physik C Particles and Fields》1992,56(4):561-563
The polarization asymmetries related to usual polarizations combine at least 4 different helicity amplitudes. The introduction of ±45° inclined transverse polarizations allows us to obtain the complete set of new polarization asymmetries combining only up to 3 helicity amplitudes. There are no further polarization asymmetries depending on a smaller number of helicity amplitudes. These expressions are most economical to determine the helicity amplitudes from observed data. Some of them are suitable to study especially the spin-flip effects. We give a complete Table of all such polarization asymmetries. 相似文献
6.
Anders Frankild 《Mathematische Zeitschrift》2003,244(3):615-630
We study the vanishing properties of local homology of complexes of modules without assuming that its homology is artinian.
Using vanishing results for local homology and cohomology we prove new vanishing results for Ext- and Tor-modules.
Received: 1 August 2002; in final form: 23 September 2002 /
Published online: 16 May 2003
Mathematics Subject Classification (1991): 13C12, 13D07, 13D45. 相似文献
7.
The mechanism of ozone formation has been studied using 16O and 18O2. High-resolution microwave spectroscopy was used to measure the amounts of the isotopomeric ozone species formed. The study is hampered by the very rapid exchange process between the reactants, that tends to scramble the isotopes and hence give a 2:1 statistical ratio between the two possible isotopomers. We have found a strategy to come around this difficulty and conclude that the mechanism is a simple end-on-addition. 相似文献
8.
1-(3-Alkyl-2,3-dideoxy-alpha,beta-D-erythro-pentofuranosyl)uracils and 1-(3-alkyl-2,3-dideoxy-alpha,beta-D-threo-pentofuranosyl)uracils have been prepared from (E)-4,5-di-O-acetyl-2,3-dideoxy-aldehydo-D-glycero-pent-2-enose by a Michael addition reaction of the appropriate organocopper reagent followed in subsequent order by glycosidation of the resulting 3-alkyl-4,5-diacetoxypentanal with methanolic hydrogen chloride, protection with p-methoxybenzoyl chloride, and trimethylsilyl triflate catalyzed coupling with 2,4-di-O-(trimethylsilyl)uracil. The nucleosides were deprotected by treatment with 33% methylamine in absolute ethanol and separated by reversed-phase HPLC. 相似文献
9.
10.
A E Abdel-Megied P Hansen E B Pedersen C M Nielsen 《Acta chemica Scandinavica (Copenhagen, Denmark : 1989)》1991,45(10):1060-1063
The 3'-iodonucleoside 4 and the 3'-O-methylsulfonylthymidine 9 have been synthesized by condensation of silylated uracils 2 with methyl 5-O-tert-butyldiphensilyl-2,3-dideoxy-3-iodo-D-threo-pentofuran oside (3) and methyl 5-O-tert-butyldiphenylsilyl-2-deoxy-3-methylsulfonyl-D-erythro- pentofuranoside (8), respectively. The nucleoside 4 and 9 produced the corresponding 2',3'-didehydro-2',3'-dideoxynucleosides 5 in an elimination reaction on treatment with sodium methoxide. The compounds 5b showed no antiviral activity against HIV-1. 相似文献