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1.
Condeixa Lucas Dias Silva Pierry Moah Diego Farias Brenda Leiras Adriana 《Central European Journal of Operations Research》2022,30(3):921-940
Central European Journal of Operations Research - Societal awareness and legislation changes concerning sustainability have affected how organizations generate value for stakeholders, as well as... 相似文献
2.
Alvim Adriana C.F. Ribeiro Celso C. Glover Fred Aloise Dario J. 《Journal of Heuristics》2004,10(2):205-229
We propose in this work a hybrid improvement procedure for the bin packing problem. This heuristic has several features: the use of lower bounding strategies; the generation of initial solutions by reference to the dual min-max problem; the use of load redistribution based on dominance, differencing, and unbalancing; and the inclusion of an improvement process utilizing tabu search. Encouraging results have been obtained for a very wide range of benchmark instances, illustrating the robustness of the algorithm. The hybrid improvement procedure compares favourably with all other heuristics in the literature. It improved the best known solutions for many of the benchmark instances and found the largest number of optimal solutions with respect to the other available approximate algorithms. 相似文献
3.
This paper addresses the natural question: “How should frames be compared?” We answer this question by quantifying the overcompleteness of all frames with the same index set. We introduce the concept of a frame measure function: a function which maps each frame to a continuous function. The comparison of these functions induces an equivalence and partial order that allows for a meaningful comparison of frames indexed by the same set. We define the ultrafilter measure function, an explicit frame measure function that we show is contained both algebraically and topologically inside all frame measure functions. We explore additional properties of frame measure functions, showing that they are additive on a large class of supersets—those that come from so called non-expansive frames. We apply our results to the Gabor setting, computing the frame measure function of Gabor frames and establishing a new result about supersets of Gabor frames. 相似文献
4.
Adriana Tudose 《Tetrahedron letters》2006,47(48):8529-8533
Simple catalysts formed in situ from palladium acetate and a variety of imidazolium and imidazolinium carboxylates and dithiocarboxylates have been screened in the coupling of aryl halides with trans-2-phenylvinylboronic acid. Imidazol(in)ium carboxylates show an excellent activity, which compares to that displayed by the parent imidazol(in)ium chlorides, whereas imidazol(in)ium dithiocarboxylates are poorly efficient. Interestingly, the base employed exerts a profound influence on the trans/cis stereochemistry of the coupling product. 相似文献
5.
N. Jiten Singh Adriana C. Olleta Anupriya Kumar Mina Park Hai-Bo Yi Indrajit Bandyopadhyay Han Myoung Lee P. Tarakeshwar Kwang S. Kim 《Theoretical chemistry accounts》2006,115(2-3):127-135
In earlier studies, the interactions of isolated ionic species with various solvents were investigated using ab initio calculations.
The ionic species investigated included cations (proton, hydronium, ammonium, and metal cations) and anions (single electron,
hydroxide, and halide anions). However in the present study, we investigate the interactions of these ionic species with the
solvent in the presence of other competing ionic species. We also elaborate on how the information obtained from these extensive
studies have been employed in designing and synthesizing various kinds of novel ionophores and receptors. 相似文献
6.
Angela Lopedota Adriana Trapani Annalisa Cutrignelli Valentino Laquintana Nunzio Denora Massimo Franco Giuseppe Trapani Gaetano Liso 《Journal of inclusion phenomena and macrocyclic chemistry》2007,57(1-4):425-432
The objective of this work was to develop a novel microparticulate system based on the mucoadhesive polymer Eudragit-RS 100
and cyclodextrins (CDs), potentially useful for the oral administration of Glutathione (γ–glutamylcysteinylglycine, GSH).
For this purpose, an oil-in-oil (O/O) emulsion-solvent evaporation method was used for the preparation of microparticles (MPs)
containing GSH alone or together with one of the following CDs: α-, β-, γ-, methyl-β-(Me-β-), hydroxypropyl-β-(HP-β-) or sulfobutylether-β-cyclodextrin
(SBE7m-β-CD). MPs were obtained by emulsifying a mixture of Eudragit RS 100, GSH, CD and magnesium stearate in acetone or acetonitrile
with a mixture of liquid paraffin and Span 80. Size, encapsulation efficiency, and drug release of the prepared MPs were evaluated.
The results clearly indicated that all the examined properties were dependent on the water-miscible solvents and CD used.
In particular, MPs prepared by using acetone or acetonitrile showed different size distributions with mean diameters in the
ranges 82–350 and 15–22 μm, respectively. Moreover, encapsulation efficiency values were found to be high in all cases (71–99%)
and was significantly affected by the CD type. The GSH release rates were evaluated employing dissolution media with different
pH values (1.2, 6.8 and 7.4) and the following rank order was obtained for MPs prepared using acetone: MPs incorporating Me-β-CD > MPs
without CD > MPs incorporating the remaining CDs. On the other hand, MPs prepared using acetonitrile gave the highest GSH
release rate. Finally, stability of GSH encapsulated in MPs containing HP-β-CD to enzymatic attack by pepsin A, α-chymotrypsin,
and γ-glutamyltranspeptidase was also investigated. 相似文献
7.
Maurizio Lenarda Renzo Ganzerla Adriana Lisini Mauro Graziani Tristano Boschi 《Transition Metal Chemistry》1981,6(4):199-203
Summary Platinum(0) and palladium(0) complexes of the type: P2M(R1R2C=CR3R4) (P=trisubstituted phosphine; R1, R2, R3 and R4 are different groups having electron acceptor or electron donor properties; M=Pt or Pd) with so called pushpull olefins, have been prepared and characterized. In some cases unusual patterns in the n.m.r. spectra of olefinic protons were observed. The spectra were analyzed by computer simulation and general rules for ABMX patterns for this type of complexes are given. 相似文献
8.
Screening and analytical confirmation of sulfonamide residues in milk by capillary electrophoresis-mass spectrometry 总被引:1,自引:0,他引:1
A new methodology is proposed to automate the monitoring of sulfonamide residues in milk samples. It combines a screening unit for the total amount of sulfonamide with capillary electrophoresis-mass spectrometry (CE-MS) equipment for processing the samples containing a detectable level of sulfonamide. The screening unit consists of continuous-flow system (CFS) to precipitate the proteins connected on-line to the CE-MS equipment, in which a common characteristic ion of all sulfonamides was monitored with the MS detector by flushing the sample through the capillary. The confirmatory method is based on the purification and preconcentration of sulfonamides in a CFS unit and posterior analysis by CE-MS. The sample treatment unit was also on-line connected to the CE-MS equipment. In order to increase sensitivity, the flow rate of the sheath liquid was diminished from 0.5 to 0.2 microL.min(-1) by increasing the content in water from 0 to 50% and the formic acid from 0.5 to 1.5% in this liquid and by applying an overimposed pressure of 5 mbar during the electrophoretic separation. The method allowed the analysis of 30 samples per hour. 相似文献
9.
A spectrofluorimetrical selective method was designed for determination of paracetamol in tablets. This important technique can be characterized by its sensitivity, simplicity, celerity and cheaper cost than current official methods. The employed methodology involves coumarinic compound formation obtained by reaction between paracetamol and ethylacetoacetate (EAA) in the presence of sulphuric acid as catalyst. The reaction product is highly fluorescent at 478 nm, being excited at 446 nm.The linear concentration range of the application was 0.1-0.4 μg/ml of paracetamol and the detection limit was 57 ng/ml.The influence of different variables was studied and optimized through chemometric techniques. Applying the above-mentioned method good results were obtained with regard to pharmaceutical formulations containing paracetamol. Therefore, it is relevant to suggest this profitable technique for medicament control analysis. 相似文献
10.
This work shows the potentiality of As as internal standard to compensate errors from sampling of sparkling drinking water samples in the determination of selenium by graphite furnace atomic absorption spectrometry. The mixture Pd(NO3)2/Mg(NO3)2 was used as chemical modifier. All samples and reference solutions were automatically spiked with 500 μg l−1 As and 0.2% (v/v) HNO3 by the autosampler, eliminating the need for manual dilutions. For 10 μl dispensed sample into the graphite tube, a good correlation (r=0.9996) was obtained between the ratio of analyte absorbance by the internal standard absorbance and the analyte concentrations. The relative standard deviations (R.S.D.) of measurements varied from 0.05 to 2% and from 1.9 to 5% (n=12) with and without internal standardization, respectively. The limit of detection (LD) based on integrated absorbance was 3.0 μg l−1 Se. Recoveries in the 94-109% range for Se spiked samples were obtained. Internal standardization (IS) improved the repeatability of measurements and increased the lifetime of the graphite tube in ca. 15%. 相似文献