Metal-Assisted Oxidative Cyclization of Arylamidrazones I. Synthesis of 3-Acetyl-1,4-dihydro-1-phenyl-1,2,4-benzotriazine

In the presence of RuCl₃, N-phenylamidrazone underwent oxidative cyclization into 1,4-dihydro-1-phenyl-1,2,4-benzotriazine, the structure of which is established by spectral and X-ray diffraction data.     

Analysis of electromagnetic wave propagation in complex dielectric materials with uncertainty

We consider the propagation of high frequency electromagnetic pulses in complex materials with nonlinear polarization. The physical problem is modeled by Maxwell’s equations in variational form, and well-posedness results are established with respect to probability distributions on the polarization parameters (in a Prohorov metric sense).     

Synthesis and characterization of MFe2O4 sulfur nanoadsorbents

Nanoparticles of ferrites (Fe₃O₄, NiFe₂O₄, CuFe₂O₄, and MnFe₂O₄) were prepared by a reverse (water/oil) microemulsion method. The microemulsion system consisted of cetyltrimethylammonium bromide, 1-butanol, cyclohexane, and a metal salt solution. The procedure was carried out using aqueous ammonia as the coprecipitating agent. Nanosized particles were characterized by thermal analysis, X-ray diffraction, Fourier transform infrared spectroscopy, transmission electron microscopy, and pyridine adsorption. The NiFe₂O₄ sample exhibited narrow mesoporous pore size distribution and high surface area ≈233 m²/g. It achieved good adsorption activity towards the dibenzothiophene (DBT) compound (166.3 μmol/g of DBT adsorbent). The structural properties obtained were very interesting for potential applications in the desulfurization process in petroleum refining.     

Project of an internal target for the antiproton ring at FAIR

The case of the internal target for the hyper-nuclear experiment of the PANDA (antiproton Annihilation at Darmstadt) Collaboration at the High Energy Storage Ring of Facility for Antiproton and Ion Research is illustrated. After a discussion of the problems arising from the interaction of a solid internal target with an antiproton beam, the design of material, shape and sizes of a target satisfying the experimental requirements is presented. The techniques used to produce a prototype of this target are illustrated. Then the results of the tests performed on the prototype for investigating the properties (purity, radiation hardness, structure modifications after shaping) are reported and the plan of the future activity is pointed out.     

Douglas algebras which are invariant under the Bourgain map

Part of this work was done while the second author was visiting the University of Georgia, Athens/Georgia, USA.     

Indirect spectrophotometric determination of chromium(VI)

A new simple and sensitive spectrophotometric method for the determination of chromium(VI) is established. It relies upon the oxidation of iron(II) with the titled ion, in acidic medium, to form iron(III) which is complexed with tiron to form a stable blue color with maximum absorption at 650 nm. Adherence to Beer's law is observed in the range 10–100 μg of chromium(VI) per 25 ml, with a molar absorptivity of 5.6 × 10³ liters mol^?1 cm^?1, sensitivity index of 0.0093 μg cm^?1, relative error of ?5.0 to +0.3%, and relative standard deviation of 0.3–4.0%, depending on the concentration level. Furthermore, the reaction needs neither temperature control nor an extraction step.