Excitation energy transfer between Er3+ and Tm3+ in LiNbO3

Conclusions Nonradiative energy transfer between similar and different rare-earth ions in LiNbO₃ has been evidenced for the first time. The contribution of nonradiative energy transfer to the decay of the¹G₄ and³H₄ levels of thulium and the⁴S_3/2 and⁴I_13/2 levels of erbium is significant for activator concentrations of the order of several thousand ppm in LiNbO₃. The excitation of higher-lying levels of both activators is transferred faster in codoped crystal to the lowest luminescent levels, from which the luminescence in the 1–2-μm spectral region occurs. This accelerated relaxation is advantageous for broadband optical pumping since the contribution of radiative transitions competing with the³F₄−³H₆ laser transition of thulium is reduced. On the other hand, it appears that erbium ions will influence adversely the efficiency of a laser-diode-pumped LiNbO₃∶Er, Tm laser operating near 1.8 μm since the part of the³H₄ excitation transferred to erbium ions is emitted from the long-lived⁴I_11/2 level of Er³⁺. Furthermore, the⁴I_13/2 excitation is not transferred fully to thulium ions and is lost in⁴I_13/2−⁴I_15/2 emission. Lithium niobate singly doped with thulium is more promising since the cross-relaxation process that transfers the excitation from the³H₄ level to the³F₄ level appears to be efficient in this host. Published in Zhurnal Prikladnoi Spektroskopii, Vol. 62, No. 5, pp. 125–133, September–October, 1995.     

Optical spectroscopy of chromium doped (CH3)2NH2X(SO4)2·6H2O (X=Al, Ga) single crystals

Chromium doped (CH₃)₂NH₂Al(SO₄)₂·6H₂O (DMAAlS) and (CH₃)₂NH₂Ga(SO₄)₂·6H₂O (DMAGaS) single crystals were grown and investigated using the methods of optical spectroscopy. It was found that the Cr³⁺ ions in the two crystals are situated in a strong crystal field in which the ²E state is the lowest. The single narrow R-line associated with the ²E–⁴A₂ phosphorescence of Cr³⁺ in DMAAlS in a ferroelectric phase indicates an undistorted octahedral site, whereas important distortion of O_h symmetry and structural disorder was inferred from spectral data obtained with DMAGaS:Cr³⁺ in a low temperature phase. Results of optical investigation are discussed taking into account the structural data.     

Isotope Zusammensetzung Der Mineralwässer Der Mongolei

Abstract

The isotopic composition (D, ¹⁸O, ⁸⁷Sr, ³He) of thermal and mineral waters of Mongolia is discussed. The Sr-isotope ratio depends on the rock's contact. Near the Chubsugul-lake ³He-/⁴He-values are high. A certain similarity between the waters of Mongolia and those of East Siberia can be derived from the obtained data.     

Semi-active stabilisation of a pipe conveying fluid using eddy-current dampers: state-feedback control design,experimental validation

An application of electromagnetic devices of the motional type (i.e. eddy-current dampers) to improve the dynamic stability of a cantilever pipe discharging fluid is proposed. When the flow velocity reaches a critical value, this system loses stability through the flutter. A contactless damping device is used. This actuator is made of a conducting plate attached to the pipe that moves together with it within the perpendicular magnetic field that is generated by the controlled electromagnets. During the motion the eddy currents in the plate and a resultant drag force of a viscous character are generated. First, an optimal control problem that aims to stabilise the system with the optimal rate of decrease of the system’s energy is posed and solved. Then a state-feedback parametrization of the obtained optimal control, which can be used in a closed-loop scheme is proposed. The effectiveness of the designed optimal controller is validated by making a comparison with the corresponding passive solutions on the specially designed and constructed experimental test stand of a pipe conveying air.

     

Effect of heat treatment on Er3+ containing multicomponent oxyfluoride lead borate glass system

Effect of heat treatment on Er³⁺ containing multicomponent oxyfluoride lead borate glasses in (72 ? x)PbO–xPbF₂–18B₂O₃–6Al₂O₃–3WO₃–1ErF₃ (where x = 9 or 72) system have been studied. The samples with low and high PbF₂ concentrations were analyzed using X-ray diffraction and luminescence spectroscopy. Several narrowed and relatively intense diffraction lines have been formed after heat treatment attributed to the orthorhombic PbF₂ phase. Luminescence spectroscopy revealed bands due to ⁴I_13/2–⁴I_15/2 and ⁴S_3/2–⁴I_15/2 transitions of Er³⁺ ions. This observation makes these glasses candidates for NIR laser active media and up-conversion applications.