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Vianney Guilly Boris Khasainov Henri-Noël Presles Daniel Desbordes 《Comptes Rendus Mecanique》2006,334(11):679-685
We present the results of numerical two-dimensional simulations of detonation cellular structures under non-monotonous heat release provided by a chemical reaction comprising two successive exothermic steps. The influence of the rate of the second step of chemical reaction on the detonation cellular structure has been investigated. Our simulations are the first that reproduce a cellular structure composed of two clearly distinct sets of cells with different characteristic sizes where fine cells completely fill up larger ones, as has been observed experimentally. To cite this article: V. Guilly et al., C. R. Mecanique 334 (2006). 相似文献
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Daniel Desbordes Henri Noël Presles Franckie Joubert Cresus Gbagdo Douala 《Comptes Rendus Mecanique》2004,332(12):993-999
Calculations of the detonation reaction zone of gaseous H2NO2/N2O4 mixtures in the range of equivalence ratio Φ between 0.25 and 0.7 show that for 0.25Φ0.4 the chemical energy is released in two distinct and successive exothermic steps characterised by different chemical characteristic times. As for rich mixtures, the first exothermic step is mainly due to the reaction NO2 + H → NO + OH, but the second one is different since it results from the exothermic decomposition of NO into N2 and O2. For Φ=0.3 the measured detonation velocity in a tube of 52 mm internal diameter is very much smaller than the calculated value and the mean size of the cellular structure is very much larger than the value extrapolated from data obtained with mixtures of higher but close equivalence ratio. All these results show that the detonation, though self-sustained and steady, is ‘non-ideal’, i.e. it is supported only by a part of the available chemical energy, that provided mainly by the first exothermic step. To cite this article: D. Desbordes et al., C. R. Mecanique 332 (2004). 相似文献
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Christophe Matignon Daniel Desbordes Henri Noël Presles 《Comptes Rendus Mecanique》2006,334(10):605-610
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Detonation in gaseous nitromethane (NM) and mixed with O2 has been studied. Experiments were performed in a preheated steel tube at an initial temperatureT
0∼=390 K for different initial pressuresP
0 (1.7≥P
0≥5 10−2 bar). Different selfsustained detonation regimes were obtained, from multiheaded mode to spinning and galloping mode in marginal
conditions. These chemical systems were characterized by a specific detonation cellular structure very different from that
currently observed with classical gaseous C
n
H
m
/O2/N2 mixtures. All modes of detonation propagation in rich NM/O2 mixtures exhibit a double scale cellular structure. The pattern of this double scale structure is particularly clear in the
case of spinning mode.
An abridged version of this paper was presented at the 15th Int. Colloquium on the Dynamics of Explosions and Reactive Systems
at Boulder, Colorado, from July 30 to August 4, 1995 相似文献
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Detonation experiments in H2–NO2/N2O4–Ar mixtures (Equivalence ratio 1.2 and initial pressure lower than 0.1 MPa) confined in a tube of internal diameter 52 mm
reveal two propagation regimes depending on initial pressure: (1) a quasi-CJ regime is observed along with a double cellular
structure at high pressures; (2) at lower pressures, a low velocity detonation regime is observed with a single structure.
Transition between this two regimes happens when the spinning detonation of the larger cell vanishes. Each detonation regime
is characterized by velocity and pressure measurements and cellular structure records. Coherence between all experimental
data for each experiment leads in assumption that losses are responsible for the transition between one regime to another.
In a second part, we study such behaviour for a two-step mixture through numerical simulations using a global two-step chemical
kinetics and a simple losses model. Numerical simulations qualitatively agree with experiments. Both detonation regimes with
their own cellular structures are reproduced. 相似文献
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Boris Khasainov Henri-Noel Presles Daniel Desbordes Pietro Demontis Pierre Vidal 《Shock Waves》2005,14(3):187-192
An experimental study of the detonation diffraction from 26- and 52-mm inner diameter tubes to cones of various angles α in
stoichiometric acetylene/oxygen mixture allowed us to determine critical conditions for diffraction and to detail the mechanisms
involved. All soot-foil records show that critical transmission is due to super-detonation propagating transversally in shocked
gas before the decoupled flame front. However, at large cone angles (α > 40∘), super-detonation originates at the axis of the flow and propagates tangentially to the cone wall (this situation is close
to detonation transmission to a space and a half-space). At smaller angles (i.e. α < 40∘), on the opposite, super-detonation originates at the cone wall and propagates toward the axis. In addition the soot plates
often give some evidence that, during escape of detonation products from the tube, a Mach disk is formed at a distance of
about one tube diameter from the tube exit. Numerical two-dimensional simulations of detonation diffraction favorably agree
with the observations.
PACS 47.40.-x
This paper was based on work that was presented at the 19th Inter-national Colloquium on the Dynamics of Explosions and Reactive
Systems, Hakone, Japan, July 27 - August 1, 2003 相似文献
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Analysis of available data on dependence of the critical detonation diameter of various heterogeneous condensed explosives on mean size of grains and voids demonstrated that in many cases surprising
correlations between and the initial specific surface area of heterogeneous explosives exist, namely, or . The run distance to detonation in wedge test with sustained strong shock of constant amplitude also linearly correlates
with , i.e. .
At the same time, the shock sensitivity reversal effect is often observed when grain size of HE is reduced. Apart from that
Moulard (1989) found that detonation critical diameter of plastic bonded explosive with mono- and bimodal RDX grain size distribution
depends nonmonotonously on mean grain size.
Complicated dependence of shock sensitivity of heterogeneous explosives on their specific surface area can be explained based
on comparison of the critical hot spot size at given characteristic pressure behind shock wave with the mean heterogeneity size . At high characteristic pressure (relative to the critical ignition pressure) is small compared with and all specific surface area of heterogeneous explosive is available for the hot spot growth process in accordance with
the grain burn concept.
However, when characteristic pressure of shock wave decreases, increases and can become comparable with . In this case only relatively large potential hot spots with size can result in self-supported hot spot growth process and shock sensitivity is controlled by the specific surface area which
corresponds to only larger heterogeneities and can be significantly smaller than initial specific surface area.
Received 18 July 1996 / Accepted 6 November 1996 相似文献
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