Ⅱ型裂纹疲劳扩展中超载行为的研究

利用铝合金ＬＹ１２ＣＺ制十字型试样进行Ⅱ型裂纹的疲劳扩展试验，施加若干次短瞬的Ⅱ型超载。发现Ⅱ型裂纹的超载行为与Ⅰ型裂纹的不同，裂纹的扩展速率可几倍于未超载时相同应力强度因子幅度下的扩展速率；而且超载后的短瞬期间，裂纹在塑性区内仍保持较快的速率扩展。试验研究表明：Ⅱ型超载和Ⅰ型超载也许分别受不同的机制控制；它更类似于Ⅲ型超载。     

粒径可控纳米LiFePO4/C的制备及其电化学性能研究

LiFePO4电极的倍率特性与材料的粒度和电子导电性有很大关系.采用共沉淀方法,调控预处理温度,将3种不同尺寸的FePO4前驱体通过表面修饰对-羟基苯甲酸的聚合物,可合成不同尺度的LiFePO4/C材料,分别为80 nm、200nm和1μm.纳米尺度LiFePO4-a/C电极,30C放电比容量达到了100 mAh·g-1,而微米级LiFePO4-c/C电极放电比容量仅为54mAh·g-1.均一碳包覆的LiFePO4/C电极表现出强抗氧化性,不仅提高其导电性,还可防止材料氧化.     

Preparation and characterization of thick cubic boron nitride films

Cubic boron nitride （c-BN） films are prepared by the radio frequency magnetron sputtering technique. The stresses and crystallinities of the films are estimated by the Fourier transform infrared spectroscopy of c-BN samples, including the peak shifts and varieties of full widths at half maximum. The effects of the B-C-N interlayer and the two-stage deposition method on the c-BN films are investigated. Then the thick and stable c-BN films are prepared by a combination of the two methods. The properties of the interlayer and film are also characterized.