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1.
L. I. Bryukvina E. A. Ermolaeva S. N. Pidgurskiĭ L. F. Suvorova V. M. Khulugurov 《Physics of the Solid State》2006,48(1):68-72
It was detected for the first time that films consisting of a transition-metal-based structure form (via thermal diffusion
of intracrystalline impurities) on the surface of alkali-halide (LiF, NaF) crystals activated by transition metals Co, Ni,
or Mn. The thickness, density, and composition of the films are shown to be different, depending on the heat treatment conditions.
The crystals were annealed at temperatures varying from 473 to 1073 K in vacuum and air. The surface structures forming upon
annealing in vacuum exhibit magnetic properties. The films were studied by optical, x-ray fluorescence, and electron spectroscopy
to reveal the mechanisms of transition-metal film formation during thermal annealing. 相似文献
2.
A. N. Titov O. N. Suvorova S. Yu. Ketkov S. G. Titova A. I. Merentsov 《Physics of the Solid State》2006,48(8):1466-1471
Single crystals and polycrystals of titanium diselenide TiSe2 intercalated with ferrocene Fe(η5-C5H5)2 and cobaltocene Co(η5-C5H5)2 are synthesized. The magnetic susceptibility and electrical resistivity of the intercalation compounds are measured. The results obtained demonstrate that the intercalation brings about the formation of an impurity band with a temperature-dependent width. 相似文献
3.
Suvorova V. V. Panicheva L. P. Mamontova Yu. V. Belyatskii M. K. 《Russian Journal of Organic Chemistry》2003,39(7):957-962
Selective dehydrobromination of 1,2-dibromo-1-phenylethane to -bromostyrene was effected under conditions of phase-transfer catalysis in systems containing KOH, toluene, and tetraalkylammonium bromides. The high selectivity of the catalytic systems originates from stabilization by lipophilic cation of the phase-transfer catalyst of a E1cb-like transition state in the E2 mechanism. In the presence of a catalytic amount of lipophilic alcohols, phenylacetylene was obtained. Substrate activation by alcohol molecules is explained by enhancement of the acceptor power of halogen atoms due to solvation and by increased mobility of hydrogen atoms. 相似文献
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6.
B. A. Tertov Yu. G. Bogachev Yu. V. Koshchienko G. M. Suvorova E. B. Tsupak N. K. Chub S. F. Breus 《Chemistry of Heterocyclic Compounds》1986,22(8):868-872
Organolithium and organosodium compounds of 1,2-dimethyl-, 1-methyl-2-ethyl-, 1-methyl-2-propyl-, and 1-phenyl-2-methylbenzimidazole, containing the metal in the alkyl group at position C(2), were obtained by metallation. It was found that metallation can be complicated by the addition of the metalling reagent at the C=N bond of the heterocycle. It was shown that the obtained organometallic compounds can be used for the synthesis of various derivatives of benzimidazole.The calculation was performed with the standard bond lengths. A planar model was used for the carbanion.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1073–1077, August, 1986. 相似文献
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8.
EI Rodriguez Martinez CI Barriga-Paulino MI Zapata CC Chinchilla AM López-Jiménez CM Gómez 《BMC neuroscience》2012,13(1):104-23
ABSTRACT: BACKGROUND: The peri-adolescent period is a crucial developmental moment of transition from childhood to emergent adulthood. The present report analyses the differences in Power Spectrum (PS) of the Electroencephalogram (EEG) between late childhood (24 children between 8 and 13 years old) and young adulthood (24 young adults between 18 and 23 years old). RESULTS: The narrow band analysis of the Electroencephalogram was computed in the frequency range of 0--20 Hz. The analysis of mean and variance suggested that six frequency ranges presented a different rate of maturation at these ages, namely: low delta, delta-theta, low alpha, high alpha, low beta and high beta. For most of these bands the maturation seems to occur later in anterior sites than posterior sites. Correlational analysis showed a lower pattern of correlation between different frequencies in children than in young adults, suggesting a certain asynchrony in the maturation of different rhythms. The topographical analysis revealed similar topographies of the different rhythms in children and young adults. Principal Component Analysis (PCA) demonstrated the same internal structure for the Electroencephalogram of both age groups. Principal Component Analysis allowed to separate four subcomponents in the alpha range. All these subcomponents peaked at a lower frequency in children than in young adults. CONCLUSIONS: The present approaches complement and solve some of the incertitudes when the classical brain broad rhythm analysis is applied. Children have a higher absolute power than young adults for frequency ranges between 0-20 Hz, the correlation of Power Spectrum (PS) with age and the variance age comparison showed that there are six ranges of frequencies that can distinguish the level of EEG maturation in children and adults. The establishment of maturational order of different frequencies and its possible maturational interdependence would require a complete series including all the different ages. 相似文献
9.
Tamer Shoeib Junfang Zhao Houssain EI Aribi Alan C. Hopkinson K. W. Michael Siu 《Journal of the American Society for Mass Spectrometry》2013,24(1):38-48
The fragmentations of [AA + M]+ complexes, where AA = Phe, Tyr, Trp, or His, and M is a monovalent metal (Li, Na, or Ag), have been exhaustively studied through collision-induced dissociation (CID) and through deuterium labeling. Dissociations of the Li- and Ag-containing complexes gave a large number of fragment ions; by contrast, the sodium/amino acid complexes have lower binding energies, and dissociation resulted in much simpler spectra, with loss of the entire ligand dominating. Unambiguous assignments of these fragment ions were made and formation mechanisms are proposed. Of particular interest are fragmentations in which the charge was retained on the organic fragment and the metal was lost, either as a metal hydride (AgH) or hydroxide (LiOH) or as the silver atom (Ag?). Caption for Graphical Abstract
CID products of Li+, Na+, and Ag+ complexes of Phe, Tyr, Trp, and His are reported and mechanisms by which they are formed are proposed. 相似文献
10.
A. D. Avrorin A. V. Avrorin V. M. Aynutdinov R. Bannash I. A. Belolaptikov D. Yu. Bogorodsky V. B. Brudanin N. M. Budnev A. R. Gafarov O. N. Gaponenko K. V. Golubkov T. I. Gress I. A. Danilchenko Zh. -A. M. Dzhilkibaev G. V. Domogatsky A. A. Doroshenko A. N. Dyachok V. A. Zhukov A. V. Zagorodnikov V. L. Zurbanov K. G. Kebkal O. G. Kebkal A. V. Kozhin K. V. Konischev A. V. Korobchenko F. K. Koshel A. P. Koshechkin V. F. Kulepov D. A. Kuleshov V. I. Ljashuk M. B. Milenin R. A. Mirgazov E. R. Osipova A. I. Panfilov L. V. Pan’kov E. N. Pliskovsky M. I. Rozanov E. V. Rjabov A. V. Skurihin A. A. Smagina O. V. Suvorova V. A. Tabolenko B. A. Tarashansky S. V. Fialkovsky Z. Honz B. A. Shaybonov A. A. Sheifler M. D. Shelepov S. A. Yakovlev 《Physics of Particles and Nuclei Letters》2016,13(6):737-746
In April 2015, the first cluster of Baikal-GVD was deployed in Lake Baikal and put into operation. It comprises eight strings. Each string consists of 24 optical modules. An optical module is a detection element of Baikal-GVD; it includes a Hamamatsu R7081-100 photomultiplier tube with a high quantum sensitivity. We describe the design of the optical module, the front-end electronics, and the laboratory characterization and calibration. 相似文献