全文获取类型
收费全文 | 2475篇 |
免费 | 77篇 |
国内免费 | 11篇 |
专业分类
化学 | 1826篇 |
晶体学 | 23篇 |
力学 | 39篇 |
数学 | 88篇 |
物理学 | 587篇 |
出版年
2023年 | 21篇 |
2022年 | 10篇 |
2021年 | 20篇 |
2020年 | 30篇 |
2019年 | 32篇 |
2018年 | 31篇 |
2017年 | 15篇 |
2016年 | 42篇 |
2015年 | 46篇 |
2014年 | 60篇 |
2013年 | 104篇 |
2012年 | 146篇 |
2011年 | 144篇 |
2010年 | 89篇 |
2009年 | 90篇 |
2008年 | 127篇 |
2007年 | 177篇 |
2006年 | 152篇 |
2005年 | 127篇 |
2004年 | 115篇 |
2003年 | 98篇 |
2002年 | 97篇 |
2001年 | 63篇 |
2000年 | 35篇 |
1999年 | 23篇 |
1998年 | 23篇 |
1997年 | 23篇 |
1996年 | 29篇 |
1995年 | 20篇 |
1994年 | 24篇 |
1993年 | 26篇 |
1992年 | 36篇 |
1991年 | 29篇 |
1990年 | 36篇 |
1989年 | 26篇 |
1988年 | 31篇 |
1987年 | 36篇 |
1986年 | 34篇 |
1985年 | 42篇 |
1984年 | 36篇 |
1983年 | 17篇 |
1982年 | 28篇 |
1981年 | 14篇 |
1980年 | 14篇 |
1979年 | 23篇 |
1978年 | 18篇 |
1977年 | 18篇 |
1976年 | 9篇 |
1975年 | 14篇 |
1974年 | 23篇 |
排序方式: 共有2563条查询结果,搜索用时 109 毫秒
1.
Dr. Nozomi Mihara Dr. Yasuyuki Yamada Dr. Hikaru Takaya Prof. Yasutaka Kitagawa Dr. Kazunobu Igawa Prof. Katsuhiko Tomooka Prof. Hiroshi Fujii Prof. Kentaro Tanaka 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(13):3369-3375
Development of supramolecular methods to further activate a highly reactive intermediate is a fascinating strategy to create novel potent catalysts for activation of inert chemicals. Herein, a supramolecular approach to enhance the oxidizing ability of a high-valent oxo species of a nitrido-bridged iron porphyrinoid dimer that is a known potent molecular catalyst for light alkane oxidation is reported. For this purpose, a nitrido-bridged dinuclear iron complex of porphyrin-phthalocyanine heterodimer 3 5+, which is connected through a fourfold rotaxane, was prepared. Heterodimer 3 5+ catalyzed ethane oxidation in the presence of H2O2 at a relatively low temperature. The site-selective complexation of 3 5+ with an additional anionic porphyrin (TPPS4−) through π–π stacking and electrostatic interactions afforded a stable 1:1 complex. It was demonstrated that the supramolecular post-synthetic modification of 3 5+ enhances its catalytic activity efficiently. Moreover, supramolecular conjugates achieved higher catalytic ethane oxidation activity than nitrido-bridged iron phthalocyanine dimer, which is the most potent iron-oxo-based molecular catalyst for light-alkane oxidation reported so far. Electrochemical measurements proved that the electronic perturbation from TPPS4− to 3 5+ enhanced the catalytic activity. 相似文献
2.
3.
Kosuke Morita Kouji Morimoto Daiya Kaji Yu Liang Zhao Atsushi Yoshida Toshimi Suda Akira Yoneda Tetsuya Ohnishi Hiromitsu Haba Eiji Ideguchi Hu Shan Xu Tao Zheng Hisaaki Kudo Keisuke Sueki Kenji Katori Isao Tanihata 《Acta Physica Hungarica A》2004,19(1-2):53-60
A gas-filled type of recoil separator for heavy element research was installed at an experimental hall of RIKEN Linear Accelerator facility to realize getting higher intensity of primary beam and long beam time. Performance of the separator was studied using target recoils and various nuclear reactions. The results show the high performance of the separator for heave element research. As an application of the GARIS, production and identification of an isotope of the 110th element 271[110] have been performed using the 208Pb(64Ni,1n)271[110] reaction. Three decay chains coincide well both in decay times and energies with the ones reported by the group of SHIP experiment at GSI, Germany. Our results provide a confirmation of the synthesis of an isotope 271[110] of element 110. 相似文献
4.
Akihide Itoh Taisuke Nagasawa Yanbei Zhu Kyue-Hyung Lee Eiji Fujimori Hiroki Haraguchi 《Analytical sciences》2004,20(1):29-36
In order to elucidate the distributions of the elements among the particulate and dissolved fractions in pond water, major-to-ultratrace elements in different sizes of particles as well as in the filtrate passed through the 0.05 microm filter were determined by inductively coupled plasma atomic emission spectrometry (ICP-AES) and inductively coupled plasma mass spectrometry (ICP-MS). The different sizes of particle samples (ca. 100-300 microg each) were collected on the membrane filters with pore sizes of 10, 3.0, 1.2, 0.4, 0.2 and 0.05 microm, respectively, by sequential fractionation. As a result, about 40 elements in different sizes of particles could be determined by ICP-AES and ICP-MS, after acid digestion using HNO3/HF/HClO4. Then, the fractional distribution factors of major-to-ultratrace elements among the particulate and dissolved fractions were estimated from the analytical results. The total contents of Al, Fe, Ti, REEs (rare earth elements), Bi, Pb and Ag in the particulate fractions (larger than 0.05 microm) were more than 80-90%, while those of Ca, Sr, Cs, W, Ba, Mn and Co in the dissolved fraction, which corresponded to the filtrate passed through the 0.05 microm membrane filter, were more than 80%. It was further found that the fractional distributions of Cu and Zn in the dissolved fraction were ca. 50%. In addition, the enrichment factors (EFs) of the elements in the particulate fractions with particle sizes of 3.0-10 microm and 0.05-0.2 microm were estimated to elucidate their geochemical characteristics in natural water. 相似文献
5.
Jun Fujii Giancarlo Panaccione Giorgio Rossi Giancarlo Trimarchi 《Surface science》2006,600(18):3884-3887
Bulk carbon impurities segregate at the Fe(1 0 0) surface and, upon thermal annealing, can form metastable surface phases with local and long range order and peculiar electronic properties. We present a surface science study of C-segregated Fe(1 0 0) with scanning tunneling microscopy, angle resolved photoemission, and ab initio calculations of the surface structure and electron states. In particular the c(3√2 × √2) structure, observed for 0.67 atomic layers of C segregated at the iron surface, is found to be due to self-organized carbon stripes made of zig-zag chains. The strong hybridization between C and Fe was observed in ARPES spectra. 相似文献
6.
Taking into account pseudoscalar as well as scalar condensates, we reexamine the chiral restoration path on the chiral manifold. We shall see both condensates coherently produce a density wave at a certain density, which delays chiral restoration as density or temperature is increased. 相似文献
7.
Eiji Yanagida 《Journal of Dynamics and Differential Equations》2007,19(4):895-914
This paper is concerned with the irregular behavior of solutions for Fisher’s equation when initial data do not decay in a
regular way at the spatial infinity. In the one-dimensional case, we show the existence of a solution whose profile and average
speed are not convergent. In the higher-dimensional case, we show the existence of expanding fronts with arbitrarily prescribed
profiles. We also show the existence of irregularly expanding fronts whose profile varies in time. Proofs are based on some
estimate of the difference of two distinct solutions and a comparison technique.
Dedicated to Professor Pavol Brunovsky on his 70th birthday. 相似文献
8.
The mucosal upheaval (MU), where the mucosal wave starts and propagates upward, appears only when the vocal fold vibrates. The location of the MU histologically and the effect of changes in mean air flow rate (MFR) and vocal fold length on occurrence of the MU were studied in twelve excised canine larynges. The lower surface of the vocal fold was marked to serve as a landmark for subsequent study. Cricothyroid approximation was performed to lengthen the vocal fold. After taking high-speed pictures or recording stroboscopic images from the tracheal side, a small cut wound was made at the mark. This wound served to compare the position of the MU with the histologically identified location of the mark. The larynx was then sectioned in the frontal plane. Before lengthening the vocal fold, the MU occurred on the area where the lamina propria became thinner and where the muscular layer neared the epithelial layer. After lengthening the vocal fold, the MU actually shifted medially compared with its original position. The subglottic area surrounded by the bilateral MUs became longer and thinner. Whether or not complete glottal closure during a vibratory cycle was achieved did not alter these findings. In contrast, with a fixed vocal fold length the MU appeared more laterally as MFR increased, but, based on the relation with the mark, its location on the vocal fold did not change from its original position before increase of MFR. 相似文献
9.
The potential of the internal rotation of the methyl group was determined for o-, m-, and p-fluorotoluene cations by pulsed field ionization spectroscopy. The potential of the internal rotational motion was also surveyed for other toluene derivative cations. It was found that the barrier height generally increases by ionization. The increase in the barrier height has been discussed in connection with the reduction of the internal rotational constant B by ionization. The geometrical distortion of the methyl group during the internal rotation has been suggested. 相似文献
10.