Arene sulfenylation by arenesulfenamides and arenesulfenylacetates

Two systems for arene sulfenylation were investigated: arenesulfenamides in the presence of SO₃ and sulfenylacetate complexes with AlBr₃. A preference for the second reagent was demonstrated for sulfenylation of substrates bearing donor substituitents.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 324–326, February, 1995.     

Diene synthesis with 5-chloro-1-alkyl-2-pyridones

For the first time, we describe the diene synthesis of 5-chloro-1-alkyl-2-pyridones with N-phenylmaleic imide and have shown that the reaction proceeds nonstereoselectively with formation of a mixture of [4+2]cycloadducts with anendo andexo configuration. We have obtained 1,4-cycloadducts with 4-phenyl-1,2,4-triazoline-3,5-dione.M. V. Lomonosov Moscow State University, Moscow 119899. Translated from Khimiya Geterotsklicheskikh Soedinenii, No. 5, pp. 687–691, May, 1997.     

Dipyrrolo[1,2-a;2':,1'-c]pyrazines. 7. Electrophilic Substitution of Dipyrrolo[1,2-a;2',1'-c]pyrazines and 5,6-Dihydrodipyrrolo[1,2-a;2',1'-c]pyrazines via Formylation of Dipyrrolo[1,2-a;2':,1'-c]pyrazines

A series of previously unreported aldehydes has been prepared by the formylation reaction of dipyrrolo[1,2-a;2':,1'-c]pyrazines and their 5,6-dihydro analogs by DMF and phosphorus oxychloride.     

Arylselenenation of conjugated dienes by arylselenenamides in the presence of phosphorus(V) oxyhalides

Arylselenenation of conjugated and non-conjugated dienes by arylselenenamides in the presence of phosphorus(V) oxyhalides has been studied. Reactions with conjugated dienes lead to 1,4-adducts whilst only addition to double bonds takes place in reactions with non-conjugated dienes.     

2-isoxazolines from arylcyclopropanes: I. Monoarylcyclopropanes in a reaction with nitrosyl chloride activated by sulfur(IV) oxide

A reaction of monoarylcyclopropanes with nitrosyl chloride activated by sulfur (IV) oxide gave in good yields 5-arylisoxazolines. The reaction is of electrophilic character. A scheme of the reaction was suggested.     

Dipyrrolo[1,2-a;2',1'-c]pyrazines. 6. Electrophilic Substitution in a Series of Dipyrrolo[1,2-a;2',1'-c]pyrazine and 5,6-Dihydrodipyrrolo[1,2-a;2',1'-c]pyrazine Derivatives. Phosphorylation of Dipyrrolo[1,2-a;2',1'-c]pyrazines

We have studied the behavior of asymmetrically substituted dipyrrolo[1,2-a;2',1'-c]pyrazines and their 5,6-dihydro analogs under phosphorylation reaction conditions.     

Reactions of 2-aminothiophenol with pyridineand imidazolecarboxaldehydes

Russian Chemical Bulletin - Reflux of imidazole-2-carboxaldehyde, 1-methylimidazole-2-carboxaldehyde, imidazole4-carboxaldehyde, or 5-bromopyridine-2-carboxaldehyde with 2-aminothiophenol in...     

Structure of 3,7-Diazabicyclo[3.3.1]nonane Complexes as the Basis of Creating New Metallocyclic Supramolecular Ensembles

The molecular and crystal structure of the complex of cupric bromide with 1,5-diphenyl-3,7-dimethyl-3,7-diazabicyclo[3.3.1]nonan-9-ones was studied. The geometry of the complexes of bispydines with cupric halides was shown to depend on the substituent at the nitrogen atom.