Sensitive fluorescence probes for dihydrogen phosphonate anion based on calix[4]arene bearing naphthol-hydrazone groups

t-Butyl and t-pentylcalix[4]arenes bearing two 2-naphthol-1-hydrazone groups at the lower rim were synthesized,and showed excited-state intermolecular proton transfer fluorescent signal with basic anion.They are more sensitive to dihydrogen phosphate anion than to fluoride anion,although the latter has stronger basicity.Compared with t-butylcalix[4]arene bearing two 2-naphthol-1-hydrazone groups,t-pentylcalix[4]arenes derivative has a larger fluorescent difference between dihydrogen phosphate and fluoride a...     

Effects of surfactants on enzyme-containing reversed micellar system

With the development of colloid interface and enzyme technologies,enzyme-containing reversed micellar system has been receiving much attention in bioseparation and bioconversion. Because of its high efficiency,it has brought new opportunities for the development of molecular biotechnology. Reversed micelles represent nano-sized aqueous droplets stabilized by surfactant amphiphiles inside the bulk organic solvents. The entrapped enzymes have enhanced activities under those conditions as suited in the lipid b...     

甲醇浓度对被动式自呼吸直接甲醇燃料电池性能的影响

依据单电池测试结果和甲醇传质理论考察了甲醇溶液的浓度对被动式自呼吸直接甲醇燃料电池（DMFC）性能的影响.研究结果表明,电池的法拉第效率和能量转化效率会随着浓度的增大而降低,采用4mol/L的甲醇溶液实现了最大的放电功率13.9mW/cm^2,并能在60mA下稳定放电长达20h.这取决于电池运行过程中电极内部的甲醇传质和甲醇透过的共同作用.     

The first pulsar discovered by FAST

<正>To assist with the commissioning [1] of the Five-hundredmeter Aperture Spherical radio Telescope (FAST), we performed a pulsar search, with the primary goal of developing and testing the pulsar data acquisition and processing pipelines. We tested and used three pipelines, two (P1 and P2 hereafter) searched for the periodic signature of pulsars     

国内外液化天然气输运容器发展状态

液化天然气输运容器包括罐箱、罐车和车载储气瓶,普遍采用高真空多层绝热方式是国际发展趋势,其合理应用需要多项关键技术.由于产品种类型号相对较少,适合批量化生产以适应液化天然气工业的迅猛发展.液化天燃气输运容器产品发展趋势和技术发展趋势可为我国低温储运容器生产厂家提供一定的参考.     

Isotope effect of the phonons mean free path in graphene by micro-Raman measurement

The isotope labeled graphene was synthesized in the concentration of ¹³C carbon atom in 1%, 25%, 50%, 75% and 99%. The isotope effect on the phonon behavior in graphene was investigated based on the micro-Raman analysis of ¹³C isotope labeled graphene samples. We found that the phonon scattering is affected by the isotopic carbon atom as a point defect. Based on the experiment results, the Klemens-Callaway model and uncertainty principle were used to obtain the mean free path of the G and D phonons. The results agree with the thermal conductivity measurement by non-contact optical method and with other theoretical calculations.     

First-principles study of lithium intercalated bilayer graphene

Lithium intercalated bilayer graphene has been investigated using first-principles density functional theory calculations. Results show that there exist AB and AA stacking sequences for bilayer graphene in which the latter is more favorable for the Li storage and the former will evolve into the latter with the intercalation of Li ions. The relationship between the interlayer distance of two graphene sheets and the intercalated capacity of Li ions is discussed. It is found that structural defect is identified to store Li ions more favorably than pristine bilayer graphene and an isolated C atom vacancy in bilayer graphene can capture three Li ions between two graphene sheets.     

Some interesting C<Emphasis Type="Italic">H</Emphasis><Subscript>2</Subscript>C<Emphasis Type="Italic">H</Emphasis><Subscript>3</Subscript> spin systems in several diethyl malonate indene derivatives studied with NMR and molecular modeling

While studying the electrophilic cyclization of acetylenic malonates in synthesizing malonate indene derivatives with high regio and stereo-selectivity, we found that the CH₂ and CH₃ protons of two COOCH₂CH₃ groups in some diethyl malonate indene derivatives showed very interesting spin-spin coupling and signal multiplicity. To explain those phenomena, we synthesized several diethyl malonate indene derivatives, and then used ¹H NMR spectra and molecular modeling to investigate the CH ₂CH ₃ spin system of these two COOCH₂CH₃ groups in detail. The results showed that the spin systems of CH ₃CH ₂ of the two COOCH₂CH₃ groups in those compounds may exist in different froms (AMX ₃, ABX ₃ and A ₂ X ₃), and the effect of the aromatic ring induced by the phenyl group at the end of the triple bond is the main reason responsible for those phenomena.     

Synthesis and biological evaluation of ~(99m)Tc-HEDTA/HYNIC-MPP4 complex for 5-HT1A receptor imaging

5-HT1A receptor is associated with a variety of pathophysiology of neuropsychiatric disorders. Accordingly, we have synthesized a new 5-HT1A receptor ligand (HYNIC-MPP4) and labeled it with 99mTc using N-(2-hydroxyethyl)ethylenediaminetriacetic acid (HEDTA) as coligand. 99mTc-HEDTA/HYNIC-MPP4 was prepared under pH 6 at room temperature. Biodistribution of 99mTc-HEDTA/HYNIC-MPP4 in normal mice showed that this complex had moderate brain uptake (0.60% ID·g-1 at 2 min p.i.) and good retention. The hippocampus ...