CD生产函数与CES生产函数的几点比较

本文对ＣＤ生产函数与ＣＥＳ生产函数进行了几个方面的比较分析，以便于实际运用中的选择。     

基团的电子效应与单取代苯对位^1H,^13C的化学位移

基团的电子效应与单取代苯对位１Ｈ、１３Ｃ的化学位移＊韩长日冯娇杨钟照平（海南师范学院化学系海口５７１１５８）关键词１Ｈ的化学位移１３Ｃ的化学位移基团电负性共轭效应引言在１Ｈ、１３Ｃ核磁共振谱中，化学位移值的大小主要取决于屏蔽作用的大小，而屏蔽作用的大...     

Synthesis, crystal structure and magnetic property of a new 1D molecular material [1-(4′-chlorobenzyl)-4-aminopyridinium](+) bis(maleonitriledithiolato)nickel(-)

A new ion-pair complex, [1-(4′-chlorobenzyl)-4-aminopyridinium](+)bis(maleonitrile-dithiolato)nickel(−),[ClbzPyNH₂][Ni(mnt)₂] (1), has been prepared and characterized. X-ray single crystal structure conforms that the Ni(mnt)₂⁻ anions and [ClbzPyNH₂]⁺ cations of 1 form completely segregated uniform stacking columns with the Ni?Ni distance 3.944 Å in the Ni(mnt)₂⁻ stacking column. The temperature dependence of the magnetic susceptibility reveals that 1 undergoes a magnetic transition, and exhibits ferromagnetic interaction in the high-temperature phase and spin gap system in the low-temperature phase.     

羟基磷灰石/聚乙烯醇/壳聚糖水凝胶在模拟体液中的力学性能

从仿生学角度出发,将自制的人工角膜支架材料羟基磷灰石/聚乙烯醇/壳聚糖(n-HA/PVA/CS)浸泡在模拟体液中,对材料的含水率及力学性能进行了测试,并利用扫描电镜、X射线衍射仪、电感耦合等离子体原子发射光谱仪及热重分析仪研究了材料在模拟体液中的形貌、晶体结构、元素组成及热稳定性.结果表明,在模拟体液中,n-HA/PVA/CS复合水凝胶的含水率为80%~86%,具有较高的拉伸强度,能承受正常眼压,且热稳定性较好.在浸泡后期,n-HA/CS/PVA复合材料对Ca2+的吸附和释放达到动态平衡;而其表面含有微量的纳米羟基磷灰石沉积,有利于纤维细胞的长入.     

Growth of Cu2S ultrathin nanowires in a binary surfactant solvent

We demonstrate a facile solution-phase method for the synthesis of single-crystal, high aspect ratio, and ultrathin nanowires of hexagonal-phase Cu2S by thermal decomposition of CuS2CNEt2 in a mixed surfactant solvent of dodecanethiol and oleic acid at 160 degrees C. Cu2S nanowires can be controllably synthesized with a diameter as thin as 1.7 nm and length up to tens of micrometers; they are usually aligned in the form of bundles with a thickness of hundreds of nanometers. Based on the experimental results, the formation mechanism of the ultrathin nanowires has been properly proposed. Some key synthetic parameters, which have a significant effect on the sizes and shapes of the products, have also been investigated in detail. UV-vis spectroscopy measurement reveals that the resultant ultrathin nanowires show a strong quantum size effect.     

A simple method to study hemihydrate phosphoric acid crystals growth process

A simple method is introduced in this study to better understand the growth process of hemihydrate phosphoric acid crystals. Using the proposed approach, large particles (>2 mm) can be produced reflecting the true state of the phosphoric acid particulate system. In contrast to previous studies, the principles for the crystallization curves were divided into two regions, based on the consumption of the phosphoric acid in solution. To maintain a constant crystal growth rate, a programmed cooling requirement was needed. In this reported study, the influence of a complexing agent (EDTA) on the crystallization process of phosphoric acid was also investigated. The results of this study showed that the presence of EDTA affected the metastable zone widths, as well as the kinetics of crystal growth.     

预烧温度对CaO-Li_2O-Sm_2O_3-TiO_2微波介质陶瓷介电性能的影响

用固相反应法制备了CaO-Li2O-Sm2O3-TiO2(CLST)微波介质陶瓷。通过改变预烧温度(1 000~1 200℃)研究其对CLST微波介质陶瓷介电性能的影响。研究过程中,对预烧粉体与烧结陶瓷进行XRD与SEM分析,对陶瓷的介电性能εr、Q、τf进行了测试。结果表明,预烧温度对CLST微波介质陶瓷介电性能有较大影响,在预烧温度1 150℃,烧结温度1 340℃时可获得较好的介电性能:εr=112,Q=845,τf=52×10-6/℃。     

在［311］面上直接生长GaAs／AlAs的量子线结构及其光学性质

本文介绍在分子束外延系统中，沿［３１１］面原位生长ＧａＡｓ／ＡＩＡｓ量子线结构的一种简单方法及其拉曼和发光特性。这一方法能克服目前纳米尺度光刻技术的困难，因此，是一种制备低维样品的有希望的方法。     

采场顶板稳定性动态预测及控制研究

运用人工神经网络技术,综合岩石介质条件、赋存环境条件以及工程因素3大方面的5个指标,即岩石单轴抗压强度、岩石质量指标、煤体强度、地下水状况、工作面月推进速度,建立了采场顶板稳定性动态预测模型。并以工作面月推进速度40m、60m、80m、100m分别预测了新集井田顶板稳定性分区。根据5个指标因素分析结果,对顶板稳定性影响程度由大到小排序为岩石质量指标、地下水状况、岩石单轴抗压强度、煤体强度、工作面月推进速度。     

非协调四结点平面等参位移元新列式方法

本文导出一种等参协调元位移函数的新的表示方法,在此基础上建立起了构造等参非协调元的新方法。作为实例,构造出两个可以给出单刚显式的四结点平面非协调新单元。