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An assumption that the most probable fragments of spontaneous low-energy fission inherit the quantum structure of initial nuclei is discussed. The energies Q of spontaneous decay into two fragments of nuclei with 2 < Z < 102 are estimated. The transition from negative to positive values of Q occurs near Z = 40. 相似文献
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Russian Physics Journal - 相似文献
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Zakharova L. Ya. Mirgorodskaya A. B. Zhil"tsova E. P. Kudryavtseva L. A. Konovalov A. I. 《Russian Chemical Bulletin》2004,53(7):1385-1401
The factors determining the catalytic effect of supramolecular systems on the nucleophilic substitution reactions are analyzed. The role of the structural and phase transitions of nanoaggregates in the catalytic mechanism are determined. The substrate specificity is shown for different structures of the supramolecular composition. 相似文献
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M. S. Vigdergauz N. V. Zakharova T. R. Bankovskaya F. Z. Safaeva 《Chromatographia》1978,11(6):316-320
Summary The regularities of changes of the polarity factors with the composition of mixed stationary phases are discussed. Values
of the polarity factors of active solids, partitioning liquids and also colloidal stationary phases are compared.
Part I: ref. [1]. 相似文献
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M. F. Budyka G. V. Zakharova O. D. Laukhina M. V. Alfimov 《Russian Chemical Bulletin》1992,41(9):1589-1596
The reaction of the photochemical synthesis of 2,7-dimethylacridine from di(para-tolyl)amine and bromoform was studied utilizing the method of microsecond impulse photolysis. The proposed new scheme for the formation of acridine assumes the recombination of the primary alkyl radicals at the nitrogen atom of the cation radical and/or the radical of the amine as the main route of the reaction. The data obtained indicate the common character of the nature of some intermediate stages and the structures of the intermediates in the photochemical formation of acridine compounds and triphenylmethane dyes from aromatic amines and halogenomethanes.Institute of Chemical Physics, Chernogolovka, Russian Academy of Sciences, 142432 Chernogolovka. Translated from Izvestiya Akademii Nauk, Seriya Khimicheskaya, No. 9, pp. 2044–2052, September, 1992. 相似文献
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M. V. Otdel’nova J. A. Zakharova E. M. Ivleva V. A. Kasaikin A. B. Zezin V. A. Kabanov 《Polymer Science Series A》2006,48(4):413-421
Supramolecular organization of complexes formed by poly(N-ethyl-4-vinylpyridinium bromide) and sodium dodecylsulfate in aqueous salt solutions was studied as a function of temperature and concentration of the complexes. It was shown that a decrease in temperature and/or concentration of complexes led to their reversible disaggregation into a molecularly dispersed (“unipolymer”) state. The ratio between the components in complex particles remained unchanged in this case. It was first found that phase separation in aqueous solutions of the complexes upon temperature elevation is accompanied by the precipitation of a nonstoichiometric complex. 相似文献