Electron transport properties of magnetic granular films

In this paper,we present a review of electron transport properties of magnetic granular films.Magnetic granular films are nanocomposite materials which consist of magnetic nanoparticles embedded in a nonmagnetic matrix or assembling of magnetic nanoparticles.According to the style of the nonmagnetic matrix,microstructure and the electron transport mechanism of the films,the magnetic granular films were divided into three groups:(1) magnetic metal-metal granular films,(2) magnetic metal-insulator granular films and(3) magnetic nanocluster-assembled granular films.Moreover,we also systematically review the magnetic properties,transport properties and magnetoresistance effect of size-monodispersed Co and Fe nanocluster-assembled films.     

制备方法对聚合物共混物相分离与黏弹弛豫的影响

采用小角激光光散射(SALLS)和动态流变方法研究了通过不同制备方法得到的等规聚丙烯/乙丙橡胶共混物(iPP/EPR)的相分离行为与黏弹行为.依据Cahn-Hilliard-Cook理论分析了熔融共混和溶液共混法制备的质量比为60/40和40/60的iPP/EPR共混物在恒温相分离早期的动力学,发现熔融共混iPP/EPR具有更大的表观扩散系数(Dapp).相分离中后期的实验结果表明,当相区尺寸增长程度相同时,熔融共混试样所用时间更短.表明熔融共混iPP/EPR试样具有更快的相分离速率.动态流变测试结果表明,与溶液共混相比,熔融共混试样具有更快的松弛速率.考虑到相分离过程实质是由高分子链的运动与扩散所控制,两种方法制备的iPP/EPR共混物相分离速率的差异应归于其分子链运动能力的不同.     

LIGAND EXCHANGE RESIN FOR AMINO ACID RECEMATES

Hydrophilic ligand exchange complexes with different chemical environment in chiral cavity were prepared and used as stationary phases of HPLC to resolve DL-amino acids.The mechanism and models of resolution were studied.