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1.
Yildiray Topcu Omer Andac Veysel T. Yilmaz William T. A. Harrison 《Journal of Molecular Structure》2002,610(1-3):99-103
The synthesis, molecular and crystal structure of bis(triethanolamine)Mn(II) saccharinate, [Mn(tea)2](sac)2 are reported. The configuration of the tea ligands results in an unusual example of coordination number seven for the Mn(II) ion. The two triethanolamine (tea) ligands coordinate to the Mn(II) ion forming a monocapped trigonal prism geometry, in which one of the tea ligands behaves as a tridentate ligand, while the other one acts as a tetradentate donor. The free and coordinated hydroxyl hydrogens of the tea ligands are involved in hydrogen bonding with the amine nitrogen, carbonyl and sulfonyl oxygens of the neighbouring sac ions to form a three-dimensional infinite network. A weak π–π interaction between the phenyl rings of the sac ions also occurs. 相似文献
2.
Yildiray Ozan 《Journal of Pure and Applied Algebra》2002,170(2-3)
Assume that X is a compact connected orientable nonsingular real algebraic variety with an algebraic free S1-action so that the quotient Y=X/S1 is also a real algebraic variety. If π : X→Y is the quotient map then the induced map between reduced algebraic K-groups, tensored with
,
is onto, where
,
denoting the ring of entire rational (regular) functions on the real algebraic variety X, extending partially the Bochnak–Kucharz result that
for any real algebraic variety X. As an application we will show that for a compact connected Lie group G
. 相似文献
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3.
Özgür Kabak Füsun Ülengin Emel Aktaş Şule Önsel Y. Ilker Topcu 《European Journal of Operational Research》2008
Efficient workforce scheduling has an important impact on store profit and customer service. Standard scheduling problems do not recognize the effect of staff availability on customer sales, however, even though the latter is an important factor in the retail sector. In this paper a two-stage model is proposed for this purpose. In the first stage a sales response model is used to specify hourly staff requirements. The output of the sales response model is then used as the input of a mixed integer optimization model, which finds an optimum assignment of the staff to daily shifts. Simulations are used to validate the sales response function, and to revise the model for more accurate results. In the simulations, customer arrivals and sales response error values are generated using appropriate distribution functions. As a case study the proposed model is applied to a Turkish retailer in the apparel sector. 相似文献
4.
In this study, the coupling kinetics of sulfanilamid diazonium salt with 1-naphthylamine has been studied by spectrophotometric method. In the experiments conducted at constant temperature, 25°C, pH has been varied between 2.2?3.4, reactant concentration between 1.25 × 10?5 ? 5 × 10?5 M, and ionic strength between 0.1?1 M. The reaction has been confirmed to be of second-order and rate constants and the dissociation constant of 1-naphthylamine have been calculated. © 1993 John Wiley & Sons, Inc. 相似文献
5.
Gamze Kökdil Gulaçti Topcu Mariusz Krawiec William H. Watson 《Journal of chemical crystallography》1998,28(7):517-519
The title compound C20H24O4 crystallizes in the orthorhombic space group P21212, with a = 10.245(3), b = 17.103(3), c = 9.879(3) Å, D
c = 1.260 g cm –3, and Z = 4. Nepetanudone is postulated to be formed by a [4+4] cycloaddition of two 5,9-dehydronepetalactone moieties to give an asymmetric dimer in which each pair of atoms is magnetically nonequivalent. The compound was recovered from extracts of Nepeta nuda ssp. albiflora. 相似文献
6.
H. Nazemiyeh F. Bahadori A. Delazar M. Ay G. Topcu U. Kolak L. Nahar A. A. Auzie S. D. Sarker 《Chemistry of Natural Compounds》2008,44(2):174-177
Reversed-phase preparative HPLC purification of the methanol (MeOH) extract of the aerial parts of Erica arborea resulted in the isolation of a new flavonoid glycoside, tricetin 4′-O-α-L-rhamnopyranoside, together with the known flavonoid, isorhamnetin 3-O-α-L-rhamnopyranoside. The structures of these compounds were determined by spectroscopic means. The antioxidant properties
of these compounds were assessed by the DPPH assay.
Published in Khimiya Prirodnykh Soedinenii, No. 2, pp. 138–140, March–April, 2008. 相似文献
7.
In this paper, we introduce conformable variational iteration method (C-VIM), conformable fractional reduced differential transform method (CFRDTM) and conformable homotopy analysis method (C-HAM). Between these methods, the C-VIM is introduced for the first time for fractional partial differential equations (FPDEs). These methods are new versions of well-known VIM, RDTM and HAM. In addition, above-mentioned techniques are based on new defined conformable fractional derivative to solve linear and non-linear conformable FPDEs. Firstly, we present some basic definitions and general algorithm for proposal methods to solve linear and non-linear FPDEs. Secondly, to understand better, the presented new methods are supported by some examples. Finally, the obtained results are illustrated by the aid of graphics and the tables. The applications show that these new techniques C-VIM, CFRDTM and C-HAM are extremely reliable and highly accurate and it provides a significant improvement in solving linear and non-linear FPDEs. 相似文献
8.
Cihan Topcu Gamze Lacin Vedat Yilmaz Fatih Coldur Bulent Caglar Osman Cubuk 《Analytical letters》2018,51(12):1890-1910
A novel copper(II)-selective electrode based on graphite oxide/imprinted polymer composite was developed for the electrochemical monitoring of copper(II) (Cu2+) ions. The electrode exhibited highly selective potentiometric response to Cu2+ with respect to common alkaline, alkaline earth and heavy metal cations. The composite composition studies indicated that the most suitable composite composition performing the most promising potentiometric properties was 20.0% ionophore (Cu2+-ion imprinted polymer), 10.0% paraffin oil, 5.0% multiwalled carbon nanotubes, and 65.0% graphite oxide. The fabricated electrode exhibited a linear response to Cu2+ over the concentration range of 1.0?×?10??6–1.0?×?10??1?M (correlation coefficient of 0.9998) with a sensitivity of 26.1?±?0.9?mV decade??1. The detection limit of the fabricated electrode was determined to be 4.0?×?10??7?M. The electrode worked well in the pH range of 4.0–8.0. The electrode had stable, reversible and fast potentiometric response (3?s). In addition, the electrode had a lifetime of more than 1 year. The analytical applications of the proposed electrode were performed using as an indicator electrode for the potentiometric titration of Cu2+ with ethylene diamine tetraacetic acid solution and for the determination of Cu2+ of spiked river, dam, and tap water samples. The obtained results for potentiometric titration and water samples were satisfactory. 相似文献
9.
Ulubelen A Oksüz S Topcu G Gören AC Bozok-Johansson C Celik C Kökdil G Voelter W 《Natural product letters》2001,15(5):307-314
From the roots of Saliva caespitosa Montbret and Aucher ex. Bentham a new diterpene 6beta-hydroxyisopimaric acid (1) has been isolated together with four known diterpenes, one new triterpenoid, 3-acetylvergatic acid (2), as well as five known triterpenoids, two steroids and a flavone. The structures of the compounds were established by spectroscopic analyses. The isolated compounds were tested against standard bacterial strains. Only the new diterpene, 6beta-hydroxyisopimaric acid has strong activity (MIC 9 microg/ml) against S. aureus and (MIC 18 microg/ml) against S. epidermidis as well as against B. subtilis (MIC 9 microg/ml). 相似文献
10.