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排序方式: 共有1261条查询结果,搜索用时 343 毫秒
1.
Numerical Algorithms - In this paper, we study a fast linearized numerical method for solving nonlinear time-fractional diffusion equations. A new weighted method is proposed to construct... 相似文献
2.
Weiyi Li Geng Leng Caiqin Li Yajing Lyu 《International journal of quantum chemistry》2020,120(8):e26150
The mechanisms of CO2 coupling with the propargylic alcohol using alkali carbonates M2CO3 (M = Li, Na, K, Cs) have been investigated by means of density functional theory calculations. The calculations reveal that the target product tetronic acid (TA) is yielded through two stages: (a) the formation of the α-alkylidene cyclic carbonate (αACC) intermediate via Cs2CO3-mediated carboxylative cyclization of the propargylic alcohol with CO2, and (b) the conversion of the αACC intermediate with Cs2CO3 to produce the cesium salt of the TA. Since the overall kinetic barriers for the two stages are comparable and affordable, the excellent chemoselectivity to the TA should be primarily originated from the high thermodynamic stability of the cesium salt of the TA. Moreover, relative to the TA, the possibility to yield the by-product acyclic carbonate can be excluded due to the both kinetics and thermodynamic inferiority. This result is different from the organic base-mediated reaction. Alternatively, our calculations predict that CsHCO3 together generated with the cesium salt of the TA might also be an available mediating reagent for the incorporation of CO2 with the propargylic alcohol. Compared to other alkali carbonates M2CO3 (M = Li, Na, K), the stronger basicity of Cs2CO3 and the lower ionic potential of cesium ion can raise the effective concentration of the αACC intermediate, and thus the conversion of the αACC intermediate into the cesium salt of the TA can be achieved with high yield. 相似文献
3.
The Burton-Miller boundary integral formulation is solved by a complex variable boundary element-free method (CVBEFM) for the boundary-only meshless analysis of acoustic problems with arbitrary wavenumbers. To regularize both strongly singular and hypersingular integrals and to avoid the computation of the solid angle and its normal derivative, a weakly singular Burton-Miller formulation is derived by considering the normal derivative of the solid angle and adopting the singularity subtraction procedures. To facilitate the implementation of the CVBEFM and the approximation of gradients of the boundary variables, a stabilized complex variable moving least-square approximation is selected in the meshless discretization procedure. The results show the accuracy and efficiency of the present CVBEFM and reveal that the method can produce satisfactory results for all wavenumbers, even for extremely large wavenumbers such as k = 10 000. 相似文献
4.
Paul阱内的压缩效应与量子跃迁 总被引:1,自引:1,他引:0
处理一个一维Paul阱系统中的压缩现象与量子跃迁现象,对于阱内的最强压缩态和共振跃迁(一种极不稳定状态)之间的关系作了阐述,并对利用压缩性质在阱内进行精密测量的可能性作了讨论 相似文献
5.
This paper is to investigate the approximate confidence limits of the reliability performances (such as failure rate, reliability function and average life) for a cold standby series system. The Bayesian approximate upper confidence limit of failure rate is obtained firstly, and next Bayesian approximate lower confidence limits for reliability function and average life are presented. The expressions for calculating Bayesian lower confidence limits of the reliability function and average life are also obtained, and an illustrative example is examined numerically by means of the Monte-Carlo simulation. Finally, the accuracy of confidence limits is discussed. 相似文献
6.
一类拟线性大系统的稳定性 总被引:1,自引:0,他引:1
彭晓林 《新疆大学学报(理工版)》1991,8(1):41-45
本文应用大系统的分解方法和一个推广的不等式,研究了一类拟线性大系统的稳定性问题,所得结果简洁、易于验证,且推导过程不复杂,最后给出了应用实例。 相似文献
7.
280mm×280mm口径单脉冲过程电光开关 总被引:4,自引:1,他引:3
用于高功率惯性约束聚变(ICF)激光驱动器的大口径电光开关均采用等离子体电极泡克耳斯盒。与传统的等离子体电极电光开关原理不同,单脉冲过程驱动电光开关没有独立的大电流等离子体发生单元,而只是通过具有较高幅值的正负开关脉冲完成对大口径电光开关的驱动。介绍单脉冲过程驱动等离子体电极泡克耳斯盒电光开关的设计,并建立280 mm×280 mm口径电光开关实验平台,利用连续激光器测试了电光开关特性,实验测得该电光开关中心处开关效率为99.3%,开关上升时间为90 ns。 相似文献
8.
Berry Frank J. Ren Xiaolin Gancedo J. Ramón Marco José F. 《Hyperfine Interactions》2004,156(1-4):335-340
Hyperfine Interactions - Perovskite-related phases of the type LaFe1?x Co x O3 (x=0 and 0.5) have been synthesised by milling techniques. The materials are of smaller particle size and more... 相似文献
9.
Further study of the viscoelastic phase separation of cyanate ester modified with poly(ether imide) 总被引:1,自引:0,他引:1
Guozhu Zhan Yingfeng Yu Xiaolin Tang Qingsheng Tao Shanjun Li 《Journal of Polymer Science.Polymer Physics》2006,44(3):517-523
In this study, the viscoelastic phase separation process was studied further by time‐resolved light scattering, differential scanning calorimetry, and scanning electron microscopy in the system of poly(ether imide)‐modified bisphenol‐A dicyanate. It was observed that the evolution time of phase structure and relaxation time of diffusion flow of the bisphenol‐A dicyanate were similar with the phase diagram of curing conversion versus content of PEI. The results suggested that the viscoelastic phase separation was affected by the curing conversion of the system at the onset point of phase separation. © 2005 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 517–523, 2006 相似文献
10.
本文报道综合利用长叶烯(1)催化异构化为异长叶烯(2)及合成系列香料的方法;通过氧化反应合成不同香型烯醇酯类等;Prins反应合成系列化合物。鉴定了10种香料化合物的香型。 相似文献