全文获取类型
收费全文 | 2919篇 |
免费 | 435篇 |
国内免费 | 378篇 |
专业分类
化学 | 2180篇 |
晶体学 | 25篇 |
力学 | 167篇 |
综合类 | 22篇 |
数学 | 373篇 |
物理学 | 965篇 |
出版年
2024年 | 10篇 |
2023年 | 70篇 |
2022年 | 71篇 |
2021年 | 108篇 |
2020年 | 135篇 |
2019年 | 104篇 |
2018年 | 105篇 |
2017年 | 90篇 |
2016年 | 145篇 |
2015年 | 137篇 |
2014年 | 146篇 |
2013年 | 196篇 |
2012年 | 239篇 |
2011年 | 256篇 |
2010年 | 164篇 |
2009年 | 181篇 |
2008年 | 177篇 |
2007年 | 158篇 |
2006年 | 170篇 |
2005年 | 133篇 |
2004年 | 98篇 |
2003年 | 72篇 |
2002年 | 71篇 |
2001年 | 77篇 |
2000年 | 61篇 |
1999年 | 71篇 |
1998年 | 47篇 |
1997年 | 56篇 |
1996年 | 62篇 |
1995年 | 38篇 |
1994年 | 26篇 |
1993年 | 31篇 |
1992年 | 31篇 |
1991年 | 31篇 |
1990年 | 29篇 |
1989年 | 12篇 |
1988年 | 13篇 |
1987年 | 13篇 |
1986年 | 10篇 |
1985年 | 8篇 |
1984年 | 9篇 |
1983年 | 8篇 |
1982年 | 10篇 |
1981年 | 5篇 |
1980年 | 4篇 |
1979年 | 6篇 |
1978年 | 3篇 |
1976年 | 4篇 |
1974年 | 3篇 |
1973年 | 5篇 |
排序方式: 共有3732条查询结果,搜索用时 15 毫秒
1.
2.
Dr. Jun Zeng Dr. Zhichao Wang Dr. Xin Huang Dr. Sabine S. Eckstein Prof. Dr. Xiaohui Lin Prof. Dr. Hailong Piao Prof. Dr. Cora Weigert Dr. Peiyuan Yin Prof. Dr. Rainer Lehmann Prof. Dr. Guowang Xu 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(21):5427-5432
Mass spectrometry (MS) driven metabolomics is a frequently used tool in various areas of life sciences; however, the analysis of polar metabolites is less commonly included. In general, metabolomic analyses lead to the detection of the total amount of all covered metabolites. This is currently a major limitation with respect to metabolites showing high turnover rates, but no changes in their concentration. Such metabolites and pathways could be crucial metabolic nodes (e.g., potential drug targets in cancer metabolism). A stable-isotope tracing capillary electrophoresis–mass spectrometry (CE-MS) metabolomic approach was developed to cover both polar metabolites and isotopologues in a non-targeted way. An in-house developed software enables high throughput processing of complex multidimensional data. The practicability is demonstrated analyzing [U-13C]-glucose exposed prostate cancer and non-cancer cells. This CE-MS-driven analytical strategy complements polar metabolite profiles through isotopologue labeling patterns, thereby improving not only the metabolomic coverage, but also the understanding of metabolism. 相似文献
3.
4.
Two novel 2′-hydroxychalcone derivatives (i.e., M1 and M2) are explored in this work. We mainly focus on investigating the effects of photoexcitation on hydrogen bonds and on the excited-state intramolecular proton transfer (ESIPT) process. On the basis of calculations of electrostatic potential surface and intramolecular interactions, we verify the formation of hydrogen bond O1 H2···O3 in both S0 and S1 states. Exploring the ultraviolet–visible spectra in the liquid phase, our simulated results reappear in the experimental phenomenon. Analyzing molecular geometry and infrared stretching vibrational spectra, we confirm O1 H2···O3 is strengthened for both M1 and M2 in the S1 state. We further confirm that charge redistribution facilitates ESIPT tendency. Constructing potential energy curves, we find the ultrafast ESIPT behavior for M1, which is because of the deficiency of side hydroxyl moiety comparing with M2. This work makes a reasonable affiliation of the ESIPT mechanism for M1 and M2. We wish this paper could facilitate understanding these two novel systems and promote their applications. 相似文献
5.
温度/应变/扭曲三参量同时测量低成本传感系统 总被引:9,自引:3,他引:6
提出了一种利用布喇格光纤光栅反射光作信号源、高频CO2激光脉冲写入的长周期光纤光栅和超周期光纤光栅作传感器实现温度、应变和扭曲同时测量的全光栅型低成本强度解调传感方案.文中利用长周期光纤光栅边缘滤波效应实现了温度、应变和扭曲传感信号的实时解调.实验结果表明,其温度和应变的测量灵敏度分别为-0.211 dB/℃和-0.012 dB/10με;而扭曲率的测量灵敏度为0.4394 dB/(rad·m-1),是该法写入普通LPFG的4倍以上. 相似文献
6.
An experimental method for determining the real-time depth of laser-drilled holes is presented. The proposed method involves
detecting the laser-induced optoacoustic waves generated during the interaction of the laser beam with the material. Our optodynamic
study involved measuring the propagation times of these waves as they traveled through the material and analyzing their temporal
behavior during the drilling process. The experimental observations revealed an exponential relationship between the propagation
time of the longitudinal stress wave and the number of consecutive laser pulses.
Received: 25 October 2001 / Accepted: 27 October 2001 / Published online: 20 December 2001 相似文献
7.
Xiaohui Yang Xiaoying Sun Jiajia Shao Yunhang Liu Xinling Wang 《Journal of Polymer Science.Polymer Physics》2004,42(22):4195-4198
A series of polymer electrolytes based on multiarm polymers and lithium salt complexes were characterized by Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), and impedance measurement. The relationships of conductivity with salt concentration, temperature, and arm numbers are discussed. It is suggested that the star polymer has a higher solvency and ion transfer ability on lithium salts than on linear polymers. The conductivity maximum appeared at a higher salt concentration ([EO]/[Li] = 4). Impedance measurement suggested that the optimum conductivity was 2 × 10?4 s · cm?1. The conductivity increased with temperature and the dependence of ionic conductivity on temperature fits the Arrhenius equation. Among the studied systems, the star polymer with a five arm number performs better than other structures. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 4195–4198, 2004 相似文献
8.
一类具有非局部反应扩散方程的奇摄动问题 总被引:7,自引:0,他引:7
本文讨论一类具非局部反应扩散方程的奇摄动初始边值问题,利用迭代法及微分不等式,研究了初始边值问题的存在唯一及其渐近性态。 相似文献
9.
封闭圆内开缝圆自然对流换热的振荡特性 总被引:1,自引:0,他引:1
本文通过数值计算探讨了封闭圆内开缝圆自然对流换热的振荡特性。数值计算以整个圆为计算区域,采用了非稳态的数学模型和具有QUICK差分格式的SIMPLE算法。在相同条件下计算结果和实验结果符合很好。数值结果显示, 当几何结构一定时,Rayleigh数Ra小于某个临界值时,流动和换热处于稳态,并且关于垂直中心线对称;Ra大于这个临界值时,流动和换热是振荡的,非对称的。数值实验还表明,流动和换热出现振荡时的临界Rayleigh数Rac与开缝圆的开缝度有关,且流动和换热的振荡会出现对称振荡和非对称振荡两种情形。 相似文献
10.