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1.
本文采用脉冲激光沉积方法在LaAlO3(001)单晶衬底上制备了反钙钛矿GaCMn3薄膜,通过控制制备过程中脉冲激光的能量,研究了不同激光能量条件对GaCMn3薄膜结构与物理性能的影响.分别利用X射线衍射仪、原子力显微镜、超导量子干涉仪和物理性能测试系统,对所制备的薄膜的晶体结构、表面形貌和磁性、电输运性质进行了研究.结果表明,制备的样品均为具有多个晶面取向的反钙钛矿薄膜,且薄膜结构和物性明显随制备激光能量的变化而变化.当激光能量为450mJ时,制备的薄膜多晶面取向性最弱,结晶性和表面形貌最优良.实验所得的薄膜均表现出顺磁-铁磁-反铁磁相转变,然而转变过程比块材较平缓,同时薄膜的电阻率并未表现出块材中的突变特征,我们推测该现象很可能是由衬底的应力及衬底的晶格膨胀对薄膜反常晶格变化的抑制作用造成的. 相似文献
2.
A polymerized quaternary ammonium salt polydiallyldimethylammonium chloride, exhibiting high stability to heat and base, was prepared and applied as phase-transfer catalyst (PTC) in halogen-exchange (Halex) fluorination of chloronitrobenzenes to give excellent yields of corresponding fluoronitrobenzenes. Dimethyl sulfoxide was found to be the best solvent when microwave was applied as heating resource. 相似文献
3.
锗在国防工业、航空航天和通信等领域中的战略性,锗含量的测定对于保证材料质量和满足国际标准至关重要。本文综述了锗含量测定方法的多种技术,包括分光光度法、原子荧光光谱法、原子吸收光谱法、电感耦合等离子体原子发射光谱法、电感耦合等离子体质谱法以及滴定法。在每个检测方法的介绍中,详细探讨了方法的原理、前处理步骤以及应用范围,并分别总结了各个方法的优势和不足。最后,强调了锗含量测定方法的意义,特别是在满足出口监管和促进科学研究方面的作用。同时对锗元素的测定方法进行了展望,为未来的发展提供了参考方向。 相似文献
4.
Wei Zhou Xiangning Fang Qinglong Qiao Wenchao Jiang Yue Zhang Zhaochao Xu 《中国化学快报》2021,32(2):943-946
With the development of single-molecule detection and super-resolution fluorescence imaging, rhodamine dyes gain new life. Through the modification of the N-substituents and the replacement of the oxygen atom in xanthene, the wavelength and brightness can be effectively changed. However, the spectra of rhodamine, especially due to the balance between ring-closed non-fluorescent lactone and ring-opened fluorescent zwitterion/cation, are sensitive to interference from various environmental factors. In this way, the spectral data of various rhodamines reported by different research groups under different test conditions lacked comparability, sometimes even lacked accuracy. In order to meet the requirements for the accuracy and uniformity of spectral data in the research of single molecule imaging and dye structure-fluorescence relationship study, we have tested the spectra of fifteen rhodamine dyes that cover the visible and near-infrared regions under exactly the same conditions. By studying the dependence of the spectra on dye concentrations, it was confirmed that 1 μmol/L was ideal for detection less from the interference of dye molecule aggregation. We provide comprehensive and reliable spectral data of these fifteen dyes, which are expected to be used as references for future research. And the direct comparison of different rhodamine spectra would help to understand the structure-fluorescence relationship of rhodamines. 相似文献
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Shamsa Kanwal Qiang Ma Wenchao Dou Guannan Wang 《International journal of environmental analytical chemistry》2013,93(2):210-221
A new sensitive chemiluminescence (CL) method combined with continuous flow injection analysis is described for the determination of Cr(VI). Strong CL signals were generated by Cr(VI)-catalysed oxidation of gallic acid in the presence of potassium permanganate and hydrogen peroxide. Effects of reagent concentrations, temperature, pH, flow rates, mixing coil length and mixing flow sequences on the chemiluminescence intensity were studied. Under the optimised experimental conditions, the relationship between the logarithm of concentration (log?C) of Cr(VI) and the logarithm of intensity (log?I) is linear over the range of 2?×?10?11 – 5?×?10?4?mol?L?1, with the detection limit (3σ) of 4?×?10?12?mol?L?1. Relative standard deviation of ten measurements of 1?×?10?9?mol?L?1 Cr(VI) is 1.7%. This flow injection analysis (FIA) system proved to be able to analyse up to 40 samples h?1. Effects of various interferences possibly present in the water samples were investigated. Most cations and anions, as well as organic compounds, did not interfere with the determination of Cr(VI) in water samples. The experimental results obtained for chromium in reference materials were also in good agreement with the certified values. 相似文献
9.
Enhanced Crystal Quality of Perovskite via Protonated Graphitic Carbon Nitride Added in Carbon-Based Perovskite Solar Cells 下载免费PDF全文
Mingxing Guo Wenchao Liu Junyan Huang Jiaqi Liu Shuhui Yin Jing Leng 《化学物理学报(中文版)》2022,35(2):390-398
The quality of perovskite layers has a great impact on the performance of perovskite solar cells (PSCs). However, defects and related trap sites are generated inevitably in the solution-processed polycrystalline perovskite films. It is meaningful to reduce and passivate the defect states by incorporating additive into the perovskite layer to improve perovskite crystallization. Here an environmental friendly 2D nanomaterial protonated graphitic carbon nitride (p-g-C\begin{document}$_3$\end{document} N\begin{document}$_4$\end{document} ) was successfully synthesized and doped into perovskite layer of carbon-based PSCs. The addition of p-g-C\begin{document}$_3$\end{document} N\begin{document}$_4$\end{document} into perovskite precursor solution not only adjusts nucleation and growth rate of methylammonium lead tri-iodide (MAPbI\begin{document}$_3$\end{document} ) crystal for obtaining flat perovskite surface with larger grain size, but also reduces intrinsic defects of perovskite layer. It is found that the p-g-C\begin{document}$_3$\end{document} N\begin{document}$_4$\end{document} locates at the perovskite core, and the active groups -NH\begin{document}$_2$\end{document} /NH\begin{document}$_3$\end{document} and NH have a hydrogen bond strengthening, which effectively passivates electron traps and enhances the crystal quality of perovskite. As a result, a higher power conversion efficiency of 6.61% is achieved, compared with that doped with g-C\begin{document}$_3$\end{document} N\begin{document}$_4$\end{document} (5.93%) and undoped one (4.48%). This work demonstrates a simple method to modify the perovskite film by doping new modified additives and develops a low-cost preparation for carbon-based PSCs. 相似文献
10.
The ease of undesirable agglomeration and a low efficiency are two problems that restrict the application of graphite nanoplatelets (GNPs) in epoxy resins (EP). Herein, a new strategy with melamine (MEL) as the precursor to functionalize GNPs chemically, which form a bonding layer that is compatible with epoxy matrix, is reported. The MEL fragments with secondary amine groups were grafted uniformly on the GNPs surface by covalent junctions to exploit the diazonium chemistry. This behavior led to a better dispersion and a stronger interaction with the epoxy matrix and resulted in an enhanced glass transition temperature and bending strength, compared with the pure EP. When only 1 wt% functionalized GNPs (f‐GNPs) was used, the Tg of the modified EP raised of about 15°C compared with pure EP, and the bending strength increased by approximately 39%. The dielectric constant of the EP with f‐GNPs was impacted slightly, and the dielectric loss decreased. At 105 Hz, the dielectric loss of the EP with 1 wt% f‐GNPs decreased by approximately 11% compared with pure EP. Therefore, diazotization modification of the GNPs is a useful approach to improve the compatibility in nanoparticle networks. 相似文献