Constraint on a New Short-Range Spin—Orbit Interaction from Neutron Diffraction Data for a Noncentrosymmetric Crystal

JETP Letters - A constraint $$g_{A}^{2}\leq 4.5\times10^{-24}\big(g^{2}+1/\lambda_{A}^{2}\big)$$ on the constant gA of a new short-range (spin—orbit) interaction between nucleons, which is...     

Modeling of the defect structure in dislocation-free silicon single crystals

A mathematical model of the formation of primary grown-in microdefects on the basis of dissociation diffusion is presented. Cases of “vacancy-oxygen” (V + O) and “carbon-interstitial” (C + I) interaction near the crystallization front are considered for dislocation-free Si single crystals grown by the floating-zone and Czochralski methods. The approximate analytical expressions obtained by setting 1D and 2D temperature fields in a crystal are in good agreement with the heterogeneous mechanism of formation of grown-in microdefects.     

Remarks on mathematical structure of BRST theories

A number of rigorous results concerning the mathematical structure of quantum systems with the BRST symmetry are presented. For studying model-independent properties of such systems, a generalization of the Strocchi-Wightman theory is suggested, which is a Wightman type theory in the Krein space with an OpJ*-algebra of physical and ghost fields. It is proved that the BRST charge operatorQ is either bounded with (Q)={0} or unbounded with (Q)=¢. A number of conditions equivalent to the no-ghost theorem (which states that the kernel ofQ is non-negative) are derived.     

Cyclic deformation of aluminium and its alloys

The formation of slip bands is the main mechanism of cyclic deformation in pure Al. Their density, orientation and heights in polycrystalline Al were investigated during cycling. Types, sizes and densities of precipitates are responsible for the mode of cyclic deformation in AlCu4 pure alloy. In technical Al alloys intermetallic phases have detrimental effects on deformation homogeneity and largely govern the fatigue mechanism of the material and especially microcrack initiation.     

含氧光敏引发体系的研究——Ⅵ.二苯酮/三乙胺体系引发光聚合过程中的再次引发效应

过去,作者曾发表了多种光敏引发体系引发烯类单体光聚合的工作,在研究2,2-二甲氧基苯乙酮在氧存在下引发甲基丙烯酸甲酯光聚合时,结合在聚合物链端的引发剂碎片具有光化学活性,在光聚合反应中产生高分子自由基,发生再次聚合,出现高分子量     

Lifting bodies using the flow behind axisymmetric conical shock waves

One of the methods of designing aircraft with supersonic flight speeds involves solving an inverse problem by means of the well-known flow schemes and the substitution of rigid surfaces for the flow surfaces. Lifting bodies using the flows behind axisymmetric shock waves belong to these configurations. All lifting bodies using the flow behind a conical shock wave can be divided into two types [1]. Bodies whose leading edge passes through the apex of the conical shock wave pertain to the first type and those whose leading edge lies below the apex of the conical shock wave, to the second. For small apex angles of the basic cone at hypersonic flow velocities an approximate solution of the variation problem was obtained, which showed that the lift-drag ratio of lifting bodies of the second type is higher than that of the first [2]. The present paper gives a numerical solution of the problem for flow past lifting bodies of the second type using the flow behind axisymmetric conical shock waves with half-angles of the basic cone _S=9.5 and 18° The upper surfaces of the bodies are formed by intersecting planes parallel to the velocity vector of the oncoming flow.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 2, pp. 135–138, March–April, 1986.     

Catalytic oxidation of CO,hydrocarbons, and ethyl acetate over perovskite-type complex oxides

The catalytic activity of M^IM^IIO₃] perovskite-type complex oxides (M^I = La, Y, Nd, Yb; M^II = Co, Mn, Ni) in the oxidation of CO, propylene, benzene, ethylbenzene,o-xylene, and ethyl acetate was investigated. The Co-containing catalysts were shown to be more active in the oxidation than the Mn-containing catalysts. A relationship between the catalytic and adsorption properties was established.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 4, pp. 602–605, April, 1994.     

The Effect of the Nature and Structure of Adsorbents on Interaction with Ibuprofen

The interaction of ibuprofen [2-(4-isobutylphenyl)propionic acid] with the surface of carbon and oxide adsorbents was investigated. The significant role of wide pores during the adsorption of ibuprofen on carbon adsorbents in the presence of protein molecules was demonstrated. At low concentrations ibuprofen is adsorbed on the surface of hydrophilic and hydrophobic adsorbents in the form of a monomer, but the contribution from the adsorbed dimer increases with increase in its concentration.     

Crystal Structures of Double Vanadates LiCoVO4 and Li0.5Co1.25VO4

The crystal structures of vanadates Li_1-2xCo_1+xVO₄ with x = 0 and 0.25 have been studied by a full pattern analysis. It has been shown that in cubic spinel LiCoVO₄ (space group Fd3m), the 8a tetrahedral sites contain a majority of vanadium and a small amount of lithium; all cobalt, lithium, and a small amount of vanadium occupy the 16d octahedral sites. Li_0.5Co_1.25VO₄ crystals belong to the rhombic system (Imma space group) with unit cell parameters a = 5.939(1), b = 5.810(1), and c = 8.303(1). On substitution of lithium by cobalt according to the scheme 2Li⁺ Co²⁺ + , half of the lithium and 70% of the vacancies formed are in the 4a octahedral sites, and onethird of lithium and most of cobalt occupy the 4d octahedral sites. The 4e tetrahedral sites are completely occupied by vanadium and lithium in a ratio of 0.92/0.08. The interatomic distances in LiCoVO₄ and Li_0.5Co_1.25VO₄ are calculated, and the sizes of lithium ion transport channels are evaluated.     

Mass-spectrometric study of 2- and 4-thiobarbituric acid derivatives

The mass spectra of 2- and 4-thiobarbituric acids and some of their close analogs at ionizing voltages of 70 and 14 eV are compared. Qualitative and quantitative differences in the behavior of these compounds under the influence of electron impact were established. It is shown that the position of the thione group in the ring and the tautomeric transformations have a substantial effect on the character of the fragmentation of the investigated compounds. The established fragmentation principles make it possible to distinguish the structural isomers in a series of 2- and 4-thiobarbituric acids from their mass spectra.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 4, pp. 529–535, April, 1976.