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排序方式: 共有889条查询结果,搜索用时 15 毫秒
1.
Edward G. Sheetz Zhao Zhang Alyssa Marogil Minwei Che Dr. Maren Pink Dr. Veronica Carta Prof. Dr. Krishnan Raghavachari Prof. Dr. Amar H. Flood 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(60):e202201584
The recognition of boron compounds is well developed as boronic acids but untapped as organotrifluoroborate anions (R−BF3−). We are exploring the development of these and other designer anions as anion-recognition motifs by considering them as substituted versions of the parent inorganic ion. To this end, we demonstrate strong and reliable binding of organic trifluoroborates, R−BF3−, by cyanostar macrocycles that are size-complementary to the inorganic BF4− progenitors. We find that recognition is modulated by the substituent's sterics and that the affinities are retained using the common K+ salts of R−BF3− anions. 相似文献
2.
A new sample business survey for agriculture, the REA survey, and a project of integration with the FADN network (RICA in
Italy) have significantly changed the production of statistical information nowadays available with reference to the agricultural
sector. On the basis of this relevant information, new economic analyses are being developed on farms’ performance, agricultural
households’ income and the Common Agricultural Policy (CAP). In this paper the authors estimate the relationship between the
levels of variables of interest and their sampling errors using models in order to improve the accessibility of the information
on estimates accuracy to the final users (agricultural analysts, policy makers).
The paper is the result of a joint research of the three authors. Sections 1–3 and 6 by Pizzoli, Sects. 4 and 5 by Rondinelli,
Sect. 7 by Filiberti, conclusions joint to the three authors. 相似文献
3.
Veronica Felli Susanna Terracini 《Calculus of Variations and Partial Differential Equations》2006,27(1):25-58
This paper deals with a class of nonlinear elliptic equations involving a critical power-nonlinearity as well as a potential featuring multiple inverse square singularities. When the poles form a symmetric structure, it is natural we wonder how the symmetry affects such mutual interaction. The present paper means to study this aspect from the point of view of the existence of solutions inheriting the same symmetry properties as the set of singularities.
Mathematics Subject Classification (2000) 35J60, 35J20, 35B33 相似文献
4.
Ionic elastomers based on carboxylated nitrile rubber (XNBR) crosslinked with magnesium oxide (OMg) and filled with layered nanoclays have been prepared. Two types of nanofillers were employed: a commercial one (Cloisite 15 A) and the other prepared in our laboratory (BCA-ODA). The properties of raw and vulcanized compounds have been studied in order to elucidate the effect of layered nanoclays. X-ray diffraction analysis shows that during compounding and crosslinking the macromolecular chains of rubber were intercalated in a commercial nanofiller, whilst our nanoclay was exfoliated. However, this fact does not affect the properties of compounds homogeneously. Vulcanization parameters, Mooney viscosity and decay and rheological properties were affected depending on the filler type. Mechanical properties were not significantly varied, but glass transition temperature and ionic transition temperature were shifted in comparison with those of the unfilled compound. 相似文献
5.
Angel L. Esteban Maria P. Galache Francisco Mora Ernesto Diez Jesus San Fabian 《Journal of computational chemistry》1989,10(7):887-895
An equation is formulated on the basis of theoretical INDO/FPT calculations which describes the angular dependence of the propanic long-range coupling constant 4JMeH in substituted HCCCH3 fragments. This equation is a truncated Fourier series in the torsion angle ?, HCCMe, which takes into account the dependence of the Fourier coefficients on the bond angle θ, CCMe. The substituent effects are assumed to be additive. Some parameters in the equation may be obtained from the 4JMeH couplings in propane and neopentane derivatives. The calculated effect upon 4JMeH of changes in the bond angle θ is significant and it seems to be in part the cause of some effects which have been attributed to conformational dependence. 相似文献
6.
Veronica?StigssonEmail author G?ran?Kloow Ulf?Germg?rd Niclas?Andersson 《Cellulose (London, England)》2005,12(4):395-401
Controlling the reduction in molecular weight of the cellulose chains is essential in the production of carboxymethyl cellulose
(CMC). Such a reduction can be achieved by the addition of cobalt during the process of cobalt(II) ions, which act as a catalyst
for oxidative cleavage, and the influence thereof has been studied under a variety of conditions. This study has resulted
in a model that summarises the effects of the added amount of cobalt, the time for the cobalt reaction, the temperature in
the mercerisation stage of the CMC-manufacturing process and finally the effect of the temperature in the etherification stage.
It is shown that it is important for cobalt to be present during the mercerisation stage in order to achieve the desired viscosity. 相似文献
7.
The bond dissociation enthalpies (BDE) of several phenols containing electron-withdrawing substituents in the para position have been determined by means of the EPR radical equilibration technique. It has been found that CN, NO(2), CHO, COOR, and COOH induce an increase of the BDE value of the O-H bond, thus producing a worsening of the antioxidant activity of phenols, while Cl, Ph, and CH[double bond]CHPh show an opposite effect. The contributions of these substituents for the calculation of the BDE values in polysubstituted phenols by using the group additivity rule have also been derived. It is shown that this rule provides quite reliable predictions of bond strengths, so that the method can be conveniently used to estimate new data on substituted phenols. 相似文献
8.
Roman E. Enrique Castro W. Veronica Camus O. Margarita 《Journal of organometallic chemistry》1985,293(1):93-101
The reactions between the phosphine-organoiron [CpFeII-η6-C6Me5CH2PPh2]+ PF6? (1) and [RhCl(η4-diolefin)(μ-Cl)]2 in CH2Cl2 at reflux give the new heterobinuclear air-stable crystalline complexes [CpFeII-η6-C6Me5CH2)P(Ph)2Rh(η4-diene)Cl]PF6,(D'*-diene=cyclooctadiene (COD): 65%, 2; trimethylfluorobenzobicyclo[2.2.2]octadiene (Me3TFB): 48%, 3). Complexes 2 and 3 have been studied by 1H, 13C and 31P NMR spectroscopy and they are carbonylated (CO, 1 atm). Cyclic voltammetry experiments with addition of MeOH show electron transfer FeIRhI → FeIIRh0, the presence of a catalytic wave FeI/FeII and the possible formation of Rh hydrides. Under normal conditions 2 is a catalyst for hydrogenation of cyclohexene, but it is less efficient than the known mononuclear Rh1 analogues. 相似文献
9.
Many gas-phase anions react with carbonyl sulfide by sulfur atom transfer to form RS? ions. The properties of H2NS?, formed in this way from H2N? and OCS, are described. 相似文献
10.