Allobetulin Ring A Contraction Effected by Sulfur Diethylaminotrifluoride

Russian Journal of General Chemistry - The action of sulfur diethylaminotrifluoride on 19β,28-epoxyoleanan-3-ol (allobetulin) causes dehydration of the terpenoid and isomerization of the ring...     

Formation of substituted pyrazolines in the reaction of C,N-diphenylnitrilimine with a zwitterion derived from triisopropylphosphine and ethyl 2-cyanoacrylate

The reaction of C,N-diphenylnitrilimine with a P-zwitterion derived from Prⁱ ₃P and H₂C=C(CN)CO₂Et afforded the first representative of 2-pyrazolines containing the phosphonium group and products of the addition of nitrilimine to Prⁱ ₃P and H₂C=C(CN)CO₂Et. The reaction of the P-zwitterion with C-4-nitrophenyl-N-phenylnitrilimine gave rise to a condensation product of one Prⁱ ₃P molecule and two nitrilimine molecules. The three-dimensional structures of the compounds synthesized were established by X-ray diffraction analysis.     

The structure of 113Sn from proton and alpha- particle induced reactions

The results of in-beam investigations of ¹¹³ Sn using the (p,n), (p,3n), (α,n) and (α,2n) reactions are summarized. Excited states have been identified until E _x = 4715 MeV and J ^π = (27/2^{t -}). For a large number of levels mean lifetimes τ have been determined with the DSA method. For the J ^k = 25/2⁺ state at E _x = 4059 MeV, τ = 1.0(4) ns has been measured with the γ-RF method. The experimental results are compared with the predictions of shell-model calculations. Most of the positive-parity states may be considered as one-or three-quasiparticle neutron excitations of the 2d_5/2, 1_g7/2, 3_s1/2 and 2d_3/2 shells, the negative-parity states as the coupling of one 1h_11/2 neutron to the two- or four-quasiparticle neutron excitations in the even-mass ¹¹²Sn core. For the 25/2⁺ isomer the three-quasiparticle neutron configuration ν(h ₁₁ ^2/2 g ₇ ^2/?1 ) has been proposed on the basis of a shell-model analysis using the mass-formula formalism. The experimentally observed yrast states in ₅₀ ¹¹³ Sn₆₃ are compared with the corresponding states in the valence mirror nucleus ₆₃ ¹⁴⁵ Eu82 giving remarkable similarities although the parameters for the shell-model calculations differ considerably. The analysis of nearest-neighbour spacing distributions of experimentally obtained 5/2⁺ states in ¹¹³Sn does not allow definite conclusions about regularity or chaos.     

Reaction of 2-(4,5-dihydrofur-3-yl)-1,3-diphenyl-1,3-diaza-2-2λ3-phospholidine withC,N-diphenylnitriliminewithC,N-diphenylnitrilimine

The reaction of 2-(4,5-dihydrofur-3-yl)-1,3-diphenyl-1,3-diaza-2λ³-phospholidine withC,N-diphenylnitrilimine is a multistage process, in the course of which the 1,2,4-diazaphosphorine ring is formed and both rings of the initial organophosphorus compound are cleaved. 5-(2-Chloroethyl)-4-(N,N′-diphenylethylenediamino)-1,3-diphenyl-1,4-dihydro-1, 2,4λ⁵-diazaphosphorine was obtained as the final product. Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 1, pp. 125–128, January, 2000.     

Reaction of (Pentafluorophenyl)diphenylphosphine with Azadicarboxylic Acid Dimorpholide

Russian Journal of General Chemistry -     

Addition of perfluoroalkanoic acids to (R)-(+)-limonene

Perfluoroalkanoic acids with different lengths of the perfluoroalkyl radical selectively add under mild conditions to the exocyclic double C=C of limonene to give the corresponding Markovnikov adducts, α-terpinyl perfluoroalkanoates. The reaction in the presence of sulfuric acid 0°C involves both double C=C bonds in the limonene molecule with formation of p-menthane-1,8-diyl bis(perfluoroalkanoates).     

Some physical problems of cumulation

A review and analysis of some results related to the phenomenon of cumulation are given. The various models used to describe this phenomenon are considered. Lavrent’ev Institute of Hydrodynamics, Russian Academy of Sciences, Novosibirsk 630090. Translated from Prikladnaya Mekhanika i Tekhnicheskaya Fizika, Vol. 41, No. 5, pp. 10–26, September–October, 2000.     

10-(3-Hydroxypropyl)-1,4,6,8-tetraphenyl-1,4,7,8-tetraaza-5-phosphoniaspiro[4.5]deca-6,9-diene chloride: synthesis and molecular structure

The reaction of 2-(3,4-dihydro-2H-pyran-5-yl)-1,3-diphenyl-1,3-diaza-2³-phospholidine with C,N-diphenylnitrilimine yields 10-(3-hydroxypropyl)-1,4,6,8-tetraphenyl-1,4,7,8-tetraaza-5-phosphoniaspiro[4.5]deca-6,9-diene chloride. Its structure was determined by X-ray diffraction analysis.