全文获取类型
收费全文 | 811篇 |
免费 | 7篇 |
国内免费 | 9篇 |
专业分类
化学 | 536篇 |
晶体学 | 14篇 |
力学 | 7篇 |
数学 | 26篇 |
物理学 | 244篇 |
出版年
2022年 | 3篇 |
2021年 | 5篇 |
2020年 | 5篇 |
2019年 | 7篇 |
2018年 | 4篇 |
2016年 | 6篇 |
2015年 | 7篇 |
2014年 | 11篇 |
2013年 | 31篇 |
2012年 | 35篇 |
2011年 | 45篇 |
2010年 | 20篇 |
2009年 | 21篇 |
2008年 | 44篇 |
2007年 | 68篇 |
2006年 | 58篇 |
2005年 | 67篇 |
2004年 | 60篇 |
2003年 | 47篇 |
2002年 | 49篇 |
2001年 | 11篇 |
2000年 | 9篇 |
1999年 | 9篇 |
1998年 | 9篇 |
1997年 | 13篇 |
1996年 | 5篇 |
1995年 | 5篇 |
1993年 | 6篇 |
1992年 | 3篇 |
1991年 | 10篇 |
1990年 | 6篇 |
1989年 | 10篇 |
1988年 | 5篇 |
1987年 | 10篇 |
1986年 | 5篇 |
1985年 | 10篇 |
1984年 | 12篇 |
1983年 | 8篇 |
1982年 | 9篇 |
1981年 | 4篇 |
1980年 | 8篇 |
1979年 | 8篇 |
1978年 | 13篇 |
1977年 | 6篇 |
1976年 | 3篇 |
1975年 | 5篇 |
1974年 | 6篇 |
1973年 | 12篇 |
1969年 | 3篇 |
1968年 | 3篇 |
排序方式: 共有827条查询结果,搜索用时 62 毫秒
1.
2.
Toshihiko Hoshiro 《Journal d'Analyse Mathématique》2003,91(1):211-230
This article discusses some smoothing estimates of the initial value problem for dispersive equations with constant coefficients.
In particular, it is shown that a certain condition for the principal part of the symbol (see the assumption (1.3) below,
which is equivalent to the one “of principal type” in the paper by Ben-Artzi and Devinatz [2]) is necessary and sufficient
for the maximal smoothing in space-time.
Dedicated to Professor Norio Shimakura
The author was supported in part by Grant-in-Aid for Scientific Research, Ministry of Education, Culture, Sports, Science
and Technology, Japan (No. 13640187). 相似文献
3.
Hoon Kim Toshihiko Koseki Tomohiro Ohta Hiroshi Sato Yukihiro Shimogaki 《Applied Surface Science》2006,252(11):3938-3942
The adhesion of Cu on Ru substrates with different crystal orientations was evaluated. The crystal orientation of sputter deposited Ru could be changed from (1 0 0) to (0 0 1) by annealing at 650 °C for 20 min. The adhesion of Cu was evaluated by the degree of Cu agglomeration on Ru. Cu films on annealed Ru films with the (0 0 1) crystal orientation showed 28% lower RMS values and 50% lower Ru surface coverage than Cu as-deposited on Ru having the (1 0 0) crystal orientation after annealing at 550 °C for 30 min, which suggest that Cu wettability on the Ru(0 0 1) was better than that on the Ru(1 0 0) plane. The low lattice misfit of 4% between Cu(1 1 1) and Ru(0 0 1) may be the reason for this good adhesion property. 相似文献
4.
Preconcentration by collection of metal complexes on chitin has been applied to the spectrophotometric determination of iron in water. The iron is collected as its 1,10-phenanthroline (phen) complex on a column of chitin in the presence of tetraphenylborate as counter-ion. The iron(II)-phen complex retained on the chitin is eluted with an acetone-1M acetic acid mixture (8:2 v/v), and the absorbance of the eluate is measured at 512 nm. Beer's law is obeyed over the concentration range 1.1-11.2 mug of iron in 10 ml of eluate. In the presence of EDTA as masking agent, Ca, Mg, Al, Mn, Zn, Cd and Pb do not interfere in concentrations up to 100 times that of iron(II) and Co, Ni and Cu do not interfere in concentrations up to 20 times that of iron(II). Common inorganic anions do not interfere in concentrations up to 10,000 times that of iron(II). The proposed method has been applied to determination of iron in tap water. 相似文献
5.
S Ozaki T Akiyama T Morita M Kumegawa T Nagase N Uehara A Hoshi 《Chemical & pharmaceutical bulletin》1990,38(11):3164-3166
Various kinds of 5'-O-unsaturated acyl 5-fluorouridines were synthesized to obtain 5-fluorouridine derivatives with low toxicity and high antitumor activity. Antitumor activity of the compounds against L-1210 leukemia in mice was examined, and the 5'-O-4-pentenoyl derivative showed the highest antitumor activity. 相似文献
6.
Isotachophoretic qualitative indices, RE, for twenty-eight dipeptides were measured in the range pH 7.4–9.6. The absolute mobility, mo, and pKa values were evaluated by the use of the least-squares method, utilizing a simulation of the isotachophoretic steady state. The mo values were newly evaluated and the pKa values were in good agreement with literature values. By comparison of the evaluated mo and pKa values of the dipeptides with those of the constituent amino acids, simple relationships were found which may be used to estimate the mo and pKa values of other dipeptides. The separability of the dipeptides was also evaluated by considering the differences between their simulated effective mobilities. It is concluded that isotachophoresis is very convenient for the separation of dipeptides and their constituent amino acids. 相似文献
7.
To detect a lectin from soybean, an electrochemical procedure was developed by the use of a labeling of galactosamine. Because the lectin has binding sites to galactosamine, galactosamine labeled with daunomycin having electroactivity was prepared. When labeled galactosamine (LG) combines with lectin, the part of daunomycin is taken in the binding sites of the lectin and becomes electroinactive. Therefore, the concentration of the lectin can be estimated by measuring the peak current of the LG. On the other hand, a competitive reaction to the lectin of galactosamine and the LG makes a detection of galactosamine possible. This method has merit that does not require a separation procedure of the free LG from the bound one. An effect of length of spacer between daunomycin and galactosamine was also investigated. It was found that adsorption of reagent on the electrode increased due to introduction of the spacer. Furthermore, the electrode response of the LG was influenced by the type of the spacer. 相似文献
8.
Dosimetry of fast neutrons in 1W nuclear reactor with plastic nuclear-track detectors 总被引:1,自引:0,他引:1
A nuclear reactor at Kinki University is operated at the maximum of 1W. It produces fission neutrons as much as gamma-rays. To facilitate its use for neutron radiobiology, fast neutrons inside the reactor were measured with nuclear-track detectors TS 16 N and a pair of ion chambers. The angular dependence of TS 16 N response, an anisotropy of fast neutron fluxes in the reactor and misuse of the kerma factor assumed for radiation protection business are the major causes of discrepancy is measured doses by the two methods. Correction factors for the three causes are proposed. After correction, neutron doses estimated with TS 16 N and chambers agree within 5%. The dose-rate at the reactor's center is about 20 tissue-cGy/h. This is the first in situ dosimetry of fast neutrons in a reactor with track detectors attached to biologic samples. Our routine usage has demonstrated that, if used with caution, TS 16 N elements are handy, reliable monitors for fast neutron dosimetry as they are insensitive to contaminated gamma-rays and small enough to be attached to biologic samples. 相似文献
9.
C. Yonezawa M. Magara H. Sawahata M. Hoshi Y. Ito E. Tachikawa 《Journal of Radioanalytical and Nuclear Chemistry》1995,196(1):171-178
The extraction behavior of uranium(VI), plutonium(IV) and some fission products like zirconium(IV), ruthenium(III) and europium(III) from 3.5M nitric acid with -irradiated organic phase pre-equilibratedn-dodecane solutions of dihexyl derivatives of hexanamide (DHHA), octanamide (DHOA) and decanamide (DHDA) has been investigated as a function of absorbed dose upto 184·104 Gy. The results indicate that the extraction of uranium(VI) decreases gradually with dose upto 72·104 Gy and becomes almost constant thereafter, while, the extraction of plutonium(IV) decreases upto a dose of 20·104 Gy and then increases rapidly up to a dose of 82·104 Gy indicating synergistic effects of radiolytic products formed at higher doses. Extraction of zirconium(IV) increases gradually upto a dose of 72·104 Gy. Europium(III) does not get extracted with any of these amides in the entire dose range (0–184·104 Gy) studied, however, ruthenium shows insignificant increase in extraction with dose. The decrease inD values noticed in the case of plutonium and zirconium after the dose of 72·104 Gy which was attributed to the third phase formation and emulsification. Infrared studies confirm the final products of radiolysis as the respective amines and carboxylic acids. The degraded amide contents have been estimated by quantitative IR spectrophotometric technique. Extraction data obtained for uranium(VI) and plutonium(IV) with TBP/n-dodecane system have also been compared under similar experimental conditions. 相似文献
10.
Kajihara M Sugie T Sano A Fujioka K Urabe Y Tanihara M Imanishi Y 《Chemical & pharmaceutical bulletin》2003,51(1):11-14
Silicone has been utilized as a carrier material for sustained release system of lipophilic drugs. Extensive studies revealed that drug release rate is influenced by factors such as physicochemical properties of the drug and additives.(1-5)) When a lipophilic drug is highly potent at low concentrations, the drug release rate should be strictly controlled so as to avoid side effects. In this study, using vitamin D(3) (VD(3)) as an example of such drugs, we investigated novel method to suppress initial burst and to modify drug release rate from silicone matrix. As a result, it was found that (a). addition of human serum albumin (HSA) suppressed initial burst and enhanced release rate in the later stage, resulting constant release of VD(3), (b). covering a matrix formulation with a membrane of low diffusivity (core-rod formulation) suppressed initial burst and released drug in a constant rate, and (3) using materials for which the drug has high affinity as dissolution solvent (reservoir formulation), the drug release rate was reduced. 相似文献