全文获取类型
收费全文 | 859篇 |
免费 | 34篇 |
国内免费 | 3篇 |
专业分类
化学 | 636篇 |
晶体学 | 10篇 |
力学 | 11篇 |
数学 | 26篇 |
物理学 | 213篇 |
出版年
2022年 | 5篇 |
2021年 | 4篇 |
2020年 | 13篇 |
2019年 | 18篇 |
2018年 | 7篇 |
2017年 | 5篇 |
2016年 | 11篇 |
2015年 | 18篇 |
2014年 | 22篇 |
2013年 | 37篇 |
2012年 | 49篇 |
2011年 | 39篇 |
2010年 | 31篇 |
2009年 | 29篇 |
2008年 | 50篇 |
2007年 | 52篇 |
2006年 | 53篇 |
2005年 | 50篇 |
2004年 | 44篇 |
2003年 | 33篇 |
2002年 | 23篇 |
2001年 | 8篇 |
2000年 | 14篇 |
1999年 | 19篇 |
1998年 | 9篇 |
1997年 | 5篇 |
1996年 | 10篇 |
1995年 | 8篇 |
1994年 | 10篇 |
1993年 | 12篇 |
1992年 | 15篇 |
1991年 | 19篇 |
1990年 | 12篇 |
1989年 | 7篇 |
1988年 | 9篇 |
1987年 | 13篇 |
1986年 | 11篇 |
1985年 | 23篇 |
1984年 | 10篇 |
1983年 | 10篇 |
1982年 | 12篇 |
1981年 | 11篇 |
1980年 | 10篇 |
1979年 | 7篇 |
1978年 | 5篇 |
1977年 | 4篇 |
1975年 | 4篇 |
1974年 | 3篇 |
1973年 | 8篇 |
1972年 | 3篇 |
排序方式: 共有896条查询结果,搜索用时 312 毫秒
1.
Stability Properties of Maps Between Hopf Spaces 总被引:1,自引:0,他引:1
2.
Hiroshi Maruyama Tadao Ishii Naruhiko Bamba Hironobu Maeda Akihisa Koizumi Yuzo Yoshikawa Hitoshi Yamazaki 《Physica C: Superconductivity and its Applications》1989,160(5-6):524-532
The temperature dependence of the extended X-ray absorption fine structure (EXAFS) is studied in the high Tc superconductors, YBa2Cu3O7−δ. The measurements were done at the Cu K-edge for samples of two orthorhombic phases (Tc≈90 K and ≈58 K, respectively) and a nonsuperconducting tetragonal phase. Interatomic distances and mean square relative displacements σ2 for Cu-O bonds are determined by the least squares refinement. The results indicate that values of σ2 increase near Tc for both the orthorhombic samples. It is concluded that this anomalous behavior related to Tc is caused by an anomalous vibration of oxygen atoms in the Ba-O layer. Changes in the Cu-O distances from 300 to 20 K are not found. 相似文献
3.
Lian-Chun Park Tatsuo Maruyama Noriho Kamiya Masahiro Goto Hiroyuki Kuma Naotaka Hamasaki 《Analytical sciences》2004,20(11):1609-1611
The emergence of drug-resistant hepatitis B virus (HBV) has been reported in patients with prolonged administration of lamivudine, which is a potent drug for the prevention of HBV infection. Lamivudine-resistant HBV has several types of mutations at the YMDD motif of its DNA polymerase. We successfully demonstrated that monitoring the hybridization behavior in nanostructured reverse micelles enables us to detect single nucleotide polymorphisms (SNPs). With the aid of reverse micelles, a model 40-mer oligonucleotide containing a single-base substitution was clearly distinguished from the normal, complementary oligonucleotide. In addition, we extended this technique to a high-throughput analysis. The results obtained with a 96-well micro-plate reader indicated the possibility of SNPs detection toward multiple samples of patients. 相似文献
4.
The Constraint Molecular Dynamics approach is illustrated together with calculation on different heavy ion collisions. In particular the charge-mass distribution produced in the collision 124Sn + 64Ni and 112Sn + 58Ni at 35 MeV/nucleon is discussed. By comparing the Y = (N ? Z)/A distributions for fragments produced in central collisions it results that this observable can be sensitive to the dynamic effects induced on the two systems by the different charge/mass ratio. 相似文献
5.
A new 20-membered macrolide designated exiguolide has been isolated from the marine sponge Geodia exigua, and its structure determined by interpretation of spectroscopic data. Exiguolide specifically inhibited fertilization of sea urchin (Hemicentrotus pulcherrimus) gametes but not embryogenesis of the fertilized egg. 相似文献
6.
7.
Transformations of chemical species formed by the reaction of gaseous BF3 with high pressure and silica preheated at 473 and 1093 K were studied with the use of infrared absorption spectrometry. The species containing -BF2 and the species containing >BF were transformed to each other on the highly-reacted silica depending on the pressure of BF3 in cell, and some of the species containing -BF2 were also desorbed without their transformations to the species containing >BF. H2O played important roles in these transformations. 相似文献
8.
Yuzo Maruyama 《Journal of multivariate analysis》2004,88(2):320-334
We consider estimation of a multivariate normal mean vector under sum of squared error loss.We propose a new class of minimax admissible estimator which are generalized Bayes with respect to a prior distribution which is a mixture of a point prior at the origin and a continuous hierarchical type prior. We also study conditions under which these generalized Bayes minimax estimators improve on the James–Stein estimator and on the positive-part James–Stein estimator. 相似文献
9.
10.
Ryosuke Sakai Issei Otsuka Toshifumi Satoh Ryohei Kakuchi Harumi Kaga Toyoji Kakuchi 《Journal of polymer science. Part A, Polymer chemistry》2006,44(1):325-334
The asymmetric polymerization of 4′‐isocyanatobenzo‐18‐crown‐6 with the lithium amide of (S)‐(2‐methoxymethyl)pyrrolidine successfully proceeded to afford end‐functionalized poly(4′‐isocyanatobenzo‐18‐crown‐6) with (S)‐(2‐methoxymethyl)pyrrolidine (polymer 2 ). In the circular dichroism (CD) spectrum of 2 , a clear positive Cotton effect was observed in the range of 240–350 nm corresponding to the absorption of the polymer backbone, indicating that 2 partially formed a one‐handed helical structure, which was preserved by the chirality of (S)‐(2‐methoxymethyl)pyrrolidine bonding to the terminal end in 2 . In the titration experiments for the CD intensity of 2 in the presence of D ‐ and L ‐Phe·HClO4 (where Phe is phenylalanine), a small but remarkable difference was observed in the amount of the chiral guest needed for saturation of the CD intensity and in the saturated CD intensity, indicating that the extremely stable, one‐handed helical part should exist in the main chain of 2 , which was not inverted even when the unfavorable chiral guest for the predominant helical sense, L ‐Phe·HClO4, was added. In addition, helical polymer 2 exhibited a chiral discrimination ability toward racemic guests; that is, the guests were extracted from the aqueous phase into the organic phase with enantiomeric excess. The driving force of the chiral discrimination ability of 2 should certainly be attributed to the one‐handed helical structure in 2 . © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 325–334, 2006 相似文献