全文获取类型
收费全文 | 640篇 |
免费 | 59篇 |
国内免费 | 1篇 |
专业分类
化学 | 546篇 |
晶体学 | 4篇 |
力学 | 6篇 |
数学 | 44篇 |
物理学 | 100篇 |
出版年
2023年 | 6篇 |
2022年 | 14篇 |
2021年 | 15篇 |
2020年 | 18篇 |
2019年 | 25篇 |
2018年 | 10篇 |
2017年 | 5篇 |
2016年 | 26篇 |
2015年 | 29篇 |
2014年 | 37篇 |
2013年 | 41篇 |
2012年 | 32篇 |
2011年 | 60篇 |
2010年 | 18篇 |
2009年 | 17篇 |
2008年 | 28篇 |
2007年 | 37篇 |
2006年 | 27篇 |
2005年 | 37篇 |
2004年 | 38篇 |
2003年 | 21篇 |
2002年 | 18篇 |
2001年 | 4篇 |
2000年 | 10篇 |
1999年 | 8篇 |
1998年 | 6篇 |
1997年 | 3篇 |
1996年 | 6篇 |
1994年 | 4篇 |
1993年 | 8篇 |
1992年 | 7篇 |
1991年 | 3篇 |
1990年 | 3篇 |
1988年 | 3篇 |
1986年 | 6篇 |
1985年 | 6篇 |
1984年 | 5篇 |
1982年 | 3篇 |
1981年 | 9篇 |
1980年 | 4篇 |
1978年 | 2篇 |
1975年 | 2篇 |
1973年 | 2篇 |
1972年 | 4篇 |
1970年 | 4篇 |
1968年 | 2篇 |
1967年 | 2篇 |
1966年 | 4篇 |
1957年 | 2篇 |
1924年 | 2篇 |
排序方式: 共有700条查询结果,搜索用时 15 毫秒
1.
2.
D3h‐Symmetric Porphyrin‐Based Rigid Macrocyclic Ligands for Multicofacial Multinuclear Complexes in a One‐Nanometer‐Sized Cavity 下载免费PDF全文
Yohei Ohkoda Akane Asaishi Tomoya Namiki Tomoaki Hashimoto Midori Yamada Koichiro Shirai Yuta Katagami Dr. Tomoaki Sugaya Prof. Makoto Tadokoro Prof. Akiharu Satake 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(33):11745-11756
The one‐step synthesis of D3h‐symmetric cyclic porphyrin trimers 1 composed of three 2,2′‐[4,4′‐bis(methoxycarbonyl)]bipyridyl moieties and three porphyrinatozinc moieties was achieved from a nickel‐mediated reductive coupling of meso‐5,15‐bis(6‐chloro‐4‐methoxycarbonylpyrid‐2‐yl)porphyrinatozinc. Although cyclic trimers 1 were obtained as a mixture that included other cyclic and acyclic porphyrin oligomers, an extremely specific separation was observed only for cyclic trimers 1 when using columns of silica gel modified with pyrenylethyl, cyanopropyl, and other groups. Structural analysis of cyclic trimers 1 was carried out by means of NMR spectroscopy and X‐ray crystallography. Treatment of an η3‐allylpalladium complex with a cyclic trimer gave a tris(palladium) complex containing three η3‐allylpalladium groups inside the space, which indicated that the bipyridyl moieties inside the ring could work as bidentate metalloligands. 相似文献
3.
4.
Investigation of one step synthesis of 2-substituted 3-tri-(or di-)fluoromethyl-2-propenals has been carried out using versatile aldehydes, tri- or di-fluoroacetaldehyde ethyl hemiacetal in the presence of diethylaminotrimethylsilane (DEATMS) in an ionic liquid, and it was demonstrated that this route enabled us to successfully construct 2-substituted 3-tri-(or di-)fluoromethyl-2-propenals with the high level selectivity of geometric isomers. 相似文献
5.
Trifluoromethylation onto the tetrafluorophthalonitrile and tetrafluoroisophthalonitrile has been carried out using CF3TMS-CuI-KF system, and it was demonstrated that these trifluoromethylation enabled us to successfully construct di- and/or tri-trifluoromethylated benzonitriles via the decyanotrifluoromethylation. 相似文献
6.
7.
Atiya MS Chiang I Frank JS Haggerty JS Ito MM Kycia TF Li KK Littenberg LS Stevens A Strand RC Louis WC Akerib DS Marlow DR Meyers PD Selen MA Shoemaker FC Smith AJ Azuelos G Blackmore EW Bryman DA Felawka L Kitching P Kuno Y Macdonald JA Numao T Padley P Poutissou J Poutissou R Roy J 《Physical review letters》1990,65(1):21-24
8.
Reaction of gem-difluorinated vinyloxiranes with RCu(X)Li allowed us to introduce the R group regioselectively at the fluorine-attached terminal carbon atom in an SN2′ manner to afford (E)-allylic alcohols exclusively, while homoallylic alcohols with anti stereochemical relationship were found to be obtained selectively from higher-ordered cuprates derived from CuCl and RMgBr in a ratio of 1:3. 相似文献
9.
10.
1,6-Enynes reacted with arylboronic acids in the presence of a catalytic amount of a rhodium(I) complex under mild conditions to give (Z)-1-(1-arylethylidene)-2-vinylcyclopentanes. The regioselective addition of an arylrhodium(I) species across the carbon-carbon triple bond triggered the cyclization process. Intramolecular carborhodation onto the pendent alkene in a 5-exo mode furnished a five-membered ring. Finally, the rhodium(I) methoxide generated by beta-methoxy elimination reacted with the arylboronic acid to promote the next catalytic cycle. 相似文献