The accuracy of determination of the optical constants of smooth copper surfaces produced by different technologies is analyzed, with particular attention paid to the consideration of the influence of scattered radiation (which is ignored by many authors) on the retrieval of the optical constants of copper surfaces from reflected radiation. The neglect of scattered radiation can lead to errors as high as 50% in determining the optical constants for bulk copper. For thin films, the errors are much lower. The influence of surface oxidation during measurements in air and surface features of studied objects on the parameters to be determined is analyzed as well. It is shown that errors in determination of the constants are maximal in the plasma resonance region of copper.
It is shown that diverse 2-substituted thiazolo[3,2-a]quinolinium 1-oxides can be obtained from 2-quinolylmercaptoacetic acids. The structures of the synthesized compounds were confirmed by the PMR and mass spectra.See [1] for communication 3.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 5, pp. 621–626, May, 1980. 相似文献
Reaction of 2-(vinyloxy)ethylisothiocyanate with unsaturated carbanions generated in situ from propargyl ethers and amines when treated with superbases, after S-alkylation and cyclization of the adducts in the presence of CuBr, leads to the previously unknown 2,3,5-substituted 1-[2-(vinyloxy)ethyl]pyrroles. 相似文献
2-Methyleneindolines containing benzazole residues at the 5-position were synthesized and polymethine dyes were obtained from them. The bathochromic shifts induced by the introduction of heterocyclic residues into indocyanines exceed the similar shifts induced by the same heterocycles in thio and quinocyanines.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1050–1054, August, 1990. 相似文献
Absorption, luminescence excitation and emission spectra of nine compounds from 4,8,4'-trimethylpsoralen, 4,4'-dimethylangelicin, and 1,2,3,4-tetrahydrocarbazole series with various terminal substituents were studied in water and 2-propanol. Proceeding from the data obtained in the present and also some previous studies we have formulated the main rules concerning a general mechanism of changes in the fluorescence characteristics of DNA-specific dyes depending on their chemical structure, substrate properties, and measurement medium. 相似文献
The reaction of 3-formylchromone with quaternary salts of nitrogen heterocycles containing active methyl or methylene groups was investigated. It is shown that the compounds obtained can be used in the synthesis of merocyanine dyes containing an o-hydroxybenzoyl substituent in the polymethine chain. Dicarbocyanines with such a substituent were not isolated, evidently because of the high electrophilicity of the polymethine chain and the ease of formation of a six-membered heteroring.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 9, pp. 1271–1275, September, 1990. 相似文献