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排序方式: 共有65条查询结果,搜索用时 31 毫秒
1.
Warnick KF Francom SJ Humble PH Kelly RT Woolley AT Lee ML Tolley HD 《Electrophoresis》2005,26(2):405-414
The class of equilibrium gradient methods utilizes the opposition of two forces, at least one of which changes in magnitude with position, to separate and concentrate analytes. The drawback of many methods of this type is that the production of two opposing forces requires in comparison to standard methods, such as capillary electrophoresis, a relatively complex apparatus. In addition, for techniques such as electric field gradient focusing, hydrodynamic flow leads to Taylor dispersion, which limits the attainable concentration factor. We propose a new method, gradient field electrophoresis, which achieves analyte separation and focusing with only one spatially varying force, an electric field gradient. A model for the method is developed and used to analyze peak capacity. Experimental results for a protein (R-phycoerythrin) are given and compared to the model. 相似文献
2.
Bekzat ABDIKADYR Alp KILI Onur ALEV Serkan BÜYÜKK
SE Zafer Ziya
ZTÜRK 《Turkish Journal of Chemistry》2021,45(2):295
Pristine and WO3 decorated TiO2 nanorods (NRs) were synthesised to investigate n-n-type heterojunction gas sensing properties. TiO2 NRs were fabricated via hydrothermal method on fluorine-doped tin oxide coated glass (FTO) substrates. Then, tungsten was sputtered on the TiO2 NRs and thermally oxidised to obtain WO3 nanoparticles. The heterostructure was characterised by X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive X-ray (EDX) spectroscopy. Fabricated sensor devices were exposed to VOCs such as toluene, xylene, acetone and ethanol, and humidity at different operation temperatures. Experimental results demonstrated that the heterostructure has better sensor response toward ethanol at 200 °C. Enhanced sensing properties are attributed to the heterojunction formation by decorating TiO2 NRs with WO3. 相似文献
3.
Samuel W. Foster Xiaofeng Xie Michelle Pham Paul A. Peaden Leena M. Patil Luke T. Tolley Paul B. Farnsworth H. Dennis Tolley Milton L. Lee James P. Grinias 《Journal of separation science》2020,43(9-10):1623-1627
A newly developed portable capillary liquid chromatograph was investigated for the separation of various pharmaceutical and illicit drug compounds. The system consists of two high‐pressure syringe pumps capable of delivering capillary‐scale flow rates at pressures up to 10 000 psi. Capillary liquid chromatography columns packed with sub‐2 μm particles are housed in cartridges that can be inserted into the system and easily connected through high‐pressure fluidic contact points by simply applying a specific, predetermined torque rather than using standard fittings and less precise sealing protocols. Several over‐the‐counter analgesic drug separations are demonstrated, along with a simple online measurement of tablet dissolution. Twenty illicit drug compounds were also separated across six targeted drug panels. The results described in this study demonstrate the capability of this compact liquid chromatography instrument to address several important drug‐related applications while simplifying system operation, and greatly reducing solvent usage and waste generation essential for onsite analysis. 相似文献
4.
5.
With the intention of determining the local thickness within a crystalline thin foil specimen, by means of transmission electron microscopy (TEM), a method previously proposed by Zuo and Shi [J.M. Zuo, Y.F. Shi, Microsc. Microanal. 7 (Suppl. 2) (2001) 224-225] was applied. Using the convergent beam technique, with the incident beam parallel to a zone axis with low indices, diffraction patterns were obtained for some aluminum alloys with low solute content. These patterns were contrasted with those obtained from simulations based on the dynamic theory with Bloch's waves formalism. The local thickness of the thin foil was then obtained by visually comparing the simulated patterns with the experimental one.Comparison of the proposed method with that based on the analysis of two-beam convergent beam patterns [P.M. Kelly, A. Jostsons, R.G. Blake, J.G. Napier, Phys. Stat. Solidi (a) 31 (1975) 771-780] and with that based on the ratio of intensity of the zero loss peak to the total intensity in an electron energy loss spectrum [R.F. Egerton, Electron Energy Loss Spectroscopy in the Electron Microscope, second ed., Plenum Press, New York, 1996] was carried out. A very good agreement between thicknesses determined using the different methods was found. The sensitivity of the method of Zuo et al. was found to be about 1 or 2 nm. The advantages and limitations of the different methods are discussed. The method of Zuo et al. can provide fast and reliable results and can be applied in all modern instruments. 相似文献
6.
Xuan J Hamblin MN Stout JM Tolley HD Maynes RD Woolley AT Hawkins AR Lee ML 《Journal of chromatography. A》2011,1218(50):9102-9110
An array of parallel planar nanochannels containing two or three segments with varying inner heights was fabricated and used for size fractionation of inorganic and biological nanoparticles. A liquid suspension of the particles was simply drawn through the nanochannels via capillary action. Using fluorescently labeled 30 nm polyacrylonitrile beads, different trapping behaviors were compared using nanochannels with 200-45 nm and 208-54-30 nm height segments. Addition of sodium dodecyl sulfate (SDS) surfactant to the liquid suspension and application of an AC electric field were shown to aid in the prevention of channel clogging. After initial particle trapping at the segment interfaces, significant particle redistribution occurred when applying a sinusoidal 8V peak-to-peak oscillating voltage with a frequency of 150 Hz and DC offset of 4V. Using the 208-54-30 nm channels, 30 nm hepatitis B virus (HBV) capsids were divided into three fractions. When the AC electric field was applied to this trapped sample, all of the virus particles passed through the interfaces and accumulated at the channel ends. 相似文献
7.
P. Janssens M. D. Tolley 《Zeitschrift für Angewandte Mathematik und Physik (ZAMP)》1979,30(2):234-242
Summary The purpose of the paper is to indicate some elementary applications of a method for the resolution of elliptic problems. The method consists in fitting solutions obtained in several subdomains and depending on arbitrary constants. One of the interests of the method is that it seems particularly efficient in the case of singularities. An application to the bending of triangular and parallelogramic plates is given.
Dédié au Professeur E. Stiefel, avec notre entière reconnaissance 相似文献
Résumé Les auteurs se proposent d'exposer sur quelques cas simples une méthode de résolution pour des problèmes elliptiques. La méthode, qui consiste à raccorder en certains points choisis diverses solutions obtenues dans des sous-domaines, semble particulièrement efficace pour traiter des problèmes présentant des singularités. La méthode est appliquée à titre d'exemple à la flexion de plaques triangulaires ou en forme de paralléllogrammes.
Dédié au Professeur E. Stiefel, avec notre entière reconnaissance 相似文献
8.
Austin DE Peng Y Hansen BJ Miller IW Rockwood AL Hawkins AR Tolley SE 《Journal of the American Society for Mass Spectrometry》2008,19(10):1435-1441
In radiofrequency ion traps, electric fields are produced by applying time-varying potentials between machined metal electrodes.
The electrode shape constitutes a boundary condition and defines the field shape. This paper presents a new approach to making
ion traps in which the electrodes consist of two ceramic discs, the facing surfaces of which are lithographically imprinted
with sets of concentric metal rings and overlaid with a resistive material. A radial potential function can be applied to
the resistive material such that the potential between the plates is quadrupolar, and ions are trapped between the plates.
The electric field is independent of geometry and can be optimized electronically. The trap can produce any trapping field
geometry, including both a toroidal trapping geometry and the traditional Paul-trap field. Dimensionally smaller ion trajectories,
as would be produced in a miniaturized ion trap, can be achieved by increasing the potential gradient on the resistive material
and operating the trap at higher frequency, rather than by making any physical changes to the trap or the electrodes. Obstacles
to miniaturization of ion traps, such as fabrication tolerances, surface smoothness, electrode alignment, limited access for
ionization or ion injection, and small trapping volume are addressed using this design. 相似文献
9.
Masumi Asakawa Peter R. Ashton Vincenzo Balzani Alberto Credi Christoph Hamers Gunter Mattersteig Marco Montalti Andrew N. Shipway Neil Spencer J. Fraser Stoddart Malcolm S. Tolley Margherita Venturi Andrew J. P. White David J. Williams 《Angewandte Chemie (International ed. in English)》1998,37(3):333-337
A mechanical switch in a [2]catenane , made up of a cyclobis(paraquat-p-phenylene) tetracation interlocked with a macrocyclic polyether containing a redox-active tetrathiafulvalene (TTF) unit and a 1,5-dioxynaphthalene ring system, can be thrown either chemically or electrochemically. The neutral TTF unit resides “inside” the tetracationic cyclophane in the reduced state and “alongside” it in the oxidized species (TTF+/ TTF2+). Switching between the reduced (I4+) and oxidized state (I5+(I6+)) is accompanied by a dramatic color change. 相似文献
10.
Xuefei Sun Dan Li Adam T. Woolley Paul B. Farnsworth H. Dennis Tolley Karl F. Warnick Milton L. Lee 《Journal of chromatography. A》2009,1216(37):6532-6538
Electric field gradient focusing (EFGF) uses an electric field gradient and a hydrodynamic counter flow to simultaneously separate and focus charged analytes in a channel. Previously, most EFGF devices were designed to form a linear field gradient in the channel. However, the peak capacity obtained using a linear gradient is not much better than what can be obtained using conventional CE. Dynamic improvement of peak capacity in EFGF can be achieved by using a nonlinear gradient. Numerical simulation results indicate that the peak capacity in a 4-cm long channel can be increased from 20 to 150 when changing from a linear to convex bilinear gradient. To demonstrate the increased capacity experimentally, an EFGF device with convex bilinear gradient was fabricated from poly(ethylene glycol) (PEG)-functionalized acrylic copolymers. The desired gradient profile was confirmed by measuring the focusing positions of a standard protein for different counter flow rates at constant voltage. Dynamically controlled elution of analytes was demonstrated using a monolith-filled bilinear EFGF channel. By increasing the flow rate, stacked proteins that were ordered but not resolved after focusing in the steep gradient segment were moved into the shallow gradient segment, where the analyte peak resolution increased significantly. In this way, the nonlinear field gradient was used to realize a dynamic increase in the peak capacity of the EFGF method. 相似文献