Synergistic Activities in the Ullmann Coupling of Chloroarenes at Ambient Temperature by Pd‐Supported Calcined Ferrocenated La2O3

Novel palladium‐doped nanoparticles have been explored to serve as the first metal oxide‐derived heterogeneous catalyst for Ullmann reaction of chloroarenes under mild condition (34 °C). This heterogeneous catalyst exhibited high catalytic activity towards the Ullmann homocoupling of chloroarenes into a series of useful symmetrically biaryl products with good to excellent yields in the presence of ethanol and NaOH, thereby leading to green and economical Ullmann reaction. The produced nanoparticles were successfully characterized by various techniques including PXRD, XPS, HRTEM, SEM‐EDS, BET, TGA techniques, elemental mapping analysis and ICP‐OES. Interestingly, based on characterization and experimental data, a reasonable mechanism has been proposed. Also, the formation of aryl methyl ketone as a by‐product has been further confirmed by isotopic labelling experiments that the acetyl moiety is derived from ethanol. Moreover, the catalyst was stable and could be easily reused up to 5 times under atmospheric air without suffering significant loss in catalytic activity.     

Net-Proton Nonstatistical Moments in High-Energy pp Collisions in PACIAE Model

The parton and hadron cascade model, PACIAE 2.0, is employed to calculate the net-proton nonstatistical moments in pp collisions at RHIC and LHC energies. By analyzing the results in the full phase space, it is found that the nonstatistical moments and moments products are significantly dependent on the collision energy. It is suggested that the net-proton nonstatistical moments in pp collisions may be studied in partial phase spaces with the PACIAE model.