全文获取类型
收费全文 | 194篇 |
免费 | 2篇 |
专业分类
化学 | 145篇 |
晶体学 | 1篇 |
力学 | 3篇 |
数学 | 4篇 |
物理学 | 43篇 |
出版年
2023年 | 1篇 |
2021年 | 3篇 |
2020年 | 1篇 |
2019年 | 5篇 |
2017年 | 1篇 |
2016年 | 1篇 |
2015年 | 1篇 |
2014年 | 3篇 |
2013年 | 6篇 |
2012年 | 11篇 |
2011年 | 15篇 |
2010年 | 6篇 |
2009年 | 5篇 |
2008年 | 13篇 |
2007年 | 19篇 |
2006年 | 13篇 |
2005年 | 9篇 |
2004年 | 8篇 |
2003年 | 14篇 |
2002年 | 13篇 |
2001年 | 4篇 |
2000年 | 5篇 |
1999年 | 3篇 |
1998年 | 1篇 |
1997年 | 2篇 |
1996年 | 2篇 |
1995年 | 2篇 |
1993年 | 6篇 |
1992年 | 2篇 |
1991年 | 3篇 |
1990年 | 3篇 |
1986年 | 1篇 |
1985年 | 2篇 |
1982年 | 3篇 |
1980年 | 4篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1973年 | 1篇 |
1932年 | 1篇 |
1931年 | 1篇 |
排序方式: 共有196条查询结果,搜索用时 15 毫秒
1.
Dr. Yogesh Kumar Maurya Dr. Pingchun Wei Takahide Shimada Dr. Kazuhisa Yamasumi Dr. Shigeki Mori Prof. Dr. Ko Furukawa Dr. Hajime Kusaba Prof. Dr. Tatsumi Ishihara Prof. Dr. Yongshu Xie Dr. Masatoshi Ishida Prof. Dr. Hiroyuki Furuta 《化学:亚洲杂志》2021,16(7):743-747
A facile synthetic strategy towards conformationally stable chiral chromophores based on dimeric porphyrinoids has been established. A peculiar class of face-to-face intramolecularly interlocked corrole dimers were formed by the oxidative C−C coupling linked at the inner carbon sites upon simple treatment of copper(II) ions. Their intrinsic electronic structures were modulated by the peripheral corrole ring annulations, which lead to distinct optical properties and redox profiles. The stereogenic carbon centers implemented in the confused corrole skeleton provided a rationale for designing novel chiral materials. 相似文献
2.
Sontaya Limmatvapirat Etsuo Yonemochi Toshio Oguchi Keiji Yamamoto 《Journal of inclusion phenomena and macrocyclic chemistry》1998,31(4):367-379
A complex between deoxycholic acid (DCA) and salicylic acid (SA) was prepared by grinding and coprecipitation methods. The resultant complex was characterized by means of powder X-ray diffractometry, IR spectroscopy and thermal analysis. The stoichiometry (DCA : SA 1 : 1) of the complex obtained by grinding was identical to that obtained by coprecipitation. The powder X-ray diffraction pattern of the DCA–SA complex differed from the typical pattern of DCA–guest complexes such as DCA–camphor and DCA–phenanthrene complexes. IR spectra suggested that a different kind of hydrogen bonding was formed in the crystal of the DCA–SA complex, compared with the other DCA–guest complexes. This was in good agreement with data from the crystal structure. 相似文献
3.
Oguchi T Tozuka Y Hanawa T Mizutani M Sasaki N Limmatvapirat S Yamamoto K 《Chemical & pharmaceutical bulletin》2002,50(7):887-891
The solid-state complexation between cholic acid (CA) and either methyl p-hydroxybenzoate (MPB) or ibuprofen (IBP) was investigated. Powder X-ray diffractometry, IR spectroscopy and thermal analysis suggested the complex formation between CA and MPB as well as between CA and IBP by co-grinding method. The stoichiometry of CA-MPB was 1 : 1 while that of CA-IBP was 2 : 1, reflecting the effect of guest size on complex formation. The guest compounds were assumed to be included in the channel of complexes formed by hydrogen bonds among CA molecules. 相似文献
4.
Yoshitaka Uenoyama Takahide Fukuyama Keisuke Morimoto Osamu Nobuta Hidefumi Nagai Ilhyong Ryu 《Helvetica chimica acta》2006,89(10):2483-2494
The carbonylation of alkanes 1 under radical‐reaction conditions was examined by using ethynyl triflone A as the unimolecular chain‐transfer (UMCT) reagent. Good to moderate yields of ethynyl ketones 2 were prepared by means of this three‐component coupling reaction. Higher CO pressures as well as lower concentrations of triflone A improved the efficiency of the reaction over the direct addition, the latter leading to alkylated ethynes 3 . In contrast to the reaction with A , the reaction of cyclohexane ( 1a ) with allyl triflone B (= ethyl 2‐methylene‐3‐[(trifluoromethyl)sulfonyl]propanoate) in the presence of CO gave a mixture of carbonylation products, including 8a formed from two molecules each of cyclohexane, CO, and allyl triflone B . 相似文献
5.
Influence of isosorbide dinitrate concentration on its skin permeability from adhesive matrix devices. 总被引:2,自引:0,他引:2
T Hatanaka M Oguchi K Sugibayashi Y Morimoto 《Chemical & pharmaceutical bulletin》1991,39(7):1802-1805
Adhesive matrix devices containing a model drug, isosorbide dinitrate (ISDN), were prepared with three different types of pressure sensitive adhesives (PSAs). ISDN permeation through excised hairless rat skin from the different devices was measured in vitro. For each PSA type, the steady state permeation rate of ISDN increased proportionally with an increase of ISDN concentration in the PSA and reached a maximum level at a certain concentration. Although the concentrations reaching the maximum skin permeation level varied among PSA types, the maximum rate for each PSA type was largely similar to that for ISDN aqueous suspension. The release rate of ISDN from devices was too fast to influence the skin permeation rate for all devices. In the PSA of devices showing maximum skin permeability, ISDN crystalline was observed by polarizing microscopy and differential scanning calorimetry. These results suggest that the skin permeation of ISDN from adhesive matrix devices was controlled by the thermodynamic activity of the drug in the PSAs. 相似文献
6.
Tojino M Uenoyama Y Fukuyama T Ryu I 《Chemical communications (Cambridge, England)》2004,(21):2482-2483
Free-radical carbonylation of omega-alkynylamines with tributyltin hydride gives a mixture of alpha-methylene lactams and alpha-stannylmethylene lactams. Nucleophilic addition of an internal amino group to the carbonyl group of alpha-ketenyl radicals is proposed as the cyclization step. The subsequent unusual 1,4-H shift from the resulting 1-hydroxyallyl radical, followed by elimination of the beta-tributyltin radical leads to the formation of alpha-methylene lactams. 相似文献
7.
Characterization of clarithromycin polymorph was performed by solid-state cross polarization and magic angle spinning (CP/MAS) 13C-NMR spectroscopy. Two polymorphs, form II and form I, of clarithromycins indicated characteristic resonances of C1 carbonyl carbon at 176.2 and 175.2 ppm, respectively. Since each peak of C1 carbon was well separated in the spectrum of the two polymorphs, we performed quantitative analysis of the polymorphic fraction from the peak area of these peaks. The peak area of form I was found to linearly increase with an increase of its content, with a correlation coefficient of above 0.99. Solid-state NMR was found to be a useful technique to determine the characteristics of the polymorphic forms. 相似文献
8.
Moribe K Tsuchiya M Tozuka Y Yamaguchi K Oguchi T Yamamoto K 《Chemical & pharmaceutical bulletin》2004,52(5):524-529
We prepared and characterized a grinding-induced equimolar complex of thiourea with ethenzamide. When thiourea and ethenzamide were co-ground at a molar ratio of 3 : 1, new powder X-ray diffraction (PXRD) peaks were observed in addition to PXRD peaks of thiourea crystals. The optimum stoichiometry of the new structure was confirmed as 1 : 1 mol/mol. Effect of grinding time on the thiourea-ethenzamide equimolar complex formation was investigated by using PXRD, differential scanning calorimetry and Fourier transform infrared spectroscopy. The equimolar crystal structure was confirmed by X-ray diffraction measurements of the single crystal which was recrystallized from ethanol. It was found that the intermolecular hydrogen bond formations between thiourea and ethenzamide molecules contributed to the equimolar complex formation. The complex formation was not observed in the cases where benzamide, salicylamide or 3-ethoxybenzamide was co-ground with thiourea. 2-Alcoxyl benzamide structures should be required for the grinding-induced equimolar complex formation with thiourea. 相似文献
9.
Fukuyama T Yamaura R Higashibeppu Y Okamura T Ryu I Kondo T Mitsudo TA 《Organic letters》2005,7(26):5781-5783
[reaction: see text] Catalytic [2 + 2 + 1 + 1] cocyclization reaction of an alkyne, an alkene, and two molecules of carbon monoxide, leading to functionalized hydroquinones, was studied. Using [Cp*RuCl2]2 as a catalyst, we found that a variety of electron-deficient alkenes, such as alpha,beta-unsaturated ketones, esters, amides, and nitriles, can be employed as an alkene coupling partner to give the corresponding hydroquinones. 相似文献
10.
Reaction steps and mechanisms of the thermal dehydration of lithium metaborate dihydrate were investigated by means of thermoanalytical measurements, high temperature powder X-ray diffractometry, FT-IR spectroscopy, and microscopic observations. The first half of thermal dehydration was characterized by the melting of the sample producing viscous surface layer, the formation of bubbles on the particle surfaces, and the sudden mass-loss taking place by an opportunity of cracking and/or bursting of the bubble surface layer. The second half of the dehydration with a long-tailed mass-loss process in a wide temperature region was divided further into three distinguished reaction steps by the measurements of controlled rate thermal analysis. During the course of the thermal dehydration, four different poorly crystalline phases of intermediate hydrates were observed, in addition to an amorphous phase produced by an isothermal annealing. Just after completing the thermal dehydration, an exothermic DTA peak of the crystallization of β-LiBO2 was appeared at around 750 K. The phase transition from β-LiBO2 to α-LiBO2 was observed in the temperature range of 800-900 K, which subsequently melted by indicating a sharp endothermic DTA peak with the onset temperature at 1101.4 ± 0.6 K. 相似文献