Loss of isocyanic acid from the internal oxadiazole ring of protonated molecules of some 2,5-diaryl-1,3,4-oxadiazoles

The fragmentation pattern of some protonated 2,5-diaryl-1,3,4-oxadiazoles is discussed. An unusual decomposition consisting of elimination of the isocyanic acid molecule from the internal oxadiazole ring was found. This fragmentation pathway was deduced on the basis of B/E linked scan mass spectra of metastable ions with liquid secondary ion mass spectrometry as the ionization method and also of low-energy CID mass spectra where electrospray was used as the ionization technique. High resolution measurements were also performed.     

The abundances of fragment ions formed via skeletal rearrangements from 2,5-disubstituted-1,3,4-oxadiazoles and their theoretical calculated stabilities

Protonated molecules of 2,5-di-R1,R2-substituted-1,3,4-oxadiazoles lose isocyanic acid (loss of mass 43) via skeletal rearrangement. This was observed in low-energy CID mass spectra recorded by using electrospray ionisation (ESI). On electron ionisation induced decomposition these compounds also reveal complex skeletal rearrangement, consisting on N2 and CO elimination, leading to the formation of fluorene or indene type ions. It was found that abundances of fragment ions formed in these processes are in good agreement with their theoretically calculated stabilities. In the case of ESI use the fragment ion abundances were calculated in relation to [M+H]+ ion abundances and for EI use, where extensive fragmentations proceed, the sums of the abundances of [M-N2-CO]+. ions and abundances of fragment ions derived from them, were expressed as a percentage of total-ion current.     

铁镍钴矩磁合金的铁心损耗

本文研究了经过纵向磁退火的铁镍钴合金带的铁心损耗,发现P/f-f曲线具有明显的反常行为。用180°畴壁移的反常涡流损耗理论模型做了解释。并提出一些减小损耗的可能途径。     

交直流叠加磁化下恒导磁薄片的反常涡流损耗

本文利用一致畴转模型分析了在交直流叠加磁化下恒导磁薄片的低频涡流损耗。指出涡流损耗的反常不仅壁移,而且同样存在于畴转。其原因是畴转过程中畴内磁导率是张量,从而比经典模型增加了一项“侧向涡流”。导出了转动涡流损耗反常系数η_r的表达式;并将结果在某些应用领域中作了推广,得出了相应的结论。     

Mass spectrometric study of some protonated and lithiated 2,5-disubstituted-1,3,4-oxadiazoles

The mass spectrometric behavior of lithiated derivatives of 2,5-disubstituted-1,3,4-oxadiazoles has confirmed the skeletal rearrangement presented earlier for protonated derivatives. In the case of [M + H](+) ions the loss of isocyanic acid was observed and for [M + Li](+) ions the loss of lithium isocyanate occurred. On the other hand, benzoyl ions [RCO](+) were formed from [M + H](+) ions, but not from [M + Li](+) ions. Formation of benzoyl ions was in agreement with the differences between bond orders calculated for [M + H](+) ions and neutral molecules. From [M + Li](+) ions the [RCNLi](+) fragment ions were formed, but the formation of [RCNH](+) fragment ions from [M + H](+) ions was not observed. This result can be explained on the basis of theoretically calculated stabilities of these fragment ions, since the calculated heats of formation of [RCNLi](+) ions were found to be substantially lower than those of the respective [RCNH](+) ions.     

高合金钢光谱分析准确度改进试验

在我国钢铁厂中,高合金钢的光谱分析受到准确度的限制,没有普遍展开。通过对两种有代表性的高合金钢,即P18高速钢及Я1不锈钢的试验,证明用摄谱方法采取种种改进以后,高合金钢的分析约可达到最小的百分均方误差1％左右。文中对某些工厂的先进经验曾加以介绍。对于高合金钢的准确度问题曾予讨论。