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排序方式: 共有175条查询结果,搜索用时 15 毫秒
1.
Surajit Some 《Tetrahedron letters》2006,47(7):1221-1224
A convenient synthetic approach to substituted benzene derivatives by modified Ullmann cross-coupling of 2-bromobenzaldehyde and bromovinylaldehydes followed by intramolecular McMurry coupling has been developed. 相似文献
2.
Surajit Sen 《Physica A》2006,360(2):304-324
There are very few formalisms available to solve the Liouville equation for energy-conserved systems. The continued fraction formalism, introduced through the works of Zwanzig, Mori, Kubo, Lee, Grigolini and others is described here. A detailed discussion is presented on ways to apply the continued fraction formalism to solve for relaxation functions and for the dynamical variable itself for a simple and exactly solvable quantum spin system. 相似文献
3.
4.
Debprasad Patra Poulami Pattanayak Jahar Lal Pratihar Surajit Chattopadhyay 《Polyhedron》2007,26(18):5484-5490
The reactions of HL 1 [where HL is 1N-(2-pyridyl-2-methyl)-2-arylazoaniline and is formulated as ArN = NC6H4N(H)(CH2C5H4N); Ar = C6H5 (for HL1) or p-MeC6H4 (for HL2) or p-ClC6H4 (for HL3)] with K2PtCl4 and Co(ClO4)3 · 6H2O afforded the (L)PtCl and [(L)2Co]ClO4 complexes, respectively. The HL ligands bind the platinum(II) and cobalt(III) centres in a tridentate (N,N,N) fashion, forming new diazoketiminato chelates upon dissociating the amino proton. The X-ray structures of (L3)PtCl and [(L3)2Co]ClO4 were determined. Redox properties of the new complexes have been examined. 相似文献
5.
Cellulose - In this study, a novel bioinspired deep eutectic solvent (DES) was synthesized and functionalized with graphene to prepare G-DES. DES was synthesized in the presence of choline chloride... 相似文献
6.
Marta Martino Andrea Salvadori Federico Lazzari Lorenzo Paoloni Surajit Nandi Giordano Mancini Vincenzo Barone Sergio Rampino 《Journal of computational chemistry》2020,41(13):1310-1323
The virtual-reality framework AVATAR (Advanced Virtual Approach to Topological Analysis of Reactivity) for the immersive exploration of potential-energy landscapes is presented. AVATAR is based on modern consumer-grade virtual-reality technology and builds on two key concepts: (a) the reduction of the dimensionality of the potential-energy surface to two process-tailored, physically meaningful generalized coordinates, and (b) the analogy between the evolution of a chemical process and a pathway through valleys (potential wells) and mountain passes (saddle points) of the associated potential energy landscape. Examples including the discovery of competitive reaction paths in simple A + BC collisional systems and the interconversion between conformers in ring-puckering motions of flexible rings highlight the innovation potential that augmented and virtual reality convey for teaching, training, and supporting research in chemistry. 相似文献
7.
AC Conduction and Time–Temperature Superposition Scaling in a Reduced Graphene Oxide–Zinc Sulfide Nanocomposite 下载免费PDF全文
Koushik Chakraborty Poulomi Das Sankalpita Chakrabarty Dr. Tanusri Pal Dr. Surajit Ghosh 《Chemphyschem》2016,17(10):1518-1523
We report, herein, the results of an in depth study and concomitant analysis of the AC conduction [σ′(ω): f=20 Hz to 2 MHz] mechanism in a reduced graphene oxide–zinc sulfide (RGO–ZnS) composite. The magnitude of the real part of the complex impedance decreases with increase in both frequency and temperature, whereas the imaginary part shows an asymptotic maximum that shifts to higher frequencies with increasing temperature. On the other hand, the conductivity isotherm reveals a frequency‐independent conductivity at lower frequencies subsequent to a dispersive conductivity at higher frequencies, which follows a power law [σ′(ω)∝ωs] within a temperature range of 297 to 393 K. Temperature‐independent frequency exponent ′s′ indicates the occurrence of phonon‐assisted simple quantum tunnelling of electrons between the defects present in RGO. Finally, this sample follows the “time–temperature superposition principle”, as confirmed from the universal scaling of conductivity isotherms. These outcomes not only pave the way for increasing our elemental understanding of the transport mechanism in the RGO system, but will also motivate the investigation of the transport mechanism in other order–disorder systems. 相似文献
8.
Synthesis of five-, six-, seven-, eight-, and nine-membered cyclic α-hydrazino acids from a common starting material ‘diethylmalonate’ with 26, 16, 34, 13.5, and 13.33% overall yields is described. Sequential allylation or homoallylation and electrophilic amination followed by cyclization gave the desired rings. The methyl esters of eight- and nine-membered rings were synthesized by RCM and the corresponding free acids were generated after hydrolysis in the presence of 1 M BBr3 solution in DCM. 相似文献
9.
Anindya Datta Amitava Raychaudhuri Sreerup Raychaudhuri Surajit Chakrabarti 《Zeitschrift fur Physik C Particles and Fields》1996,72(3):449-460
Many extensions of the Standard Model includeSU(2) L ×U(1) Y singlet higgs bosons,h 0, and also vector-like fermions which couple to it. The production and detection possibilities of such singlet neutral scalars at hadron colliders are considered for different scenarios of vectorlike fermions. We find that for some values of masses and couplings, detection at the CERN large hadron collider (LHC) appears to be a distinct possibility, while at the Fermilab Tevatron upgrade theh 0 might be observed only in very favourable circumstances. 相似文献
10.
Surajit?Dasgupta Neven?Bilic Tapas?K.?DasEmail author 《General Relativity and Gravitation》2005,37(11):1877-1890
We demonstrate that a spherical accretion onto astrophysical black holes, under the influence of Newtonian or various post-Newtonian
pseudo-Schwarzschild gravitational potentials, may constitute a concrete example of classical analogue gravity naturally found
in the Universe. We analytically calculate the corresponding analogue Hawking temperature as a function of the minimum number
of physical parameters governing the accretion flow. We study both the polytropic and the isothermal accretion. We show that
unlike in a general relativistic spherical accretion, analogue white hole solutions can never be obtained in such post-Newtonian
systems. We also show that an isothermal spherical accretion is a remarkably simple example in which the only one information–the
temperature of the fluid, is sufficient to completely describe an analogue gravity system. For both types of accretion, the
analogue Hawking temperature may become higher than the usual Hawking temperature. However, the analogue Hawking temperature
for accreting astrophysical black holes is considerably lower compared with the temperature of the accreting fluid. 相似文献