全文获取类型
收费全文 | 1717篇 |
免费 | 69篇 |
国内免费 | 3篇 |
专业分类
化学 | 1450篇 |
晶体学 | 7篇 |
力学 | 10篇 |
数学 | 94篇 |
物理学 | 228篇 |
出版年
2023年 | 11篇 |
2021年 | 33篇 |
2020年 | 26篇 |
2019年 | 32篇 |
2018年 | 17篇 |
2017年 | 15篇 |
2016年 | 46篇 |
2015年 | 32篇 |
2014年 | 43篇 |
2013年 | 66篇 |
2012年 | 104篇 |
2011年 | 117篇 |
2010年 | 56篇 |
2009年 | 45篇 |
2008年 | 90篇 |
2007年 | 93篇 |
2006年 | 83篇 |
2005年 | 64篇 |
2004年 | 63篇 |
2003年 | 50篇 |
2002年 | 51篇 |
2001年 | 23篇 |
2000年 | 21篇 |
1999年 | 20篇 |
1998年 | 15篇 |
1997年 | 13篇 |
1996年 | 24篇 |
1995年 | 14篇 |
1994年 | 20篇 |
1993年 | 14篇 |
1992年 | 23篇 |
1991年 | 16篇 |
1990年 | 13篇 |
1988年 | 15篇 |
1987年 | 15篇 |
1986年 | 12篇 |
1984年 | 12篇 |
1983年 | 9篇 |
1982年 | 11篇 |
1981年 | 12篇 |
1979年 | 16篇 |
1978年 | 12篇 |
1977年 | 20篇 |
1976年 | 13篇 |
1974年 | 9篇 |
1973年 | 11篇 |
1969年 | 11篇 |
1968年 | 26篇 |
1967年 | 72篇 |
1966年 | 17篇 |
排序方式: 共有1789条查询结果,搜索用时 728 毫秒
1.
C. H. Hesse 《Statistical Inference for Stochastic Processes》2007,10(1):75-95
In this work the Cauchy problem for the one-dimensional heat equation is considered. In contrast to existing literature it
is assumed that the initial state f is unknown and that information regarding f is obtained by some process of measurement. To enhance realism, both measurement errors and missing data are allowed for.
Under assumptions on f in the Fourier-domain first an approximation to f is derived from the data by means of a novel uncertainty principle. Then, it is studied how this perturbation in the initial
state propagates with time.
相似文献
2.
Worm Müller Jac G. Otto Arno Behr und O. Hesse 《Fresenius' Journal of Analytical Chemistry》1884,23(1):82-85
Ohne Zusammenfassung 相似文献
3.
Marit Seifert Stephanie Hesse Vasken Kabrelian Dieter Klemm 《Journal of polymer science. Part A, Polymer chemistry》2004,42(3):463-470
For the modification of medically useful biomaterials from bacterially synthesized cellulose, fleeces of Acetobacter xylinum have been produced in the presence of 0.5, 1.0, and 2.0% (m/v) carboxymethylcellulose (CMC), methylcellulose (MC), and poly(vinyl alcohol) (PVA), respectively, in the Hestrin-Schramm culture medium. The incorporation of the water-soluble polymers into cellulose and their influence on the structure, crystal modifications, and material properties are described. With IR and solid-state 13C NMR spectroscopy of the fleeces, the presence of the cellulose ethers and an increase in the amorphous parts of the cellulose modifications (NMR results) have been detected. The incorporation is represented by a higher product yield, too. As demonstrated by scanning electron microscopy, a porelike cellulose network structure forms in the presence of CMC and MC. This modified structure increases the water retention ability (expressed as the water content), the ion absorption capacity, and the remaining nitrogen-containing residues from the culture medium or bacteria cells. The water content of bacterial cellulose (BC) in the never dried state and the freeze-dried, reswollen state can be controlled by the CMC concentration in the culture solution. The freeze-dried, reswollen BC-CMC (2.0%) contains 96% water after centrifugation, whereas standard BC has only 73%. About 98% water is included in a BC-MC composite in the wet state, and about 93% is included in the reswollen state synthesized in the presence of 0.5, 1.0, or 2.0% MC. These biomaterial composites can be stored in the dried state and reswollen before use, reaching a higher water absorption than pure, never dried BC. The copper ion capacity of BC-CMC composites increases proportionally with the added amount of CMC. BC-CMC (0.5%) can absorb 3 times more copper ions than original BC. In the case of 0.5 and 1.0% PVA additions to the culture solution, this polymer cannot be detected in the cellulose fleeces after they are washed. Nevertheless the presence of PVA in the culture medium effects a decreased product yield, a retention of nitrogen-containing residues in the material during purification, a reduced water absorption ability, and a slightly higher copper ion capacity in comparison with original BC. The water content of freeze-dried, reswollen BC-PVA (0.5%) is only 62%. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 463–470, 2004 相似文献
4.
We prove that, in Euclidean space, any nonnegatively curved, compact, smoothly immersed hypersurface lies outside the convex hull of its boundary, provided the boundary satisfies certain required conditions. This gives a convex hull property, dual to the classical one for surfaces with nonpositive curvature. A version of this result in the nonsmooth category is obtained as well. We show that our boundary conditions determine the topology of the surface up to at most two choices. The proof is based on uniform estimates for radii of convexity of these surfaces under a clipping procedure, a noncollapsing convergence theorem, and a gluing procedure. 相似文献
5.
6.
A. Hotzel P. Thirolf Ch. Ender D. Schwalm M. Mutterer P. Singer M. Klemens J. P. Theobald M. Hesse F. Gönnenwein H. v. d. Ploeg 《Zeitschrift für Physik A Hadrons and Nuclei》1987,356(3):299-308
The γ-ray spectrum of 252Cf(sf) was measured in the Darmstadt-Heidelberg Crystal Ball spectrometer, with a double ionization chamber mounted inside to detect the fission fragments. The measurement was aimed at a better understanding of an unusual component found in the high-energy region between 3 and 8 MeV, with fragment mass splits near symmetry. This component was proved to be predominantly emitted by the heavier fragment, to reach its highest intensity at a fragment mass split of 132:120, and to have an almost isotropic angular distribution. Calculations with the statistical code CASCADE could reproduce the main features. 相似文献
7.
The specific electrical resistivityp(T) was measured for the reentrant spin glass system (Fe0.65Ni0.35)1–x
Mn
x
(0x0.102) in the temperature range 4 KT280 K. We used our own phenomenological ansatz to explain the results obtained in order to provide the fitted parameters with physical meaning. The cause of the observed minimum in the measured curves can be given by a model of local magnetism. 相似文献
8.
Benjamin A. DeGraff Mandy Hennip Julie M. Jones Carl Salter Stephanie A. Schaertel 《The Chemical Educator》2002,7(1):15-18
We describe an inexpensive modular Raman spectrometer system that can be assembled from commercial components for under $5000. Three typical applications are presented: a demonstration of a vibrational isotope effect, a Raman polarization experiment, and a resonance Raman experiment. This spectrometer system should make it easier to include the important topic of Raman spectroscopy in the undergraduate physical and analytical chemistry laboratory curricula. 相似文献
9.
Summary 2,8-Dihydroxyadeninuria and xanthinuria are inborn enzyme disorders which must be under lifelong therapeutic control. Quantitative
determination of 2,8-DHA and xanthine using reversed phase HPLC was performed. A new application for the separation of purines
shortens analysis-time. Examples of the determination of 2,8-DHA and xanthine before and under certain therapies are shown.
Long term monitoring of the patients offers the possibility of a reliable prophylaxis against stone recurrence. 相似文献
10.