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排序方式: 共有69条查询结果,搜索用时 312 毫秒
1.
G. I. Malofeeva O. M. Petrukhin B. Ya. Spivakov E. V. Poteshkina 《Journal of Analytical Chemistry》2003,58(3):211-216
Conditions of the liquid–liquid and solid-phase extraction of metal chelates are compared. The analogy and differences in the behavior of chelates and the effect of stability and partition constants on the completeness of the extraction of metals are discussed. 相似文献
2.
Solid-phase extraction (SPE) is an effective tool for the preconcentration of trace elements and their separation from various sample constituents. Octadecyl and other alkyl-bonded silica gels are most widely used for these purposes. The fundamentals of the SPE of inorganic ions are reviewed and compared with those of related techniques (liquid-liquid extraction and reversed-phase liquid chromatography). The extraction of ions in the form of chelate compounds, inorganic salts solvated by neutral reagents, and ion-pair compounds is considered. Numerous applications of SPE to the separation and preconcentration of different elements and their species, including on-line combinations with instrumental determination techniques, are described and tabulated. 相似文献
3.
O. N. Katasonova P. S. Fedotov V. K. Karandashev B. Ya. Spivakov 《Journal of Analytical Chemistry》2005,60(7):684-690
A complex procedure has been developed for evaluating the degree of soil contamination. Rotating coiled columns (RCCs) were used for both the fractionation of soil samples by their grain-size composition and the sequential extraction of heavy-metal species from silty, dusty, and sandy fractions. During the extraction of heavy-metal species, the soil fraction to be analyzed was retained in the column as a stationary phase, while aqueous solutions of extracting agents (mineral salts, acids, and complexing compounds) were sequentially pumped through the heterogeneous sample. The sequential extraction of element species from various soil fractions was carried out in the dynamic mode favorable to more complete extraction of metals. The use of RCCs allows the extraction of various heavy-metal species from soils to be performed in accordance with their grain-size composition. The process of the extraction of metal species can be automated, and in this case the losses of sample components are reduced to a minimum.__________Translated from Zhurnal Analiticheskoi Khimii, Vol. 60, No. 7, 2005, pp. 765–772.Original Russian Text Copyright © 2005 by Katasonova, Fedotov, Karandashev, Spivakov. 相似文献
4.
The assessment of conditional stability constants of aquatic humic substance (HS) metal complexes is overviewed with special emphasis on the application of ultrafiltration methods. Fundamentals and limitations of stability functions in the case of macromolecular and polydisperse metal-HS species in aquatic environments are critically discussed. The review summarizes the advantages and application of ultrafiltration for metal-HS complexation studies, discusses the comparibility and reliability of stability constants. The potential of ultrafiltration procedures for characterizing the lability of metal-HS species is also stressed. 相似文献
5.
This review surveys the progress in inorganic liquid-liquid extraction in the last 25 years. Achievements are emphasized in the theoretical foundations of the method, and in the synthesis, characterization and application of new extractants. Special attention is paid to the implementation of extraction methods and to the automation of extractive separation. The combination of liquid-liquid extraction as a method of preconcentration with the methods of subsequent determination of trace concentrations of elements is described in detail. 相似文献
6.
The effect of the nature of the extracted complex and of the organic solvent on the sensitivity of the extraction/atomic absorption determination of tin in a graphite-furnace atomizer is investigated. It is recommended that extracts of tin as its chloride complex, or chelates with N-benzoyl-N-phenylhydroxylamine or 8-quinolinol, in organic solvents which do not contain chlorine should be used. The depressive effect of the organic matrix can be significantly decreased by using ascorbic acid as matrix modifier, by atomization from a graphite platform, and by using an atomizer coated with tungsten carbide. The procedure developed is applied to the determination of tin in rocks. For tin concentrations of 0.1–10 μg g?1, the relative standard deviation does not exceed 10%. 相似文献
7.
A considerable decrease in the partial pressure of free oxygen in the gas phase within a graphite atomizer during atomization with the use of ascorbic acid as a matrix modifier was proved by using the method suggested by L'vov and Ryabchuk. A similar change in the gas-phase composition was observed in graphite tubes treated with compounds of refractory metals. A mechanism for this oxygen binding is suggested. It is shown that the sensitivity of the determination of tin is improved by decreasing the free oxygen content of the gas phase. 相似文献
8.
Dialkyltin salts are suitable as extractants for various oxygen-containing anions. They are particulary powerful for the extraction of arsenate and phosphate ions, but are also useful for liquid-liquid extraction of anions of dibasic acids. It is shown that the high extraction power of these dialkyltin complexes can be explained by formation of innersphere complexes with the extracted anions. A method is proposed for the separation of arsenic, phosphorus and silicon using dialkyltin salts. Applications to the extraction-spectrophotometric determination of phosphorus and arsenic in vanadium and steel, and to extraction/atomic absorption determinations of arsenic and phosphorus in metals and alloys are surveyed. The use of the dialkyltin salts for the neutron activation determination of arsenic and as active components in membranes of ion-selective electrodes for phosphorus(V) and arsenic(V) is demonstrated. 相似文献
9.
T. I. Zvarova V. M. Shkinev G. A. Vorob'eva B. Ya. Spivakov Yu. A. Zolotov 《Mikrochimica acta》1984,84(5-6):449-458
Summary Capabilities of liquid-liquid extraction systems without organic solvents have been examined. Ternary poly(ethylene glycol)-inorganic salt-water systems have been proposed for extraction of complexes of metals with water-soluble organic reagents and inorganic ligands.Phase diagrams for such two-phase systems have been studied. The distribution of some inorganic ions and organic reagents in PEG 2000-ammonium sulphate systems has been examined at different pH values of the salt-phase. It is shown that the distribution coefficients are lower than unit for all the cations studied while reagents, containing aromatic rings, are extracted into the PEG-phase with distribution coefficients higher than one hundred. Conditions are reported which provide effective extraction of iron(III) in presence of several water-soluble photometric reagents. Extraction in the PEG 2000-ammonium sulphate-water system in presence of ammonium thiocyanate and sulphuric acid has been studied. Copper, zinc, cobalt, iron(III), indium, molybdenum(V) are extracted into the PEG-phase with high distribution coefficients.
The paper has been presented at the Fifth European Conference on Analytical Chemistry (Euroanalysis V), Cracow, August 26–31, 1984. 相似文献
Flüssig-flüssig-Extraktion ohne übliche organische Lösungsmittel: Anwendung wäriger Zweiphasen-Systeme mit einem wasserlöslichen Polymerisat
Zusammenfassung Die Eignung von Flüssig-flüssig-Extraktions-Systemen ohne organisches Lösungsmittel wurde geprüft. Ternäre Systeme aus Polyethylenglykol-anorganischem Salz-Wasser wurden für die Extraktion von Metallkomplexen mit wasserlöslichen organischen Reagenzien und anorganischen Liganden vorgeschlagen.Die Phasendiagramme solcher Zwei-Phasen-Systeme wurden untersucht. Die Verteilung einiger anorganischer Ionen und organischer Reagenzien in Polyethylenglykol (PEG) 2000-Ammoniumsulfat-Systemen wurde bei verschiedenem pH der Salzphase geprüft. Dabei ergab sich, daß die Verteilungskoeffizienten für alle untersuchten Kationen geringer sind als eins, während Reagenzien, die einen aromatischen Ring enthalten, in die PEG-Phase mit Verteilungskoeffizienten über 100 extrahiert werden. Versuchsbedingungen für die wirkungsvolle Extraktion von Fe(III) in Gegenwart verschiedener wasserlöslicher photometrischer Reagenzien wurden angegeben. Die Extraktion mit PEG 2000-Ammoniumsulfat-Wasser in Gegenwart von Ammoniumrhodanid und Schwefelsäure wurde untersucht. Kupfer, Zink, Kobalt, Eisen (III), Indium und Molybdän werden mit hohem Verteilungskoeffizienten in die PEG-Phase extrahiert.
The paper has been presented at the Fifth European Conference on Analytical Chemistry (Euroanalysis V), Cracow, August 26–31, 1984. 相似文献
10.