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1.
N. A. Ermolaeva I. P. Tsypysheva I. P. Baikova L. V. Spirikhin E. A. Kantor M. S. Yunusov 《Russian Journal of Organic Chemistry》2006,42(12):1848-1850
2,4,6-Triphenyl-and 2,6-diaryl-3,5-dinitropiperidines were synthesized in 70–79% yields by reaction of 1,3,5-triaryl-2,4-diazapenta-1,4-dienes with 2,2-dimethyl-and 2-phenyl-1,3-dinitropropanes. 相似文献
2.
A. A. Panasenko L. V. Spirikhin B. V. Flekhter G. A. Tolstikov 《Russian Chemical Bulletin》1984,33(11):2287-2290
Conclusions The1H and13C NMR spectra were studied for 2,3,4-trisubstituted sulfolanes and the isomerism of these compounds was determined, The use of chemical shift information is more convenient to determine the isomerism of polysubstituted cyclic compounds by PMR spectroscopy, while use of the direct carbon-proton coupling constants is more convenient for this problem when employing13C NMR spectroscopy.Deceased.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 11, pp. 2498–2501, November 1984. 相似文献
3.
Khairitdinova E. D. Tsirlina E. M. Spirikhin L. V. Fedorov N. I. Efremov Yu. Ya. Yunusov M. S. 《Russian Chemical Bulletin》2003,52(9):2078-2080
A new norditerpenoid alkaloid has been isolated from the roots of Delphinium cuneatum. On the basis of 1H, 13C NMR, IR, and mass spectra, the structure of the alkaloid was established as 1,6,14-trimethoxy-7,8-dihydroxy-18-(2-methyl)succinylanthranoyloxyaconane (16-demethoxymethyllycaconitine). The roots of Delphinium cuneatum also contain the known alkaloid methyllycaconitine and N,N"-di(methoxycarbonyl)-3,4-diaminotoluene. 相似文献
4.
Gafarova Yu. T. Dekhtyar" E. F. Dekhtyar" T. F. Fatykhov A. A. Spirikhin L. V. Vostrikova O. S. Zlotskii S. S. Dokichev V. A. 《Russian Chemical Bulletin》2003,52(4):1003-1008
Under mild conditions, trialkylalanes (Et3Al and Bui
3Al) in chlorine-containing solvents (CH2Cl2 or ClCH2CH2Cl) react with cyclic acetals and orthoformates to form glycol monoethers and dialkylacetals, respectively, in high yields. The 1H NMR spectroscopic data demonstrate that CH2Cl2 or ClCH2CH2Cl interacts with Bui
3Al. 相似文献
5.
N. G. Komissarova N. G. Belenkova L. V. Spirikhin O. V. Shitikova M. S. Yunusov 《Chemistry of Natural Compounds》2002,38(1):58-61
Oxidation of betulin by pyridinium dichromate, pyridinium chlorochromate, and K2Cr2O7 -H2SO4 in the presence of tetrabutylammonium bromide was studied. Products of regioselective C-3, C-28-, and exhaustive oxidation, 28-hydroxylup-20(29)-3-one, 3-hydroxy- and 3-oxolup-20(29)-en-28-al were obtained. 相似文献
6.
Kataev V. A. Spirikhin L. V. Khaliullin A. N. Gailyunas I. A. 《Russian Journal of Organic Chemistry》2002,38(10):1507-1509
The alkylation of 2-chloro-5(6)-nitrobenzimidazole with 2-chloromethylthiirane was studied for the first time. Depending on the conditions, isomeric mixtures of nitro-substituted 2-chloro-1-(thietan-3-yl)benzimidazoles and dihydrothiazolo[3,2-a]benzimidazoles were obtained. 相似文献
7.
E. D. Khairitdinova E. M. Tsyrlina L. V. Spirikhin N. I. Fedorov M. S. Yunusov 《Chemistry of Natural Compounds》2005,41(5):575-577
The known alkaloids deltaline, methyllycaconitine, elasine, and the new norditerpene alkaloid alpinine were isolated from
the aerial part of Delphinium alpinum. The structure of the last was proposed as 1α,6β, 16β-trimethoxy-7-hydroxy-8-ethoxy-14α-propionyloxy-4β-(2″-methyl)succinylanthranoyloxymethyl-N-ethylaconitane
on the basis of PMR, 13C NMR, IR, and mass spectra.
__________
Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 469–471, September–October, 2005. 相似文献
8.
L. M. Khalilov L. A. Baltina L. V. Spirikhin E. V. Vasil'eva R. M. Kondratenko A. A. Panasenko G. A. Tolstikov 《Chemistry of Natural Compounds》1990,25(4):426-430
Details of the13C NMR spectra of glycyrrhizic acid and four of its derivatives are given, and on their basis the configurations of the anomeric centers of the carbohydrate chain have been redetermined and the -configuration of the C-1 carbon atom has been suggested.Institute of Chemistry, Bashkir Scientific Center, Urals Branch, USSR Academy of Sciences, Ufa. Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 500–505, July–August, 1989. 相似文献
9.
L. M. Khalilov V. S. Sultanova E. V. Vasil'eva L. V. Spirikhin I. P. Baikova S. N. Lakeev F. Z. Galin G. A. Tolstikov A. A. Panasenko 《Chemistry of Natural Compounds》1989,24(4):491-497
The structures have been established and the stereochemical assignments have been made of eight pairs of diastereomers and three quartets of stereoisomers of esters of 2,2-dialkylspiro[cyclopropane-3,3-indene]-1-carboxylic acids of the pyrethroid series by the methods of13C NMR spectroscopy using the shift reagent Eu(fod)3. Criteria have been found for assigning the stereoisomers on the basis of the characteristic values of the13C NMR chemical shifts of the signals of the methyl groups at C-2 for determining configuration of the substituents of the cyclopropane moiety of the molecule and of the C-2 signal itself for identifying isomers with respect to the side chain of the pyrethroid molecule. Criteria are proposed for identifying stereoisomers from the chemical shifts of the protons of the gem-dimethyl groups at C-2 in the1H NMR spectra.Institute of Chemistry, Bashkir Branch, Academy of Sciences, Ufa. Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 577–583, July–August, 1988. 相似文献
10.
D. V. Shishkin A. R. Shaimuratova A. N. Lobov N. Z. Baibulatova L. V. Spirikhin M. S. Yunusov N. S. Makara N. Zh. Baschenko V. A. Dokichev 《Chemistry of Natural Compounds》2007,43(2):190-196
Derivatives of N-(2-hydroxyethyl)cytisine, N-(2-hydroxypropyl)-, N-(2-hydroxy-2-(1-adamantyl)ethyl)-, and N-(2-hydroxy-2-phenylethyl)cytisine, were synthesized by reduction of N-(2-oxopropyl)-, N-(2-oxo-2-(1-adamantyl)ethyl)-and N-(2-oxo-2-phenylethyl)cytisine with metal hydrides. The antiarrhythmic and analgesic activities of the prepared compounds
were investigated.
__________
Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 157–162, March–April, 2007. 相似文献