Synthesis,design of experiments and optimization of heterogeneous Fenton-like degradation of tartrazine by MgFe2O4 nano-catalyst

In this work, magnesium ferrites nanoparticles (MgFe₂O₄ NPs) were successfully fabricated by sol-gel auto-combustion (SGAC) method and were used in heterogeneous Fenton-like degradation of tartrazine. The obtained products were characterized using XRD, FTIR, SEM and EDX. XRD studies confirmed that the synthesized MgFe₂O₄ NPs had a cubic spinel structure. The average crystallite size was evaluated using the Debyee Scherrer formula and found to be in the range 16.18–28.55 nm. In FTIR spectra, two primary absorption bands at 571 cm^?1 and 415 cm^?1 were observed. The spinel ferrites are characterized by these bands and the EDX confirms the presence of the desired elements Mg, Fe, and O. The influences of operating parameters were examined using the Box Behnken statistical design (BD), including magnesium ferrite dosage (0.04–0.12 g/L), tartrazine concentration (30–50 mg/L) and H₂O₂ concentration (3.53–7.06 mM). Using analysis of variance, a significant quadratic model was created. Optimum conditions were magnesium ferrite dosage of 0.092 g/L, tartrazine concentration of 30.21 mg/L and H₂O₂ concentration of 6.66 mM, respectively. The predicted degradation efficiency within the optimum conditions as established by the suggested model was 98.4%. Confirmatory tests were carried out and the degradation efficiency of 98.9% was observed, which was in good agreement with the model's prediction. After five recuperation and reapplications, the catalyst's degradation efficiency remains stable. These findings indicate that a heterogeneous Fenton-like process utilizing MgFe₂O₄ is effective in advanced wastewater treatment.     

Nickel Supported on Alkaline Earth Metal–Doped γ-Al2O3–La2O3 as Catalysts for Dry Reforming of Methane

Russian Journal of Applied Chemistry - Nickel catalysts supported on γ–Al2O3 doped with La2O3 and alkaline earth oxides (MgO, CaO, and SrO) were investigated in the dry reforming of...     

Second Eigenvalue of Schrödinger Operators¶and Mean Curvature

Let $M$ be a compact immersed submanifold of the Euclidean space, the hyperbolic space or the standard sphere. For any continuous potential q on M, we give a sharp upper bound for the second eigenvalue of the operator −Δ+q in terms of the total mean curvature of M and the mean value of q. Moreover, we analyze the case where this bound is achieved. As a consequence of this result we obtain an alternative proof for the Alikakos–Fusco conjecture concerning the stability of the interface in the Allen–Cahn reaction diffusion model. Received: 18 June 1999 / Accepted: 6 July 1999     

Lasers and laser applications in the 1990s: A survey of laser safety schemes

A survey of the status of laser safety in UK laser companies is reported. UK laser manufacturers/suppliers were questioned on the types of laser sold, their application and about their laser safety schemes. Nearly two-thirds of suppliers produce lasers in the Class IIIB and IV categories, i.e. those requiring the highest level of safety precautions. However, just under half the companies had difficulties in implementing the current UK laser safety standards (BS 7192/IEC 825). A case is demonstrated for a mechanism providing practical advice on implementation of these standards. This is further strengthened by comparison of a survey carried out five years ago indicating a similar number of manufacturers with difficulties.     

Fabrication of graphene‐silver/polyurethane nanofibrous scaffolds for cardiac tissue engineering

The graphene‐based nanocomposites are considered as great candidates for enhancing electrical and mechanical properties of nonconductive scaffolds in cardiac tissue engineering. In this study, reduced graphene oxide‐silver (rGO‐Ag) nanocomposites (1 and 2 wt%) were synthesized and incorporated into polyurethane (PU) nanofibers via electrospinning technique. Next, the human cardiac progenitor cells (hCPCs) were seed on these scaffolds for in vitro studies. The rGO‐Ag nanocomposites were studied by X‐ray diffraction (XRD), Raman spectroscopy, and transmission electron microscope (TEM). After incorporation of rGO‐Ag into PU nanofibers, the related characterizations were carried out including scanning electron microscope (SEM), TEM, water contact angle, and mechanical properties. Furthermore, PU and PU/nanocomposites scaffolds were used for in vitro studies, wherein hCPCs showed good cytocompatibility via 3‐(4, 5‐dimethylthiazol‐2‐yl)‐2,5‐diphenyl tetrazolium bromide (MTT) assay and considerable attachment on the scaffold using SEM studies. Real‐time polymerase chain reaction (PCR) and immunostaining studies confirmed the upregulation of cardiac specific genes including GATA‐4, T‐box 18 (TBX 18), cardiac troponin T (cTnT), and alpha‐myosin heavy chain (α‐MHC) in the PU/rGO‐Ag scaffolds in comparison with neat PU ones. Therefore, these nanofibrous rGO‐Ag–reinforced PU scaffolds can be considered as suitable candidates in cardiac tissue engineering.     

Laplacian eigenvalue functionals and metric deformations on compact manifolds

In this paper, we investigate critical points of the eigenvalues of the Laplace operator considered as functionals on the space of Riemannian metrics or a conformal class of metrics on a compact manifold. We introduce a natural notion of the critical metric of such a functional and obtain necessary and sufficient conditions for a metric to be critical. We derive specific consequences concerning possible locally maximizing metrics. We also characterize critical metrics of the ratio of two consecutive eigenvalues.     

Chaos in variable stars: Topological analysis of W Vir model pulsations

The topological characterization of chaos is applied to the irregular pulsations of a model for a star of the W Virginis type, computed with a state-of-the-art numerical hydrodynamical code. The banded W Vir attractor is found to possess an additional twist when compared to the Rossler band. It is shown that the stellar light-curve contains the same dynamical information about the attractor as the stellar radius or as the radial velocity variations. (c) 1996 American Institute of Physics.     

Extremal Eigenvalues of the Laplacian in a Conformal Class of Metrics: The `Conformal Spectrum'

Let M be a compact connected manifold of dimension n endowed witha conformal class C ofRiemannian metrics of volume one. For any integer k 0, we consider the conformal invariant _k ^c (C) defined as the supremum of the k-th eigenvalue _k (g) of the Laplace–Beltrami operator _g , where g runs over C.First, we give a sharp universal lower bound for _k ^c (C) extending to all k a result obtained by Friedlander andNadirashvili for k = 1. Then, we show that the sequence \{ _k ^c (C)\}, that we call `conformal spectrum',is strictly increasing and satisfies, k 0, _k+1 ^c (C) ^n/2– _k ^c (C) ^n/2 n ^n/2 _n , where _n is the volume of the n-dimensionalstandard sphere.When M is an orientable surface of genus , we also considerthe supremum _k ^top()of _k (g) over theset of all the area one Riemannian metrics on M, and study thebehavior of _k ^top() in terms of .     

Dynamics of Supramolecular Association Monitored by Fluorescence Correlation Spectroscopy

Supramolecular binding is a key process in many biological systems and in newly developed supramolecular assemblies. Most of the scientific work on these systems is focused on their structural properties and on the thermodynamics of the association process. However, the underlying dynamics are usually much less known, in spite of the great importance they have during the binding process in these highly dynamic systems. Understanding supramolecular binding in biological systems and controlling the functionality of new synthetic supramolecular systems can only be achieved through knowledge of the structure–dynamics relationship. There is a strong need for suitable techniques which cover the typically wide time interval of the association dynamics and which do not need a perturbation of the system. We briefly review high‐resolution fluorescence correlation spectroscopy (FCS) as a technique to monitor supramolecular dynamics and to give information on how structure determines the dynamics of host–guest association. The comparison of hosts and guests with different structures shows that geometrical and orientational requirements determine the association rate constant, whereas the dissociation is defined by the strength of specific interactions. As model hosts cyclodextrins and micelles are studied.     

A Gamma-convergence argument for the blow-up of a non-local semilinear parabolic equation with Neumann boundary conditions

In this paper we study a simple non-local semilinear parabolic equation in a bounded domain with Neumann boundary conditions. We obtain a global existence result for initial data whose L^∞$L^{\infty }$-norm is less than a constant depending explicitly on the geometry of the domain. A natural energy is associated to the equation and we establish a relationship between the finite-time blow up of solutions and the negativity of their energy. The proof of this result is based on a Gamma-convergence technique.