排序方式: 共有32条查询结果,搜索用时 15 毫秒
1.
Sonoko Kikuchi Kazuteru Kawauchi Sadatsugu Ooki Masaru Kurosawa Hisashi Honjho Teruo Yagishita 《Analytical sciences》2004,20(8):1111-1112
Using Raman spectroscopy without any preparation, we analyzed the brominated flame retardant, polybromodiphenyl ethers (PBDEs), which has been prohibited by the European Union. The typical Raman bands of PBDEs, which are clearly different from those of other brominated flame retardants, are from 100 to 300 cm(-1). In our analysis, the detection limit was about 100 ppm, and the analysis took about 1 min, whereas the usual method of solvent extraction using gas chromatography/mass spectroscopy takes 50 h. 相似文献
2.
Psychological evaluation of sound environment in a compartment of a high-speed train 总被引:1,自引:0,他引:1
Sound environment in a compartment of high-speed trains (Shinkansen) was examined in relation to speech communication and annoyance. Three experiments were conducted. In Experiment 1, the annoyance caused by the compartment noise was judged. In Experiment 2, both the compartment noise and the conversation were presented together and the annoyance of the combined sounds was judged. In Experiment 3, both sounds were presented and only the disturbance of conversation was judged. The results showed that: The annoyance of compartment noise showed good correlation with LAeq. The annoyance of the combination of the compartment noise (N) and the conversation (C) increased as C/N decreased. There was, however, a tendency that annoyance increased as C/N increased in some conditions. This suggests that there exists an optimum level of compartment noise at 50-60 dBA taking the level of conversation into consideration. The disturbance of the conversation increased as C/N increased. However, when the level of conversation became high, it was judged as being disturbing regardless of the level of compartment noise. 相似文献
3.
We have investigated the transient characteristics of discrete Raman Amplifiers and found that the response time caused by gain saturation is dependent upon the wavelength, which corresponds to the effective length of the pump light. 相似文献
4.
Tomohiro Kyotani Sonoko Kakui Takehito Mizuno Naoto Shimotsuma Soushi Inoue Junji Saito 《Analytical sciences》2006,22(7):1031-1034
A zeolite NaA (LTA) membrane supported by an alumina porous support tube for pervaporation (PV) dehydration of ethanol was characterized by transmission electron microscopy (TEM) using a focused ion beam (FIB) thin-layer specimen preparation technique and by Fourier transform infrared attenuated total reflectance method (FTIR-ATR) using a diamond prism as the waveguide. FIB-TEM clearly presented cross-section images up to about 15 microm depth from the membrane surface. FTIR-ATR monitored the Si-O asymmetric stretching vibration spectrum. The Si-O spectrum was compared with the TEM image and their relationships were discussed. By combining the two methods, we could study the thickness of surface LTA crystals, the grain boundary, the LTA/alumina interface structure and the crystallinity and density of materials inside of the alumina porous support. Consequently, fine structure changes of the LTA membrane corresponding to the hydrothermal synthesis condition could be sensitively detected. 相似文献
5.
Sadao Hayashi Toshihiro Hirai Sonoko Shimomichi Nobumasa Hojo 《Journal of polymer science. Part A, Polymer chemistry》1982,20(3):839-846
Polyiodide formed by complexation of poly(vinyl acetate) (PVAc) with iodine in the presence of iodide has been investigated by chemical analysis and resonance Raman spectrophotometry. When PVAc films were immersed in iodide-iodine aqueous solutions which had different ratios of iodide to iodine concentration [I?]/[I2], the complex films exhibited tremendous variations of swelling degree, despite the relatively small change in the amount of bound iodine. From a quantitative chemical analysis, the composition of polyiodide bound to PVAc was found to be 1.01 ± 0.035 in the molar ratio of iodide to iodine irrespective of the composition of the iodide-iodine aqueous solution ([I?]/[I2] = 2–500). The polyiodide formed in PVAc-iodine-iodide complex was therefore inferred to be (I3?)n. Resonance Raman spectra obtained on PVAc-iodine-iodide complexes were also identical to those of the benzamide-iodine complex, in which the polyiodide consists of (I3?)n, consistent with the result from chemical analysis. 相似文献
6.
In this short note we discuss the shellability of (nonpure) simplicial complexes in terms of acyclic orientations of the facet-ridge incidence graphs, which shows that we can decide shellability only from the facet-ridge incidences and the total number of faces the simplicial complex contains. 相似文献
7.
Kuniaki Tatsuta Sonoko TokishitaTomohiro Fukuda Takaaki KanoTadaaki Komiya Seijiro Hosokawa 《Tetrahedron letters》2011,52(9):983-986
K1115 B1, isolated from the broth of Streptomyces species, was found to be a mixture of stereoisomers. Authors synthesized all stereoisomers of K1115 B1 by convergent synthesis coupling a rhamnose derivative, an isobenzofuranone, and a chiral tetraol. Comparison of 1H NMR spectra and optical rotations made it clear that the absolute structures of K1115 B1α (the major isomer) and K1115 B1β (the minor isomer) were (1R, 17S)- and (1R, 17R)-configurations, respectively. The optical rotations of the stereoisomers revealed that alnumycin, reported as the identical structure with K1115 B1, might be another mixture of stereoisomers. 相似文献
8.
Komei Fukuda Hiroyuki Miyata Sonoko Moriyama 《Discrete and Computational Geometry》2013,49(2):359-381
Enumeration of all combinatorial types of point configurations and polytopes is a fundamental problem in combinatorial geometry. Although many studies have been done, most of them are for 2-dimensional and non-degenerate cases. Finschi and Fukuda (Discrete Comput Geom 27:117–136, 2002) published the first database of oriented matroids including degenerate (i.e., non-uniform) ones and of higher ranks. In this paper, we investigate algorithmic ways to classify them in terms of realizability, although the underlying decision problem of realizability checking is NP-hard. As an application, we determine all possible combinatorial types (including degenerate ones) of 3-dimensional configurations of 8 points, 2-dimensional configurations of 9 points, and 5-dimensional configurations of 9 points. We also determine all possible combinatorial types of 5-polytopes with nine vertices. 相似文献
9.
Effects of polyethylene spacer length in polymeric electrolytes on gelation of ionic liquids and ionogel properties 下载免费PDF全文
Jun'ichi Nagasawa Sonoko Wakahara Hajime Matsumoto Hideyuki Kihara Masaru Yoshida 《Journal of polymer science. Part A, Polymer chemistry》2015,53(2):249-255
Polymer electrolytes containing N,N′-(trans-cyclohexane-1,4-diyl)dibenzamide linkages, polyethylene ((CH2)m, m = 2, 4, 10) spacers, and bis(trifluoromethanesulfonyl)amide (TFSA) or bis(fluorosulfonyl)amide (FSA) counteranions (polymer abbreviation: CDBAm•X; m = 2, 4, 10; X = TFSA, FSA) have been synthesized, adding to our previous report (m = 6). In addition, their ability to effect the gelation of six ionic liquids and the properties of the resulting ionogels have been examined. The polymers, except for CDBA10•TFSA, effect the gelation for all ionic liquids used in this study at fairly low concentrations (0.9–50 g/L). Ionogel ionic conductivity is not dependent on the spacer length, but does decrease slightly as increasing amounts of the gelatinizer are introduced. In contrast to ionic conductivity, the temperatures at which these ionogels transition into isotropic fluids is dependent on the spacer length; the gel composed of [EMI][FSA] and 100 g/L of CDBA6•FSA transforms at 120 °C, while the gel composed of [EMI][FSA] and 5 g/L of CDBA2•FSA does not transform into a sol even when temperatures become 155 °C. In brief, ionogel heat resistance can be improved by changing the spacer length of the polyelectrolyte. Finally, it has been determined using cyclic voltammetry that the potential window of the polyelectrolytes is particularly wide, ranging from −1.6 to 2.5 V. © 2014 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2015 , 53, 249–255 相似文献
10.
To study noise-induced sleep disturbance, a new procedure called “noise interrupted method”has been developed. The experiment is conducted in the bedroom of the house of each subject. The sounds are reproduced with a mini-disk player which has an automatic reverse function. If the sound is disturbing and subjects cannot sleep, they are allowed to switch off the sound 1 h after they start to try to sleep. This switch off (noise interrupted behavior) is an important index of sleep disturbance. Next morning they fill in a questionnaire in which quality of sleep, disturbance of sounds, the time when they switched off the sound, etc. are asked. The results showed a good relationship between LAeq and the percentages of the subjects who could not sleep in an hour and between LAeq and the disturbance reported in the questionnaire. This suggests that this method is a useful tool to measure the sleep disturbance caused by noise under well-controlled conditions. 相似文献