全文获取类型
收费全文 | 178篇 |
免费 | 2篇 |
专业分类
化学 | 115篇 |
晶体学 | 1篇 |
力学 | 4篇 |
数学 | 13篇 |
物理学 | 47篇 |
出版年
2024年 | 1篇 |
2021年 | 2篇 |
2020年 | 3篇 |
2019年 | 1篇 |
2018年 | 2篇 |
2016年 | 4篇 |
2015年 | 1篇 |
2014年 | 8篇 |
2013年 | 7篇 |
2012年 | 5篇 |
2011年 | 4篇 |
2010年 | 4篇 |
2009年 | 6篇 |
2008年 | 13篇 |
2007年 | 7篇 |
2006年 | 8篇 |
2005年 | 11篇 |
2004年 | 8篇 |
2003年 | 7篇 |
2002年 | 6篇 |
2001年 | 9篇 |
2000年 | 5篇 |
1999年 | 3篇 |
1998年 | 3篇 |
1996年 | 2篇 |
1995年 | 3篇 |
1994年 | 5篇 |
1993年 | 5篇 |
1992年 | 7篇 |
1991年 | 6篇 |
1990年 | 4篇 |
1989年 | 5篇 |
1987年 | 5篇 |
1986年 | 1篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1982年 | 3篇 |
1980年 | 1篇 |
1976年 | 1篇 |
排序方式: 共有180条查询结果,搜索用时 15 毫秒
1.
We calculate the loss induced in a single-mode rectangular optical waveguide by the presence of a second waveguide, perpendicular to the first, which crosses over the first waveguide at a variable distance d. Our calculation is applied to the analysis of several doped silica waveguides of practical importance for optical circuit design. 相似文献
2.
3.
4.
An approximate method for the analysis of planar-waveguide distributed-feedback lasers is extended to include a nonvanishing reflectivity at the ends of the structure. An index grating structure with parasitic losses is investigated. An expression for the small-signal gain coefficient 0MN as a function of the output power P
MNout normalized to the saturation power P
s
, coupling coefficient K, complex reflectivity R of end reflectors, and waveguide parameters is presented. 相似文献
5.
6.
A. Baranowski M. Dębowska K. Jerie J. Rudzińska-Girulska Z. Paweŀka R. T. Sikorski 《Journal of Radioanalytical and Nuclear Chemistry》1995,190(2):463-467
Results of angular correlation of annihilation radiation (ACAR) and positron annihilation lifetime (PAL) measurements are presented for five styrene copolymers: poly(co-styrene-phenylmaleimide) and its three derivatives with chlorine as well as for one with the OH group substituted at the benzene ring. It occurs that the chlorine substituted at three different positions at the benzene ring poly(co-styrene-o (or-m,-p)-chlorophenylmaleimide) inhibits the formation of the positronium to different extent. The greatest effect is observed in case of the chlorine atom substituted at the benzene ring at the ortho-position towards the nitrogen atom. The two long lifetimes (3 and 4) observed in the lifetime spectra are connected with the bimodal distributions of the free volume radius in the samples. 相似文献
7.
John T. Gupton John E. Gall Steve W. Riesinger Stanton Q. Smith Kathy M. Bevirt James A. Sikorski Maria L. Dahl Zdenek Arnold 《Journal of heterocyclic chemistry》1991,28(5):1281-1285
An alternative preparation of a 2-iminovinamidinium salt from phosphonoacetic acids is described along with its application to the synthesis of 5-formylpyrimidines and masked 4-formylpyrazoles. 相似文献
8.
Pablo A. Molina R. Steven Sikorski Jan H. Jensen 《Theoretical chemistry accounts》2003,109(3):100-107
The relationship between hydrogen bonding and NMR chemical shifts in the catalytic triad of low-pH α-chymotrypsin is investigated
by combined use of the effective fragment potential [(2001) J Phys Chem A 105:293] and ONIOM–NMR [(2000) Chem Phys Lett 317:589] methods. Our study shows that while the His57 Nδ1−H bond is stretched by a relatively modest amount (to about 1.060 ?) this lengthening, combined with the polarization due
to the molecular environment, is sufficient to explain the experimentally observed chemical shifts of 18.2 ppm. Furthermore,
the unusual down-field shift of Hɛ1 (9.2 ppm) observed experimentally is reproduced and shown to be induced by interactions with the C=O group of Ser214 as previously
postulated. The free-energy cost of moving Hδ1 from His57 to Asp102 is predicted to be 5.5 kcal/mol.
Received: 26 September 2001 / Accepted: 6 September 2002 / Published online: 21 January 2003
Contribution to the Proceedings of the Symposium on Combined QM/MM Methods at the 222nd National Meeting of the American
Chemical Society, 2001
Correspondence to: J. H. Jensen e-mail: jan-jensen@uiowa.edu
Acknowledgements. This work was supported by a Research Innovation Award from the Research Corporation and a type G starter grant from the
Petroleum Research Fund. The calculations were performed on IBM RS/6000 workstations obtained through a CRIF grant from the
NSF (CHE-9974502) and on supercomputers at the National Center for Supercomputer Applications at Urbana-Champaign. The authors
are indebted to Visvaldas Kairys for help with the CHARMM program, and to Daniel Quinn for many helpful discussions. 相似文献
9.
Anna Rakowska Robert Filipek Krzysztof Sikorski Marek Danielewski Renata Bachorczyk 《Mikrochimica acta》2004,145(1-4):183-186
The interdiffusion process in thin and thick (500nm–60µm) Au–Ni layers deposited on different substrates is studied using the EDS technique. In-depth X-ray analysis based on the Pouchou and Pichoir method is applied for obtaining the concentration profiles in nanometre scale multi-layers. A theoretical analysis using the Darken method is employed for modelling interdiffusion in the Au–Ni system. Computer simulations, where intrinsic diffusivities of the Au and Ni are functions of composition, are presented and compared with experimental results. 相似文献
10.