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The protected ceramide: N‐((2S,3S,4R)‐3,4‐bis(benzyloxy)‐1‐hydroxyoctadecan‐2‐yl)tetracosanamide, was attempted to introduce a triflate as a leaving group followed by a nucleophilic substitution with azido group in one‐pot manner. Unexpectedly, the oxazole ring formed via a thermodynamically favored intramolecular cyclization was opened to generate the original ceramide by triflic acid. In addition, the residual acid promoted a formylation of the primary hydroxy group in DMF. 相似文献
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N. Destouches B. Sider A. V. Tishchenko O. Parriaux 《Optical and Quantum Electronics》2006,38(1-3):123-131
The conditions for maximum longitudinal electric field of a TM mode at the surface of a step index slab waveguide, and the value of this maximum are given in a normalized analytical form. They are applied to a grating coupling structure corresponding to a resonant laser mirror or to optical interconnects involving a normally incident free space wave and a singlemode slab waveguide. 相似文献
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