全文获取类型
收费全文 | 304篇 |
免费 | 11篇 |
专业分类
化学 | 201篇 |
晶体学 | 4篇 |
力学 | 3篇 |
数学 | 25篇 |
物理学 | 82篇 |
出版年
2022年 | 6篇 |
2021年 | 5篇 |
2020年 | 3篇 |
2018年 | 4篇 |
2017年 | 5篇 |
2016年 | 12篇 |
2015年 | 8篇 |
2014年 | 11篇 |
2013年 | 31篇 |
2012年 | 11篇 |
2011年 | 24篇 |
2010年 | 12篇 |
2009年 | 20篇 |
2008年 | 17篇 |
2007年 | 22篇 |
2006年 | 11篇 |
2005年 | 17篇 |
2004年 | 9篇 |
2003年 | 3篇 |
2002年 | 5篇 |
2000年 | 2篇 |
1999年 | 3篇 |
1998年 | 2篇 |
1997年 | 4篇 |
1996年 | 5篇 |
1995年 | 6篇 |
1994年 | 3篇 |
1993年 | 4篇 |
1992年 | 5篇 |
1991年 | 3篇 |
1990年 | 3篇 |
1987年 | 3篇 |
1985年 | 3篇 |
1984年 | 4篇 |
1983年 | 3篇 |
1982年 | 2篇 |
1980年 | 2篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1977年 | 3篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1969年 | 3篇 |
1968年 | 2篇 |
1967年 | 1篇 |
1966年 | 1篇 |
1958年 | 2篇 |
1942年 | 1篇 |
排序方式: 共有315条查询结果,搜索用时 31 毫秒
1.
It is explicitly shown that if phase transition occurs at the core of a newborn neutron star with moderately strong magnetic
field strength, which populates only the electron’s Landau levels, then in the β -equilibrium condition, the quark core is
energetically much more unstable than the neutron matter of identical physical condition. 相似文献
2.
An exact formalism for the relativistic version of Landau theory of Fermi liquid in presence of strong quantizing magnetic field is developed. Both direct and exchange type interactions with scalar and vector coupling cases are considered. 相似文献
3.
Complex dielectric spectroscopy (frequency range 5 Hz-13 MHz) has been used to analyse the frequency, temperature and bias-field dependences of the molecular dynamics of a very high-spontaneous-polarization ferroelectric liquid crystalline material exhibiting SmA, SmC* and unknown SmX smectic phases. Different smectic phase transition temperatures have been observed from the study of the temperature dependence of the dielectric strength and the relaxation frequency. The phase transition temperatures (crystalline to isotropic phases) have also been described very accurately from the temperature-dependent symmetric and asymmetric shape parameters of the relaxation function and also the dc conductivity. In a planar aligned cell, two symmetric modes (Goldstone mode and domain mode) have been observed in both the SmX and SmC* phases. One asymmetric mode (X-mode) observed in the SmC* and SmA phases could be related to the interaction of dipoles of the ferroelectric liquid crystals being affected by the surface of the cell. The soft mode, which usually appears very close to the SmC*-SmA phase transition was not observed until the bias field was applied. The second order nature of the SmC*-SmA phase transition was revealed. 相似文献
4.
Proton and alpha particle spectra have been measured in the 12C+93Nb and 12C+58Ni reactions at E(12C)=40 and 50 MeV and in the 16O + 93Nb reaction at E(16O) =75 MeV. The spectra are compared with the statistical model calculations. The shapes of the calculated spectra are in
agreement with experimental data except for the alpha spectrum in the 12C + 93Nb reaction at 40 MeV. The observed evaporation bump is at ∼2 MeV lower energy compared to the calculated one. This discrepancy
could imply alpha particle emission from a deformed configuration before compound nucleus formation at this near Coulomb barrier
beam energy. 相似文献
5.
Decomposition of isopropanol on V2O5 and the bonzes Li0.02V2O5, Na0.02V2O5, Na0.06V2O5, Li0.33V2O5, and Na0.33V2O5 has been studied in the temperature range 168–300°C. The main reaction was found to be dehydration to propene with negligible dehydrogenation to acetone on the first four catalysts. Dehydration on these catalysts increased with the alkali metal content, but the energy of activation remained unchanged. On the last two catalysts, dehydration and dehydrogenation proceeded at comparable rates. A tentative mechanism for the dehydration of isopropanol is proposed, based on the effect of the product on the initial rate, the electric conductivity of the catalysts and their ESR spectra.
V2O5 : Li0,02V2O5, Na0,02V2O5, Na0,06V2O5, Li0,33V2O5 Na0,33V2O5 186–300°C. . , . . , , .相似文献
6.
Chakrabarty D Seth D Chakraborty A Sarkar N 《The journal of physical chemistry. B》2005,109(12):5753-5758
The effects of confinement of the ionic liquid 1-butyl-3-methylimidazolium tetrafluoroborate on solvation dynamics and rotational relaxation of Coumarin 153 (C-153) in Triton X-100/cyclohexane microemulsions have been explored using steady-state and picosecond time-resolved emission spectroscopy. The steady-state and rotational relaxation data indicate that C-153 molecules are incorporated in the core of the microemulsions. The average rotational relaxation time increases with increase in w ([bmim][BF(4)]/[TX-100]) values. The solvent relaxation in the core of the microemulsion occurs on two different time scales and is almost insensitive to the increase in w values. The solvent relaxation is retarded in the pool of the microemulsions compared to the neat solvent. Though, the retardation is very small compared to several-fold retardation of the solvation time of the conventional solvent inside the pool of the microemulsions. 相似文献
7.
8.
9.
Rita Das Nigamananda Das Anadi C. Dash Ansuman Roy Shyamal K. Sarkar 《Transition Metal Chemistry》1996,21(1):90-94
Summary The reaction of ()-(tetren)CoOH2+ with S2O
3
2-
in the 7.25–8.28 pH range at 20–40 °C yielded S- (yellow) and O- (purple) bonded thiosulfato(tetren)cobalt(III) complexes, the former in larger quantities. The rate determining step is preceded by diffusion-controlled ion-pair [(tetren)CoOH2+,S2O
3
2-
] formation. Replacement of coordinated OH- by S2O
3
2-
is interpreted in terms of an internal conjugate base mechanism: (tetren)CoOH2+ (tetren-H)CoOH
2
2+
, the reactive amido conjugate base being generated by intramolecular proton transfer from the coordinated NH site.In acid medium the S-bonded (tetren)Co(S2O3)+ is highly stable to redox decomposition, in contrast to its pentaammine analogue. The complex however, undergoes base hydrolysis yielding the corresponding hydroxo complex. The rate and activation parameters for the base hydrolysis have been reported. Photolysis of O- and S-bonded isomers of [(tetren)CoS2O3]+ in acidic medium at 254 and 313 nm, respectively, yielded aquation products accompanied by some decomposition of S2O
3
2-
. 相似文献
10.
Decomposition of isopropanol (IPA) on V2O5, Li0.02V2O5, Na0.02V2O5, Na0.06V2O5, Li0.33V2O5, and Na0.33V2O5 has been studied in the temperature range 186–300°C. The first four catalysts (α-phase) show predominately dehydration, whereas the last two (β-phase) have comparable dehydration and dehydrogenation activity. Dehydration activity increases with alkali metal concentration within the α-phase, but falls sharply on the β-phase catalysts. This difference is attributed to the different rate determining steps for the reaction on the α- and β-phase catalysts. X-ray and ir spectral data show that the β-phase catalysts are much more stable than the α-phase. A mechanism for the dehydration of IPA based on the electrical resistivity, ESR spectra, and kinetic data has been proposed. 相似文献