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1.
Richard A. Cairncross Jeffrey G. Becker Shri Ramaswamy Ryan O'Connor 《Applied biochemistry and biotechnology》1996,131(1-3):774-785
Management of moisture penetration and hydrolytic degradation of polylactide (PLA) is extremely important during the manufacturing,
shipping, storage, and end-use of PLA products. Moisture transport, crystallization, and degradation, in PLA have been measured
through a variety of experimental techniques including size-exclusion chromatography, differential scanning calorimetry, and
X-ray diffraction. Quartz crystal microbalance and dynamic vapor sorption experiments have also been used to measure moisture
sorption isotherms in PLA films with varying crystallinity. A surprising result is that, within the accuracy of the experiments,
crystalline and amorphous PLA films exhibit identical sorption isotherms. 相似文献
2.
K. P. Madhusudanan Mohan Prasad Shri Nivas Rastogi D. Fraisse 《Journal of mass spectrometry : JMS》1985,20(11):680-684
The nucleophilic substitution reaction under NH3 chemical ionization (CI) conditions in cis- and trans-1,2-dihydroxybenzosuberans (1–4) has been studied with the help of ND3 CI and metastable data. The results indicate that in the parent diols 1 (cis) and 2 (trans), the substitution ion [MsH]+, is produced mainly by the loss of H2O from the [MNH4]+ ion (SNi reaction) while in their 7-methoxy derivatives 3 and 4, the ion-molecule reaction between [M? OH]+ and NH3 seems to be the major pathway for the formation of [MsH]+. The substitution ion from 1 and 2 and the [MH]+ ion from trans-1-amino-2-hydroxybenzosuberan give similar collision-induced dissociation mass-analysed ion kinetic energy spectra. Interestingly, their diacetates do not undergo the substitution reaction. 相似文献
3.
Madan Mohan Harish C. Khera Shri G. Mittal Anant K. Sirivastava 《Monatshefte für Chemie / Chemical Monthly》1978,109(2):357-368
The complexes of pyridine-2-aldoxime (HPOX) and 6-methylpyridine-2-aldoxime (HMPX) with iron (II) thiocyanate of the type [Fe(L)(NCS)2] (L=HPOX and HMPX) have been prepared and characterized. A study of X-ray, magnetic, vibrational spectra (conventional and far-infrared), electronic spectra andMössbauer spectra has indicated that these complexes have polymeric, pseudo octahedral, coordination geometry with linear bridging thiocyanate ligands. The electronic spectra of mono complexes show a larger, low symmetry, ligand field than that present in [Fe(L)2(NCS)2] complexes. UnperturbedMössbauer spectra show a large quadrupole splitting, E
Q, and smaller isomer shift values in these iron (II) thiocyanate complexes. The magnetically perturbedMössbauer spectra of these iron(II) thiocyanate complexes at room temperature show that the principal component of the electric field gradient tensor is positive and corresponds to ad
xy
(5B2) ground state.With 2 Figures 相似文献
4.
The utility of singlet oxygen-methanol as a reagent for nuclear methoxylation of complex organic natural products is illustrated by a one pot one step photoconversion of pulvinic acid dilactone to p-methoxyvulpinic acid. The study is important from biogenetic considerations. 相似文献
5.
Nagarwal RC Singh PN Kant S Maiti P Pandit JK 《Chemical & pharmaceutical bulletin》2011,59(2):272-278
The aim of this investigation was to develop 5-fluorouracil (5-FU) loaded chitosan nanoparticles (CH-DNPs) for ophthalmic delivery. CH-DNPs were fabricated by ionotropic gelation mechanism using chitosan (CH) and a polyanion (TPP). The nanoparticles were smooth and spherical, confirmed by scanning electron microscopy (SEM) and atomic force microscope (AFM). CH/TPP mass ratio and TPP significantly changed the particles size morphology and encapsulation efficiency. The nanoparticles size ranged from approximately 114 to 192 nm and had a positive zeta potential (30±4 mV). The encapsulation efficiency, loading capacity and recovery of DNPs were 8.12-34.32%, 3.14-15.24% and 24.22 to 67% respectively. Physical characterization was done by Fourier transform infrared (FT-IR) and X-ray diffraction (XRD). No interaction was observed in between drug and polymer and crystallinity of drug was not changed in drug loaded nanoparticles. In-vitro release study of DNPs showed diffusion controlled release. Bioavailability study of batch CS9 was studied in rabbit eye and compare to 5-FU solution. 5-FU level was significantly higher in aqueous humor of rabbit eye. Ocular tolerance was studied in the eye of New Zealand rabbits and tested formulation was non-irritant with no sign of inflammation. 相似文献
6.
The law of variation for mean Hubble’s parameter with average scale factor, in an anisotropic Bianchi type V cosmological space–time, is discussed within the frame work of Lyra’s manifold. The variation of Hubble’s parameter, which gives a constant value of deceleration parameter, generates two types of solutions for the average scale factor; one is the power-law and the other one is of exponential form. Using these two forms, new classes of exact solutions of the field equations have been found for a Bianchi type V space–time filled with perfect fluid in Lyra’s geometry by considering a time-dependent displacement field. The physical and kinematical behaviors of the singular and non-singular models of the universe are examined. Exact expressions for look-back time, luminosity distance and event horizon versus redshift are also derived and their significance are discussed in detail. It has been observed that the solutions are compatible with the results of recent observations. 相似文献
7.
Shri Singh 《Phase Transitions》2013,86(3):183-209
A comprehensive review of the recent developments regarding the phenomenon of reentrant phase transitions (RPT) in liquid crystals is presented. In addition to liquid crystals this phenomenon has been observed in amazingly diverse systems. A critical assessment of the experimental investigations concerning single and multiple reentrances is given. A brief account of the theoretical efforts is also given. The article ends with the identification of the factors which impede the proper understanding of the phenomenon. 相似文献
8.
Based on a thermodynamic model, we investigate how the density variation influences the smectic (Sm A)–isotropic (I) phase transition. We find that the density variation shifts the smectic A–isotropic transition temperature, however, first-order nature of the transition remains the same. Here, we also examine the effect of high pressure on the thermodynamic quantities. The present analysis shows that the pressure strongly influences the enthalpy and density step at the clearing transition. The pressure dependence of the thermodynamic properties is incorporated through the pressure dependent second Landau coefficient and the coefficients which couple the nematic and smectic order parameters to the density. We find a close agreement between theoretical and experimental results. Furthermore, we discuss the implications of the results for achiral liquid crystals. 相似文献
9.
Spatially Homogeneous Bianchi Type V Cosmological Model in the Scale-Covariant Theory of Gravitation 下载免费PDF全文
We discuss spatially homogeneous and anisotropic Bianchi type-V spacetime filled with a perfect fluid in the framework of the seale-covariant theory of gravitation proposed by Canuto et al. By applying the law of variation for Hubble's parameter, exact solutions of the field equations are obtained, which correspond to the model of the universe having a big-bang type singularity at the initial time t = 0. The cosmological model, evolving from the initial singularity, expands with power-law expansion and gives essentially an empty space for a large time. The physical and dynamical properties of the model are also discussed. 相似文献
10.
In this paper, we discuss the dynamics of spatially homogeneous and anisotropic Bianchi type-III string cosmological model in presence of bulk viscous fluid and electromagnetic field. Exact solutions of Einstein’s field equations are obtained by assuming (i) a special form of the deceleration parameter and (ii) the component \(\sigma^{1}_{1}\) of the shear scalar tensor is proportional to mean Hubble parameter. The source of magnetic field is due to an electric current produced along z-axis. The role of bulk viscosity and magnetic field in establishing string phase of universe is presented. The physical and kinematical features of solutions are also discussed in detail. 相似文献