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Trikha A. K. Kaur Shivjinder Sodhi G. S. 《Journal of Thermal Analysis and Calorimetry》2000,61(1):151-156
The new mixed ligand complexes with the formulae Zn(2-bipy)(ox), Zn(4-bipy)1.5 (ox)H2 O, Zn(2,4'-bipy)2 (ox)2H2 O, Cd(2-bipy)(ox)2H2 O, Cd(4-bipy)2 (ox) and Cd(2,4'-bipy)(ox)2H2 O (2-bipy, 4-bipy, 2,4'-bipy=2,2'-, 4,4'- and 2,4'bipyridine, ox=oxalate) were prepared. The thermal decompositions of these
compounds were studied by means of TG, DTG and DTA in air. During heating the complexes decompose via different intermediate
products to ZnO and CdO. The Zn(II) complexes are thermally more stable than the corresponding Cd(II) complexes. The influence
of nitrogen atom position in the bipyridine isomers and nature of central atom on the thermal behaviour of these complexes
was discussed.
This revised version was published online in August 2006 with corrections to the Cover Date. 相似文献
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