全文获取类型
收费全文 | 1993篇 |
免费 | 58篇 |
国内免费 | 13篇 |
专业分类
化学 | 1502篇 |
晶体学 | 25篇 |
力学 | 21篇 |
数学 | 42篇 |
物理学 | 474篇 |
出版年
2021年 | 18篇 |
2020年 | 14篇 |
2019年 | 24篇 |
2018年 | 11篇 |
2017年 | 8篇 |
2016年 | 42篇 |
2015年 | 29篇 |
2014年 | 40篇 |
2013年 | 86篇 |
2012年 | 93篇 |
2011年 | 102篇 |
2010年 | 51篇 |
2009年 | 54篇 |
2008年 | 101篇 |
2007年 | 120篇 |
2006年 | 122篇 |
2005年 | 114篇 |
2004年 | 121篇 |
2003年 | 101篇 |
2002年 | 87篇 |
2001年 | 63篇 |
2000年 | 60篇 |
1999年 | 35篇 |
1998年 | 14篇 |
1997年 | 17篇 |
1996年 | 25篇 |
1995年 | 27篇 |
1994年 | 23篇 |
1993年 | 33篇 |
1992年 | 33篇 |
1991年 | 23篇 |
1990年 | 22篇 |
1989年 | 21篇 |
1988年 | 21篇 |
1987年 | 21篇 |
1986年 | 21篇 |
1985年 | 32篇 |
1984年 | 22篇 |
1983年 | 11篇 |
1982年 | 10篇 |
1981年 | 12篇 |
1980年 | 17篇 |
1979年 | 21篇 |
1978年 | 24篇 |
1977年 | 17篇 |
1976年 | 15篇 |
1975年 | 8篇 |
1974年 | 17篇 |
1973年 | 22篇 |
1972年 | 7篇 |
排序方式: 共有2064条查询结果,搜索用时 214 毫秒
1.
Investigation of one step synthesis of 2-substituted 3-tri-(or di-)fluoromethyl-2-propenals has been carried out using versatile aldehydes, tri- or di-fluoroacetaldehyde ethyl hemiacetal in the presence of diethylaminotrimethylsilane (DEATMS) in an ionic liquid, and it was demonstrated that this route enabled us to successfully construct 2-substituted 3-tri-(or di-)fluoromethyl-2-propenals with the high level selectivity of geometric isomers. 相似文献
2.
Yoshio Moriya Shinichi Nakata Hirotaka Morimoto Nobuaki Ogawa 《Analytical sciences》2004,20(11):1533-1536
Analysis by reflection spectrometry was performed to clarify the interfacial adsorption of protonated lipophilic tetraphenylporphyrin derivatives in a dodecane-aqueous sulfuric acid system, and to confirm the utility of partial reflection spectroscopy. Interfacial adsorption was not observed for porphyrins substituted at the 2,6 positions of meso-phenyl groups, suggesting that the substituents prevent porphyrins from forming aggregates by steric hindrance. Polymorphous J-aggregates of acid dications were produced by tetra-p-tolylporphyrin with a saturated interfacial molecular density of 1.0 x 10(-10) mol cm(-2), which could yield 48 degrees as a mean tilting angle of the pyrrole ring plane from the interface normal. Partial-reflection spectrometry can provide sensitive detection and molecular orientation analysis of interfacial adsorbates. 相似文献
3.
T. Ishii M. Asai A. Makishima I. Hossain P. Kleinheinz M. Ogawa M. Matsuda S. Ichikawa 《The European Physical Journal A - Hadrons and Nuclei》2002,13(1-2):15-19
Nuclei in the neutron-rich Ni region have been studied by γ-ray spectroscopy. Gamma-rays emitted from isomers, with T
1/2 > 1 ns, produced in heavy-ion deep-inelastic collisions were measured with an isomer-scope. The nuclear structure of the
doubly magic 68Ni and its neighbor 69,71Cu is discussed on the basis of the shell model. Future experiments for more neutron-rich Ni nuclei are also viewed.
Received: 1 May 2001 / Accepted: 4 December 2001 相似文献
4.
Mark Doyle Susan A. Mulligan Tetsuya Matsuda Gerald M. Pohost 《Magnetic resonance imaging》1992,10(6):887-892
A new “bright blood” strategy, outflow refreshment imaging, is introduced in which a number of overlapping slices are excited in rapid succession. Flowing spins that refresh each overlapped slice portion contribute a bright signal. Additionally, static tissue in each non-overlapped slice portion also yields a bright signal. However, the flow/static contrast is comparable to that produced in inflow refreshment images, and angiograms can be generated by conventional maximum intensity projection processing. The dual ability to visualize angiograms and static tissue images is a major benefit of the strategy. Computer simulations of flow sensitivities and in vivo results are presented which compare the outflow and inflow refreshment imaging strategies. 相似文献
5.
We synthesized TPP[FeIII(Pc)(CN)2]2, PTMAx[FeIII(Pc)(CN)2]·y(MeCN), and PXX [FeIII(Pc)(CN)2], a new series of charge-transfer salts containing the axially-substituted phthalocyanine (Pc), [FeIII(Pc)(CN)2]−. In this molecular unit, the π conduction electron derived from the Pc-ring coexists with the d electron which is a potential source of a local magnetic moment. Therefore various phenomena associated with the interplay between local magnetic moments and conduction electrons are expected. We observed the giant negative magnetoresistance (GNMR) in all the three salts. The GNMR is highly anisotropic for the magnetic-field direction, and reflects the g-tensor anisotropy of the local magnetic moment in the [FeIII(Pc)(CN)2]− unit. This indicates that the GNMR in these salts originates from the strong π-d interaction in the [FeIII(Pc)(CN)2]− unit. 相似文献
6.
7.
The propagation characteristics of shear horizontally polarized (SH) waves passing through (Ni42Nb28Zr30)100–x Hx (x = 0–15.2) glassy alloys were investigated as a function of hydrogen content. With an increase in hydrogen content, the propagation time and main frequency of the receiving waves show increase and decrease, respectively, indicating expan‐ sion in average atomic distance which comes from solution of hydrogen. In sharp contrast to crystalline alloys, the decrease in damping ratio and the delay in phase with increasing hydrogen suggest a strong settlement of hydrogen into four‐coordination sites surrounded tetrahedrally by four Zr atoms and the resulting increase in dynamic elasticity, respectively. (© 2007 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
8.
Dong Hwan Choi Yoshio Katakura Rieko Matsuda Yuzuru Hayashi Masato Hirobe Yasuhiro Goda Kazuaki Ninomiya Suteaki Shioya 《Analytical sciences》2007,23(2):215-218
The mathematical model for predicting the precision, limit of detection (LOD) and range of quantitation (ROQ) in a competitive enzyme-linked immunosorbent assay (ELISA) proposed by Hayashi et al. (Anal. Chem., 2004, 76, 1295) was validated. The model describes the relative standard deviation (RSD) of concentration estimates by the RSDs of pipetting volumes of analyte, enzyme-conjugated antigen, antibody and substrate solutions, and the standard deviation (SD) of inherent absorbances between the wells in an ELISA plate. For 6 kinds of direct competitive ELISA kits, the LOD and ROQ predicted by the model agreed well with those obtained by experiments with real samples. It was also confirmed that the model is applicable to the prediction of uncertainty that depends on the pipetting error of the viscous antiserum solution. The model was demonstrated to be useful for estimating the LOD and ROQ of competitive ELISA. 相似文献
9.
10.
B. F. Araujo H. T. Matsuda T. A. Kuada J. A. Araujo 《Journal of Radioanalytical and Nuclear Chemistry》1992,166(1):75-83
In the actinide separation process using TBP as extractant, hydrolytic and radiolytic reactions cause a gradual decomposition of the extractant, resulting in the formation of degradation products which can affect process performance adversely. The TBP diluent has to be cleaned from these degradation products before it is reused. This paper deals with a procedure for solvent cleanup, using a fourstage continuous contactor for increasing the scrubbing efficiency. 相似文献