Molar volumes and ion pairing of lithium halides in alcohols

The concentration dependence of the apparent molar volumes of lithium halides (and electrolytes in general) in alcohols (and solvents permitting association in general) is, in the first instance, due to changes in the degree of association and to the inherent difference between the apparent molar volumes of the ions and of the ion pairs. Previous publications on the molar volumes of electrolytes in organic solvents, disregarding altogether ion pairing, appear to be incorrect. Data from the literature for lithium chloride and lithium bromide in normal primary alcohols and several branched alcohols from C₁ to C₈ and data from our laboratory for lithium halides in 1-hexanol and 2-ethyl-1-hexanol served for the determination of φ _V and φ _E . Electrical and structural contributions to the values of these functions for the ions and for the ion pairs are discussed.     

Spectral and temporal holograms with nonlinear optics

In this Letter we show how encoding techniques for computer-generated holograms may be used to arbitrarily shape a nonlinearly generated spectrum and consequently the temporal shape by modulating the quadratic nonlinear coefficient. We give examples of a modulation pattern and a simple setup that can generate high-order Hermite-Gauss and Airy functions through difference-frequency generation from a transform-limited Gaussian pulse, under practical fabrication considerations.     

The Renner—Teller effect and vibronically induced bands in the electronic spectrum of NCO

It is suggested that the forbidden, “parallel” bands in the ò Σ⁺ ? X?² Π system of NCO are a manifestation of a Renner—Teller interaction. The relative intensities of these bands are explicable when reference is made to the parameter Δg_L measured in microwave Zeeman experiments on the molecule in the X?² Π state.     

Detection limits for single small flaws and groups of flaws when using focussed ultrasonic transducers

The performance of ultrasonic imaging systems, using line-focussed transducers, was evaluated theoretically by employing a simple technique based on convolution. The analysis considered the response of single reflectors, which are mainly voids, and also multiple reflectors located both on a single plane and on multiple planes, which represent a porous layer or bond-line. The limits of detection for each of the above cases, in the presence of different levels of acoustic noise in the object under test were also calculated. The results presented are expressed as a function of a dimensionless flaw size, incorporating the ultrasonic frequency and beam F-number. The results can be used to identify the best match between ultrasonic equipment and a specific imaging problem. They can also serve to guide decisions regarding the most suitable detection method for use with the chosen equipment. If the inspection is properly designed, surprisingly small flaws could be reliably detected — even in objects where significant levels of incoherent acoustic noise are found. The method and results presented in this paper for line-focussed transducers fit qualitatively the case of spherically focussed transducers. The method is highly versatile and it can be extended to cover a range of problems, outside the scope of this paper, including, quantitatively, that of the spherically focussed transducer by employing a formulation which uses more computer time and memory.     

Enhanced shape-selective recognition of anion guests through complexation-induced organization of porphyrin hosts

We present a fortuitous discovery of enhanced shape-selective recognition of anion guests that stems from a complexation-induced conformational change in porphyrin hosts upon anion binding. Porphyrin hosts reported here exist in a conformation that is not favorable to guest binding. Anions that bind strongly are those that can induce a conformational change in the host to allow guest binding. Furthermore, guests that mimic the shape of the newly formed pocket bind the strongest.     

Third-harmonic generation via nonlinear Raman-Nath diffraction in nonlinear photonic crystal

We report on the observation of multiple third-harmonic conical waves generated in an annular periodically poled nonlinear photonic crystal. We show that the conical beams are formed as a result of the cascading effect involving two parametric processes that satisfy either the transverse and/or longitudinal phase-patching conditions. This is the first experimental observation of third-harmonic generation based on nonlinear Raman-Nath diffraction.     

A Fast Interferometer Using a Nitrogen Laser for Dense Plasmas

A Mach-Zehnder interferometer utilizing a short pulse (5 ns FWHM) nitrogen laser has been built and successfully operated. This system is capable of measuring plasma electron densities higher than 1020 cm-3 and is simple as well as inexpensive. The same system can be used for schlieren and shadow photography. Examples of an interferogram and a shadowgraph of a high density plasma are presented.